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Book Electron Paramagnetic Resonance of d Transition Metal Compounds

Download or read book Electron Paramagnetic Resonance of d Transition Metal Compounds written by F.E. Mabbs and published by Elsevier. This book was released on 2013-10-22 with total page 1347 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electron paramagnetic resonance (epr) spectroscopy is a sensitive and versatile method of studying paramagnets, which is finding increasing use in chemistry, biochemistry, earth and materials sciences. The technique is treated both qualitatively and quantitatively, with a progressive increase in sophistication in each succeeding chapter. Following a general introductory chapter, the first half of the book deals with single unpaired electron systems and considers both metal and ligand Zeeman, hyperfine and quadrupole interactions. The simulation of these spectra is discussed, followed by the relationship between spin-Hamiltonian parameters and models of the electronic structures of paramagnets. The second half of the book treats multiple unpaired electron systems using the same philosophy. An introduction to the epr properties of cluster compounds and of extended exchanging systems is also given. There is a chapter on linewidths and lineshapes, and an extensive appendix containing much additional information. A wide-ranging library of simulated and experimental spectra is given, as well as graphical data which should aid spectrum interpretation. Each chapter contains key references and there is a substantial subject and keyword index. This book is designed to teach epr spectroscopy to students without any previous knowledge of the technique. However, it will also be extremely useful to researchers dealing with paramagnetic d transition metals.

Book Transition Ion Electron Paramagnetic Resonance

Download or read book Transition Ion Electron Paramagnetic Resonance written by J. R. Pilbrow and published by Oxford University Press, USA. This book was released on 1990 with total page 746 pages. Available in PDF, EPUB and Kindle. Book excerpt: This introductory text on transition ion electron paramagnetic resonance is intended for beginning graduate students in physics and chemistry. The phenomenon studied is an important tool for the identification and characterization of transition and metal ions. The author presents a new perspective that unifies the main features of field-swept EPR of anisotropic systems, and accounts for the origin of asymmetric line shapes, linewidth anisotropy, and strain broadening. A large number of spectra are shown, since familiarity with the shape of typical spectra is essential for the proper employment of this technique. A wide range of examples are also provided, including transition ions in crystals, glasses, semiconductors, phase transitions, proteins and other biological systems. In addition to its value as a text, this work is suitable for scientists in a variety of disciplines, as well as for anyone whose work involves the use of transition ion EPR techniques.

Book Comprehensive Dissertation Index

Download or read book Comprehensive Dissertation Index written by and published by . This book was released on 1984 with total page 862 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vols. for 1973- include the following subject areas: Biological sciences, Agriculture, Chemistry, Environmental sciences, Health sciences, Engineering, Mathematics and statistics, Earth sciences, Physics, Education, Psychology, Sociology, Anthropology, History, Law & political science, Business & economics, Geography & regional planning, Language & literature, Fine arts, Library & information science, Mass communications, Music, Philosophy and Religion.

Book Comprehensive Dissertation Index  Chemistry  E O

Download or read book Comprehensive Dissertation Index Chemistry E O written by and published by . This book was released on 1984 with total page 858 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Electron Spin Resonance of Metal Complexes

Download or read book Electron Spin Resonance of Metal Complexes written by Teh Fu Yen and published by . This book was released on 1969 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Electron Spin Resonance

    Book Details:
  • Author : Philip Rieger
  • Publisher : Royal Society of Chemistry
  • Release : 2007-10-31
  • ISBN : 1847557872
  • Pages : 286 pages

Download or read book Electron Spin Resonance written by Philip Rieger and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes in mathematical terms the extraction of useful information from ESR spectra as applied to paramagnetic organic, inorganic and organometalic molecules. It lays a firm groundwork for understanding more sophisticated experiments, which the availability of newer commercial instruments has made possible. It takes the reader step by step through obtaining and interpretating ESR spectra of paramagnetic molecules. The mathematical basis of each observed phenomena are detailed and examples given. In particular there is a detailed discussion of 2nd order pertubation theory treatment of the Spin Hamiltonian for non-coincident G and A axes.

Book Comprehensive Dissertation Index  Chemistry  P Z

Download or read book Comprehensive Dissertation Index Chemistry P Z written by and published by . This book was released on 1984 with total page 844 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Electron Paramagnetic Resonance of Transition Ions

Download or read book Electron Paramagnetic Resonance of Transition Ions written by A. Abragam and published by Dover. This book was released on 1970 with total page 911 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction to electron paramagnetic resonance. The resonance phenomenon. The spin hamiltonian and the spectrum. Electron-nuclear double resonance (ENDOR). The lanthanide (4f) group. The actinide (5f) group. Ions of the 3d group in intermediate ligand fields. Ions of the d-groups in strong ligand fields. Spin-spin interaction. Spin-phonon interaction. The electronic Zeenan interaction. Group theory: an outline. Group theory: the rotation group. The cubic group and some kramers degeneracy. Elementary theory of the crystal field. Hyperfine structure. Ions in a weak crystal field (f electrons). Intermediate crystal fields (the iron group). The effects of covalent bonding. The Jan-Teller effect in paramagnetic resonance. Thermal and magnetic properties of a paramagnetic substance.

Book EPR of Exchange Coupled Systems

Download or read book EPR of Exchange Coupled Systems written by Alessandro Bencini and published by Courier Corporation. This book was released on 2012-07-19 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: From chemistry to solid state physics to biology, the applications of Electron Paramagnetic Resonance (EPR) are relevant to many areas. This unified treatment is based on the spin Hamiltonian approach and makes extensive use of irreducible tensor techniques to analyze systems in which two or more spins are magnetically coupled. This edition contains a new Introduction by coauthor Dante Gatteschi, a pioneer and scholar of molecular magnetism. The first two chapters review the foundations of exchange interactions, followed by examinations of the spectra of pairs and clusters, relaxation in oligonuclear species, approaches to infinite lattices, and how EPR can provide firsthand information on spin dynamics. Subsequent chapters explore experimental data, magnetically coupled systems, low-dimensional materials, and the use of EPR to characterize excitons and exciton motion. More than 200 figures and tables appear throughout the book, which concludes with a pair of helpful appendices.

Book Dithiolene Chemistry

    Book Details:
  • Author : Edward I. Stiefel
  • Publisher : John Wiley & Sons
  • Release : 2004-01-16
  • ISBN : 0471471917
  • Pages : 752 pages

Download or read book Dithiolene Chemistry written by Edward I. Stiefel and published by John Wiley & Sons. This book was released on 2004-01-16 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Progress in Inorganic Chemistry series provides inorganic chemistry with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 52, Dithiolene Chemistry: Synthesis, Properties, and Applications continues this forum with a focus on dithiolene chemistry and a significant, up-to-date selection of papers by internationally recognized researchers. Dithiolene complexes have a remarkable set of properties, a fact which has made them the object of intense study for new materials and sensors.

Book Advances in Inorganic Chemistry and Radiochemistry

Download or read book Advances in Inorganic Chemistry and Radiochemistry written by and published by Academic Press. This book was released on 1980-10-02 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Inorganic Chemistry and Radiochemistry

Book Electron Spin Resonance of Metal Complexes

Download or read book Electron Spin Resonance of Metal Complexes written by Teh Fu Yen and published by . This book was released on 1969 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Metals in Biology

    Book Details:
  • Author : Graeme Hanson
  • Publisher : Springer
  • Release : 2010-03-11
  • ISBN : 1441911391
  • Pages : 419 pages

Download or read book Metals in Biology written by Graeme Hanson and published by Springer. This book was released on 2010-03-11 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal ions in biology is an ever expanding area in science and medicine involving metal ions in proteins and enzymes, their biosynthesis, catalysis, electron transfer, metal ion trafficking, gene regulation and disease. While X-ray crystallography has provided snapshots of the geometric structures of the active site redox cofactors in these proteins, the application of high resolution EPR spectroscopy in conjunction with quantum chemistry calculations has enabled, in many cases, a detailed understanding of a metalloenzymes mechanism through investigations of the geometric and electronic structure of the resting, enzyme-substrate intermediates and product complexes. This volume, Part II of a two-volume set demonstrates the application of high resolution EPR spectroscopy in determining the geometric and electronic structure of active site metal ion centers in iron sulfur cluster containing metalloproteins, mononuclear molybdenum metalloenzymes, manganese-containing enzymes and novel metalloproteins.

Book Radicals for Life

    Book Details:
  • Author : Ernst van Faassen
  • Publisher : Elsevier
  • Release : 2011-10-13
  • ISBN : 9780080489599
  • Pages : 442 pages

Download or read book Radicals for Life written by Ernst van Faassen and published by Elsevier. This book was released on 2011-10-13 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radicals for Life: the Various Forms of Nitric Oxide provides an up-to-date overview of the role of nitrosocompounds and nitrosyl-iron complexes in physiology. Nitrosocompounds can be considered as stabilised forms of nitric oxide, one of the most important regulatory molecules in physiology today. Many nitrosocompounds share some of the physiological functions of nitric oxide, and may be formed inside living organisms. This is the first book to be published that is dedicated to the role of such nitrosocompounds in physiology, with particular emphasis on the nitrosocompounds that are endogenously formed in higher organisms and humans. Points of discussion include: physical and chemical properties of the compounds, the main chemical pathways in vivo, as well as the physiological effects that have been recognised to date. Each of the nineteen chapters is written by distinguished specialists in the field, well known for their original and important contributions to the subject. Also included are results from a wide range of studies in vitro, in cell cultures, animal models and human volunteers. Examples of alternative forms of nitric oxide, with special emphasis on their protective role against widespread human diseases like atherosclerosis, Alzheimer's disease, diabetes, sexual dysfunction, and renal insufficiency to stroke and ischemia are also included. First monograph to consider and provide an overview of endogenous nitrosocompounds and nitrosyl-iron complexes Extensive bibliographic references, written by specialists of human physiology Providing high scientific quality with a focus on implications for human diseases

Book Progress in Inorganic Chemistry  Volume 58

Download or read book Progress in Inorganic Chemistry Volume 58 written by Kenneth D. Karlin and published by John Wiley & Sons. This book was released on 2014-05-05 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 58 continues to report recent advances with a significant, up-to-date selection of contributions by internationally-recognized researchers. The chapters of this volume are devoted to the following topics: • Tris(dithiolene) Chemistry: A Golden Jubilee • How to find an HNO needle in a (bio)-chemical Haystack • Photoactive Metal Nitrosyl and Carbonyl Complexes Derived from Designed Auxiliary Ligands: An Emerging Class of Photochemotherapeutics • Metal--Metal Bond-Containing Complexes as Catalysts for C--H Functionalization Iron Catalysis in Synthetic Chemistry • Reactive Transition Metal Nitride Complexes Suitable for inorganic chemists and materials scientists in academia, government, and industries including pharmaceutical, fine chemical, biotech, and agricultural.