Download or read book Effects of Metal Dopants in Titanium Dioxide Suspension for Photocatalytic Degradation of Organic Compounds in Water written by Hoi-Lun Helen Tse and published by . This book was released on 1999 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Heterogeneous Photocatalysis written by M. Schiavello and published by . This book was released on 1997-10-09 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photocatalysis is a reaction which is accelerated by light while a heterogeneous reaction consists of two phases ( a solid and a liquid for example). Heterogeneous Photocatalysis is a fast developing science which to date has not been fully detailed in a monograph. This title discusses the basic principles of heterogeneous photocatalysis and describes the bulk and surface properties of semiconductors. Applications of various types of photoreactions are described and the problems related to the modeling and design of photoreactors are covered.
Download or read book Photocatalytic Activity Enhancement of Titanium Dioxide Nanoparticles written by Mohamed A. Barakat and published by Springer. This book was released on 2015-10-26 with total page 39 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this brief, a comprehensive review of the UV/visible-TiO2 photocatalytic oxidation process is presented with an insight into the mechanisms involved, the role of titanium dioxide as a catalyst, irradiation sources, types of reactors, and a comparison between various modes of TiO2 application. An overview of the development and enhancement of the activity of TiO2 nanoparticles in photocatalysis is presented. The topics covered include a detailed look at the unique properties of the TiO2 nanoparticles and their relationship to photocatalytic properties. The utilization of the TiO2 nanoparticles as photocatalysts, in the non-doped and doped forms is also reviewed. Finally, the use of modified TiO2 nanoparticles has made a significant contribution in providing definitive mechanistic information regarding the visible light photocatalytic processes.
Download or read book Photodegradation of Water Pollutants written by Martin M. Halmann and published by CRC Press. This book was released on 1995-12-05 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photodegradation of Water Pollutants, the only complete survey available of current photocatalytic methods for treating water pollutants, covers all aspects of light-stimulated detoxification. Ideal for researchers and students, this new book explains methods for pollution treatment that have proven more effective than conventional biodegradation. Photodegradation of Water Pollutants examines advanced oxidation processes that have been successful in treating the chemical substances produced by industrial effluents and intensive agriculture. These oxidation processes include irradiation with ultraviolet or visible light, the use of homogenous sensitizers, such as dyes, and the use of heterogeneous photocatalysts, such as dispersed semiconductors. In addition, Photodegradation of Water Pollutants addresses the naturally occurring self-cleaning of some pollutants in sunlit surface waters, as well as several alternative non-photochemical approaches to water treatment. Available treatment options are discussed for the main groups of water pollutants, including toxic inorganic ions (cyanides, heavy metals), hydrocarbon derivatives (oil spills, surfactants, pulp and paper wastes), halocarbons, organo-N, organo-P, and organo-S compounds. The text also contains a unique section on the economics of advanced oxidation pollution treatments.
Download or read book Photocatalysts written by Sher Bahadar Khan and published by BoD – Books on Demand. This book was released on 2019-03-06 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book enlightens the type, chemical structure, and application of photo-catalysts. It covers the recent developments in photo-catalysts and their applications, particularly in photo-catalytic degradation of different organic pollutants, hydrogen production, etc. It provides a concise but complete coverage and overview of photocatalysts and their recent advances for a broad audience: beginners, graduate students, and specialists in both academic and industrial sectors.
Download or read book Heterogeneous Photocatalytic Degradation of Organic Pollutants in Water Over Nanoscale Powdered Titanium Dioxide written by Khaled M. Mezughi and published by . This book was released on 2011 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic contaminants from industrial and/or domestic effluents may be harmful to humans directly or indirectly by degrading the quality of the aquatic environment. Consequently these contaminants must be reduced to levels that are not harmful to humans and the environment before disposal. Chemical, physical and biological methods exist for the removal of these pollutants from effluents. Among the available chemical methods, heterogeneous photocatalytic oxidation has been found particularly effective in removing a large number of persistent organics in water. In this study, photocatalytic degradation was explored for the removal of reactive azo-dye (textile dye), triclocarban (disinfectant), clopyralid (herbicide) and three endocrine disrupting compounds (EDCs) (estrone, 17?-estradiol and 17?-ethinylestradiol) from synthetic effluents. The major factors affecting the photocatalytic processes including the initial concentration of the target compounds, the amount of catalyst, the light intensity, the type of catalyst, the electron acceptor, the irradiation time and the pH were studied. Other oxidation techniques including (O3, H2O2, UV) were also studied. Generally UV light is used in combination with titanium dioxide, as photocatalyst, to generate photoinduced charge separation leading to the creation of electron-hole pairs. The holes act as electron acceptors hence the oxidation of organics occur at these sites. These holes can also lead to the formation of hydroxyl radicals which are also effective oxidants capable of degrading the organics. The results obtained in this study indicated that photolysis (i.e. UV only) was found to have no effect on the degradation of reactive azo-dye (RO16). However, complete photocatalytic degradation of 20 mg/L (3.24?10-2 mM) RO16 was achieved in 20 minutes in the presence of 1g/L TiO2 Degussa P25 at pH 5.5. Comparison between various types of catalysts (i.e. Degussa P25, VP Aeroperl, Hombifine N) gave varied results but Degussa P25 was the most effective photocatalyst hence it was selected for this study. For RO16 the optimum catalyst concentration was 0.5 g/L TiO2 with initial concentration of 20 mg/L RO16. It was found that the disappearance of RO16 satisfactorily followed the pseudo first-order kinetics according to Langmuir-Hinshelwood (L-H) model. The rate constant was k= 0.0928 mol/min. Photodegradation of TCC was studied in 70%v acetonitrile: 30%v water solutions. UV light degraded TCC effectively and the reaction rates increased with decreasing initial concentration of TCC. UV/TiO2 gave unsatisfactory degradation of triclocarban (TCC) since only 36% were removed in 60 minutes with initial concentration of TCC 20 mg/L. The degradation of clopyralid and the EDCs was studied using three oxidation systems UV/TiO2, UV/H2O2 and O3. Complete degradation of clopyralid (3,6-DCP) was achieved with UV/TiO2 in about 90 minutes at an optimum catalyst concentration of 1g/L. Zero-order kinetics was found to describe the first stage of the photocatalytic reaction in the concentration range 0.078-0.521 mM. At pH 5 the rate constant was 2.09?10-6? 4.32?10-7 M.s-1.Complete degradation of all the three EDCs was achieved with UV/H2O2 in 60 minutes at catalyst concentration of (2.94?10-2 M). On the other hand complete degradation of the EDCs was achieved in just 2 minutes with ozonation. For high concentration EDCs, TiO2/UV gave low efficiency of degradation as compared with ozone and H2O2/UV. First-order kinetics was found to describe the photocatalytic reaction of the EDCs.
Download or read book Heterogeneous Photocatalysis written by Giuseppe Marcì and published by Elsevier. This book was released on 2019-02-21 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous Photocatalysis: Relationships with Heterogeneous Catalysis and Perspectives highlights the differences between thermal-catalysis and photo-catalysis and indicates borderlines, in particular, the possible synergism between them. The book outlines the basic aspect of thermal- and photo-catalysis, along with the most important characterization techniques. In addition, it presents case studies of thermal-catalytic and photo-catalytic or thermal-photo-catalytic reactions and includes a comparison between the results obtained using an inorganic solid as thermal catalyst and photocatalyst for the same reaction, and in the same setup. Final sections offer information on the preparation methods of (photo)catalysts, various techniques used for their characterization, engineering and economical aspects. This book will be a valuable reference source for students and researchers involved in heterogeneous photocatalysis and catalysis, chemistry, chemical engineering, materials science, materials engineering, environment engineering, nanotechnology and green chemistry. - Provides selective methods for the preparation of microcrystalline/nanocrystalline solids or films used in catalytic and photocatalytic processes - Describes (photo)reactions that can be carried out catalytically and/or photocatalytically - Outlines the different mechanisms, yields and experimental conditions under which photocatalytic reactions can take place - Describes various (photo)reactors and set ups under which the photacatalytic reactions can be carried out - Provides an economic assessment to understand the feasibility of some photocatalytic reactions
Download or read book Photocatalytic Oxidation in Aqueous Titanium Dioxide Suspensions written by Philippe Jean-Luc Espitallier and published by . This book was released on 1997 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Titanium Dioxide written by Magdalena Janus and published by BoD – Books on Demand. This book was released on 2017-07-26 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Titanium dioxide is mainly used as a pigment and photocatalyst. It is possible to find it in food, cosmetics, building materials, electric devices, and others. This book contains chapters about characteristics of anatase and rutile crystallographic structure of titanium dioxide and the use of theoretical calculation for photoactivity determination.
Download or read book Nearly Zero Energy Communities written by Ion Visa and published by Springer. This book was released on 2017-08-31 with total page 739 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses the main challenges in implementing the concepts that aim to replace the regular fossil-fuels based energy pattern with the novel energy pattern relying on renewable energy. As the built environment is one major energy consumer, well known and exploited by each community member, the challenges addressing the built environment has to be solved with the consistent contribution of the community inhabitants and its administration. The transition phase, which already is under implementation, is represented by the Nearly Zero Energy Communities (nZEC). From the research topics towards the large scale implementation, the nZEC concept is analyzed in this book, starting with the specific issues of the sustainable built environment, beyond the Nearly Zero Energy Buildings towards a more integrated view on the community (Chapter1) and followed by various implementation concepts for renewable heating & cooling (Chapter 2), for renewable electrical energy production at community level (Chapter 3) and for sustainable water use and reuse (Chapter 4). As the topic is still new, specific instruments supporting education and training (Chapter 5) are needed, aiming to provide the knowledge that can drive the communities in the near future and is expected to increase the acceptance towards renewable energy implemented at community level. The sub-chapters of this book are the proceedings of the 5th edition of the Conference for Sustainable Energy, during 19-21 October 2017, organized by the R&D Centre Renewable Energy Systems and Recycling, in the R&D Institute of the Transilvania University of Brasov. This event was organized under the patronage of the International Federation for the Science of Machines and Mechanisms (IFToMM) - the Technical Committee Sustainable Energy Systems, of the European Sustainable Energy Alliance (ESEIA) and of the Romanian Academy of Technical Sciences.
Download or read book Heterogeneous Photocatalysis written by Mario J. Muñoz-Batista and published by Springer Nature. This book was released on 2020-07-01 with total page 301 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. The chapter "Mechanochemical Forces as a Synthetic Tool for Zero and One-Dimensional Titanium Oxide-Based Nano-photocatalysts" is available open access under a CC BY 4.0 License via link.springer.com.
Download or read book Papers Relating to History and Genealogy of Chalmers Family 1309 1413 written by and published by . This book was released on with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Photocatalytic Degradation of Organic Contaminants in Water written by Youn-Chul Oh and published by . This book was released on 2004 with total page 346 pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation concerns the elucidation of degradation mechanisms of organic contaminants in aqueous suspension of TiO2, and extending understanding of photo catalysis condition to optimize degradation efficiency. The degradation mechanism of maleic acid, an important intermediate from the photocatalytic degradation of aromatic contaminants, was investigated via product distribution study and control experiments. The understanding of the mechanism of degradation of these compounds can assist us in ascertaining ideal conditions to perform the mineralization of recalcitrant organic compounds. The challenge to degrade a cyanyric acid, a recalcitrant species, by modifying TiO2 suspension was carried out. The addition of fluoride to aqueous suspensions of TiO2 has proved to be an important mechanistic tool in unraveling a long-standing conundrum in photocatalytic degradation. By using this method in parallel with other methods for producing homogeneous hydroxyl-type reagents, it is shown that cyanuric acid is susceptible to degradation under easily accessible conditions. There are isotope studies of photocatalysis of dimethyl phenyl phosphonate, a simple and safe form of organic phosphonate. Exposure of DMMP and related simple phosphonates to TiO2-mediated photocatalytic conditions results first in the loss of one of the methyl esters. An important unsettled mechanistic point is the mechanism by which the methyl is removed. Through the isotope studies of TiO2-mediated photocatalytic degradation of phosphonates, we can now understand removal of the alkyl ester portion of the compounds to produce phosphonic acid monoesters among the primary steps. The retention of 18O in the formation of MMPP clearly demonstrates that the dealkylation mechanism involves degradation of the methyl group exclusively, and neither attack at phosphorous by HO[Multiplied by][Subscript ads] or a related species, nor photoinduced hydrolysis. With an attempt to activate the modified TiO2 photo catalysts by the visible light and decrease the rapid recombination of excited electrons/holes during photoreaction, WO[Subscript x]-TiO2 powder was prepared by a sol-gel method. The WO[Subscript x]-TiO2 catalysts were characterized by XRD, XPS, and SEM-EDX. The degradation of 4-methoxyresorcinol by using WO[Subscript x]-TiO2 under visible light irradiation was observed.
Download or read book Green Photocatalytic Semiconductors written by Seema Garg and published by Springer Nature. This book was released on 2021-09-20 with total page 855 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book comprises a detailed overview on the role of photocatalysts for environmental remediation, hydrogen production and carbon dioxide reduction. Effective ways to enhance the photocatalytic activity of the material via doping, hybrid material, laser light and nanocomposites have been discussed in this book. The book also further elaborates the role of metal nanoparticles, rare earth doping, sensitizers, surface oxygen vacancy, interface engineering and band gap engineering for enhancing the photocatalytic activity. An approach to recover the photocatalytic material via immobilization is also presented. This book brings to light much of the recent research in the development of such semiconductor photocatalytic systems. The book will thus be of relevance to researchers in the field of: material science, environmental science & technology, photocatalytic applications, newer methods of energy generation & conversion and industrial applications.
Download or read book TiO2 Photocatalysis written by Akira Fujishima and published by . This book was released on 1999 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book TiO2 Nanoparticles written by Aiguo Wu and published by John Wiley & Sons. This book was released on 2020-06-02 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: A unique book that summarizes the properties, toxicology, and biomedical applications of TiO2-based nanoparticles Nanotechnology is becoming increasingly important for products used in our daily lives. Nanometer-sized titanium dioxide (TiO2) are widely used in industry for different purposes, such as painting, sunscreen, printing, cosmetics, biomedicine, and so on. This book summarizes the advances of TiO2 based nanobiotechnology and nanomedicine, covering materials properties, toxicological research, and biomedical application, such as antibacter, biosensing, and cancer theranostics. It uniquely integrates the TiO2 applications from physical properties, toxicology to various biomedical applications, and includes black TiO2 based cancer theranostics. Beginning with a comprehensive introduction to the properties and applications of nanoparticles, TiO2 Nanoparticles: Applications in Nanobiotechnology, Theranostics and Nanomedicine offers chapters on: Toxicity of TiO2 Nanoparticles; Antibacterial Applications of TiO2 Nanoparticles; Surface Enhanced Raman Spectrum of TiO2 Nanoparticle for Biosensing (TiO2 Nanoparticle Served as SERS Sensing Substrate); TiO2 as Inorganic Photosensitizer for Photodynamic Therapy; Cancer Theranostics of Black TiO2 Nanoparticles; and Neurodegenerative Disease Diagnostics and Therapy of TiO2-Based Nanoparticles. This title: -Blends the physical properties, toxicology of TiO2 nanoparticles to the many biomedical applications -Includes black TiO2 based cancer theranostics in its coverage -Appeals to a broad audience of researchers in academia and industry working on nanomaterials-based biosensing, drug delivery, nanomedicine TiO2 Nanoparticles: Applications in Nanobiotechnology, Theranostics and Nanomedicine is an ideal book for medicinal chemists, analytical chemists, biochemists, materials scientists, toxicologists, and those in the pharmaceutical industry.
Download or read book Photocatalytic Degradation Process of Waste Water Using Titanium Dioxide as Catalyst written by Mohd Afendi Abdul Mutalib and published by . This book was released on 2009 with total page 51 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photocatalytic degradation is a process where the organic contaminant in water is degraded by UV light. UV photo oxidation acts to degrade and remove organic compound through the ultraviolet radiation to activate the catalyst. The catalyst used in this study is titanium dioxide (TiO2) which is chosen based on its properties that are low toxicity, low resistance to corrosion and semiconductor. The semiconductor will absorb the UV light and attract electrons across the energy gap into the conduction band. This electron will change into hydroxyl radicals which can decompose organic compounds while still in the waste water stream. So this is the basic concept that applied in industrial to treat the waste water or any pollutant in water in order to protect the environmental. Simulated oils waste water was used to replicate the Palm Oil Mill Effluent (POME). The studied parameters are the effect of catalyst concentration and irradiation time. The effect of both parameters has studied using Design Expert 7 to determine the optimum condition of degradation activities. The degradation activities were measured through the change of initial and final COD and dissolved oxygen in sample. Through Analysis of Variance (ANOVA) and optimization application of Design Expert 7, it was found that the optimum condition to achieve maximum degradation activities.-Author-
