Download or read book Development of an F element Separation Chemistry Using Solid Electrolytes written by Kristian Guy Myhre and published by . This book was released on 2016 with total page 145 pages. Available in PDF, EPUB and Kindle. Book excerpt: The f-elements (lanthanides and actinides) have numerous applications and are critically important to many industries, including the energy, security, and medical industries. One of the barriers to increased use and availability of the f-elements is the difficulty in separating them from each other due to their similar chemistries. This is especially true of the trivalent f-elements (lanthanides and minor actinides). The development of separation techniques that maximize the differences in the physicochemical properties of the f-elements is therefore an important area of research. For these reasons, an effort was undertaken to explore the use of solid electrolyte materials to accomplish separations of the f-elements. The results of this work have led to the development of a novel separation method at Oak Ridge National Laboratory for accomplishing f-element separations using inorganic solid electrolyte materials, specifically beta ́ ́-alumina. The use of beta ́ ́-alumina was both investigated both as an ion exchanger and selective membrane. Given the large dependence of superionic conductivity upon the valence of mobile ions, oxidation state control of the ions to be separated was explored. The high-temperature regimes (greater than 300°C) required for superionic conduction of multivalent metal ions in beta ́ ́-alumina necessitated the use of molten salts as a medium to contain ions to interact with the solid electrolyte. These studies also included the development of Laser Induced Breakdown Spectroscopy for determining the concentrations of f-elements in the alumina based materials

Download or read book Separations of f Elements written by Gregory R. Choppin and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: The symposium which provided the incentive for this volume was conducted in San th Diego, California as a part of the 207 National Meeting of the American Chemical Society, March 13-17, 1994. It was conceived partly to continue an informal decennial sequence of sym posia dedicated to the topic off element separations. A lot has changed in the world of f ele ments over the last ten years, precipitating a change in emphasis which should be evident to most practitioners in the field. Production and reprocessing of nuclear fuels are no longer the principal drivers of f element separation technology. Separations technology for environment restoration, waste disposal, and the preparation of high purity lanthanides are now the defming parameters in this important field. These imperatives are reflected in the contributions to this volume. The symposium itself must be considered a success, as the attendance at all sessions was above expectations, despite the fact that it was conducted on the last two days of a large five day meeting. Our thanks to the speakers for their quality presentations, and to the audience who persevered to the end of a long meeting and against the temptation of the excellent weather of San Diego in the springtime. A complete list of symposium participants is given in Appendix 1. Preparation of this volume has been a relatively painless undertaking, largely as a result ofthe high quality ofthe submitted papers.

Download or read book Aqueous Complexes in F element Separation Science written by and published by . This book was released on 1997 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt: Powerful and/or selective extractant molecules/sorbents are a necessary component of an efficient ion exchange or solvent extraction separation process. However, selectivity in extraction and efficiency in process design often rely on reactions occurring in or moderated by the aqueous medium. The focus of this report in on the role of the aqueous phase and reaction that occur in aquo in defining separation efficiency and metal ion selectivity. As the programmatic emphasis is on actinide solution chemistry, the separations chemistry of the f-elements will be used to illustrate the principal role of aqueous chemistry in separation science. Most of the arguments developed apply to metal ion separations chemistry and processes in general. The discussion will consider the application of aqueous complexants, incorporation of aqueous complexants into the extracted complex, and the effect of properties of the aqueous medium on separation efficiency and selectivity. Several historically important separations processes will be considered along with recent efforts in these laboratories to design and characterize new water soluble complexants for improved f-element separations.

Download or read book Inorganic Reactions and Methods Formation of Ceramics written by Jim D. Atwood and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 499 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kein anderes Werk bietet Ihnen diese Informationsfülle zu Reaktionen und Methoden der anorganischen Chemie in ähnlich einheitlicher, knapp zusammengefaßter, hervorragend organisierter Form! Neben Beiträgen aus allen Bereichen der anorganischen Chemie finden Sie in diesem Band eine tiefergehende Behandlung von Reaktionen zur Bindungsknüpfung, übersichtlich geordnet nach den beteiligten Elementen. Ein Verbindungsregister eröffnet Ihnen verschiedene Alternativen zum schnellen, zuverlässigen Auffinden von Informationen. (06/99)

Download or read book Fast Ion Transport in Solids written by B. Scrosati and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 375 pages. Available in PDF, EPUB and Kindle. Book excerpt: The main motivation for the organization of the Advanced Research Workshop in Belgirate was the promotion of discussions on the most recent issues and the future perspectives in the field of Solid State lonics. The location was chosen on purpose since Belgirate was the place were twenty years ago, also then under the sponsorship of NATO, the very first international meeting on this important and interdisciplinary field took place. That meeting was named "Fast Ion Transport in Solids" and gathered virtually everybody at that time having been active in any aspect of motion of ions in solids. The original Belgirate Meeting made for the first time visible the technological potential related to the phenomenon of the fast ionic transport in solids and, accordingly, the field was given the name "Solid State lonics". This field is now expanded to cover a wide range of technologies which includes chemical sensors for environmental and process control, electrochromic windows, mirrors and displays, fuel cells, high performance rechargeable batteries for stationary applications and electrotraction, chemotronics, semiconductor ionics, water electrolysis cells for hydrogen economy and other applications. The main idea for holding an anniversary meeting was that of discussing the most recent issues and the future perspectives of Solid State lonics just twenty years after it has started at the same location on the lake Maggiore in North Italy.

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1995 with total page 704 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Mass Spectrometry of Polymers written by Giorgio Montaudo and published by CRC Press. This book was released on 2001-10-29 with total page 601 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mass Spectrometry (MS) has rapidly become an indispensable tool in polymer analysis, and modern MS today complements in many ways the structural data provided by Nuclear Magnetic Resonance (NMR) and Infrared (IR) methods. Recent advances have sparked a growing interest in this field and established a need for a summary of progress made and results

Download or read book Journal of the Chemical Society written by Chemical Society (Great Britain) and published by . This book was released on 1925 with total page 1772 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Titles of chemical papers in British and foreign journals" included in Quarterly journal, v. 1-12.

Download or read book Energy Research Abstracts written by and published by . This book was released on 1988 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Fluorinated Materials for Energy Conversion written by Tsuyoshi Nakajima and published by Elsevier. This book was released on 2005-05-20 with total page 593 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fluorinated Materials for Energy Conversion offers advanced information on the application of fluorine chemistry to energy conversion materials for lithium batteries, fuel cells, solar cells and so on. Fluorine compounds and fluorination techniques have recently gained important roles in improving the electrochemical characteristics of such energy production devices. The book therefore focuses on new batteries with high performance, the improvements of cell performance and the improvement of electrode and cell characteristics. The authors present new information on the effect of fluorine and how to make use of fluorination techniques and fluorine compounds. With emphasis on recent developments, this book is suitable for students, researchers and engineers working in chemistry, materials science and electrical engineering. - Contains practical information, supported by examples - Provides an update on recent developments in the field - Written by specialists working in fluorine chemistry, electrochemistry, polymer and solid state chemistry

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1975-03 with total page 988 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Engineering Index written by John Butler Johnson and published by . This book was released on 1906 with total page 1266 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Energy Storage and Conversion Materials written by Ngoc Thanh Thuy Tran and published by CRC Press. This book was released on 2023-05-03 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explores the fundamental properties of a wide range of energy storage and conversion materials, covering mainstream theoretical and experimental studies and their applications in green energy. It presents a thorough investigation of diverse physical, chemical, and material properties of rechargeable batteries, supercapacitors, solar cells, and fuel cells, covering the development of theoretical simulations, machine learning, high-resolution experimental measurements, and excellent device performance. Covers potential energy storage (rechargeable batteries and supercapacitors) and energy conversion (solar cells and fuel cells) materials Develops theoretical predictions and experimental observations under a unified quasi-particle framework Illustrates up-to-date calculation results and experimental measurements Describes successful synthesis, fabrication, and measurements, as well as potential applications and near-future challenges Promoting a deep understanding of basic science, application engineering, and commercial products, this work is appropriate for senior graduate students and researchers in materials, chemical, and energy engineering and related disciplines.

Download or read book Handbook on the Physics and Chemistry of Rare Earths written by and published by Elsevier. This book was released on 2006-12-07 with total page 581 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume of the Handbook on the Physics and Chemistry of Rare Earth begins with a Dedication to late Professor LeRoy Eyring who had been a committed co-editor of the first 32 volumes of this series. This is followed by four chapters, the first two pertaining to solid state physics and materials science, while the last two chapters describe organic (and inorganic) reactions mediated by tetravalent cerium-based oxidants and by divalent samarium-based reductants. Chapter 227 is devoted to the description of the crystal chemistry and physical properties of rare-earth bismuthides, a class of compounds showing large similarities with the rare-earth antimonides previously reviewed in volume 33 of this series. The fascinating optical and electric properties of rare-earth hydride films displaying a switchable mirror effect as a function of hydrogen pressure, i.e. from a shiny metallic state to a transparent insulating film with increasing pressure, are described in Chapter 228, along with their fabrication methods. Many chemical reactions take advantage of the tetravalent/trivalent Ce(IV)/Ce(III) redox couple and many of its potential applications are presented in Chapter 229, from analytical procedures, to electrosynthesis, and organic and industrial (polymerization) reactions. The last review (Chapter 230) focuses on the synthesis and use of divalent samarium-based reductants in organic and inorganic reactions, mainly on those containing iodide and pentamethylcyclopentadienyl ligands.·Authoritative·Comprehensive·Up-to-date·Critical·Reliable

Download or read book Chemical News and Journal of Industrial Science written by and published by . This book was released on 1891 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Lithium ion Batteries written by Perla B. Balbuena and published by World Scientific. This book was released on 2004 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The SEI film is due to electromechanical reduction of species present in the electrolyte. It is widely recognized that the presence of the film plays an essential role in the battery performance, and its very nature can determine an extended (or shorter) life for the battery. In spite of the numerous related research efforts, details on the stability of the SEI composition and its influence on the battery capacity are still controversial. This book carefully analyzes and discusses the most recent findings and advances on this topic.

Download or read book Intermediate Temperature Solid Oxide Fuel Cells written by Gurbinder Kaur and published by Elsevier. This book was released on 2019-11-21 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intermediate Temperature Solid Oxide Fuel Cells: Electrolytes, Electrodes and Interconnects introduces the fundamental principles of intermediate solid oxide fuel cells technology. It provides the reader with a broad understanding and practical knowledge of the electrodes, pyrochlore/perovskite/oxide electrolytes and interconnects which form the backbone of the Solid Oxide Fuel Cell (SOFC) unit. Opening with an introduction to the thermodynamics, physiochemical and electrochemical behavior of Solid Oxide Fuel Cells (SOFC), the book also discusses specific materials, including low temperature brownmillerites and aurivillius electrolytes, as well as pyrochlore interconnects. This book analyzes the basic concepts, providing cutting-edge information for both researchers and students. It is a complete reference for Intermediate Solid Oxide Fuel Cells technology that will be a vital resource for those working in materials science, fuel cells and solid state chemistry. - Provides a single source of information on glass, electrolytes, interconnects, vanadates, pyrochlores and perovskite SOFC - Includes illustrations that provide a clear visual explanation of concepts being discussed - Progresses from a discussion of basic concepts that will enable readers to easily comprehend the subject matter