Download or read book Development and Mechanistic Understanding of Ball Milling as a Sustainable Alternative to Traditional Synthesis written by William C. Shearouse and published by . This book was released on 2012 with total page 175 pages. Available in PDF, EPUB and Kindle. Book excerpt: As environmental regulations become more stringent, the industrial chemical community needs methods that are sustainable, yet parallel the modern advances of organic synthesis. We believe we are solving the solution to this global problem through the development of sustainable synthesis that utilizes ball milling. Ball milling, unlike traditional synthetic methods, uses mechanical energy to drive organic reactions and transformations towards completion. Not only are we interested in finding reaction pathways that produce desired organic products in high yields, but also we are interested in understanding the mechanisms and theory of these processes in hopes that we may develop chemistries that have synthetic outcomes that are not attainable under traditional synthetic techniques. As a group, we each target different areas of "known" organic synthesis, in order to develop parallel routes that utilize sustainable, ball milling practices. Ball milling and green chemistry are introduced and described in Chapter 1. This dissertation describes specifically my efforts towards the aforementioned goals. Largely, my efforts focused on the development of sustainable olefination reactions, namely, the Wittig reaction and Horner-Wadsworth-Emmons reactions described in Chapters 3 and 4 respectively. In addition, portions of my dissertation research sought to expand the capability of ball milling reactions through the engineering and development of new ball milling tools. The use of functional resins as purification tools for ball milling reactions, described in Chapter 5, as well as the design and fabrication of vials made from different materials, described in Chapter 2, complete my dissertation research.
Download or read book Ball Milling Towards Green Synthesis written by Brindaban Ranu and published by Green Chemistry. This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ball Milling Towards Green Synthesis will introduce practicing chemists to the technique and will highlight its importance for green transformations.
Download or read book Mechanochemical Organic Synthesis written by Davor Margetic and published by Elsevier. This book was released on 2016-04-23 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mechanochemical Organic Synthesis is a comprehensive reference that not only synthesizes the current literature but also offers practical protocols that industrial and academic scientists can immediately put to use in their daily work. Increasing interest in green chemistry has led to the development of numerous environmentally-friendly methodologies for the synthesis of organic molecules of interest. Amongst the green methodologies drawing attention, mechanochemistry is emerging as a promising method to circumvent the use of toxic solvents and reagents as well as to increase energy efficiency. The development of synthetic strategies that require less, or the minimal, amount of energy to carry out a specific reaction with optimum productivity is of vital importance for large-scale industrial production. Experimental procedures at room temperature are the mildest reaction conditions (essentially required for many temperature-sensitive organic substrates as a key step in multi-step sequence reactions) and are the core of mechanochemical organic synthesis. This green synthetic method is now emerging in a very progressive manner and until now, there is no book that reviews the recent developments in this area. - Features cutting-edge research in the field of mechanochemical organic synthesis for more sustainable reactions - Integrates advances in green chemistry research into industrial applications and process development - Focuses on designing techniques in organic synthesis directed toward mild reaction conditions - Includes global coverage of mechanochemical synthetic protocols for the generation of organic compounds
Download or read book Catalysis written by James J Spivey and published by Royal Society of Chemistry. This book was released on 2021-06-14 with total page 494 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume looks at modern approaches to catalysis and reviews the extensive literature. Chapters highlight application of 2D materials in biomass conversion catalysis, plasmonic photocatalysis, catalytic demonstration of mesoporosity in the hierarchical zeolite and the effect of surface phase oxides on supported metals and catalysis. Looking to the future a chapter on ab initio machine learning for accelerating catalytic materials discovery is included. Appealing broadly to researchers in academia and industry, these illustrative chapters bridge the gap from academic studies in the laboratory to practical applications in industry not only for catalysis field but also for environmental protection. Other chapters with an industrial perspective include heterogeneous and homogeneous catalytic routes for vinyl acetate synthesis, catalysis for production of jet fuel from renewable sources by HDO/HDC and microwave-assisted catalysis for fuel conversion. Chemical reactions in ball mills is also explored. The book will be of great benefit to any researcher wanting a succinct reference on developments in this area now and looking to the future.
Download or read book Mechanochemistry in Nanoscience and Minerals Engineering written by Peter Balaz and published by Springer Science & Business Media. This book was released on 2008-10-20 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mechanochemistry as a branch of solid state chemistry enquires into processes which proceed in solids due to the application of mechanical energy. This provides a thorough, up to date overview of mechanochemistry of solids and minerals. Applications of mechanochemistry in nanoscience with special impact on nanogeoscience are described. Selected advanced identification methods, most frequently applied in nanoscience, are described as well as the advantage of mechanochemical approach in minerals engineering. Examples of industrial applications are given. Mechanochemical technology is being applied in many industrial fields: powder metallurgy (synthesis of nanometals, alloys and nanocompounds), building industry (activation of cements), chemical industry (solid waste treatment, catalyst synthesis, coal ashes utilization), minerals engineering (ore enrichment, enhancement of processes of extractive metallurgy), agriculture industry (solubility increase of fertilizers), and pharmaceutical industry (improvement of solubility and bioavailability of drugs). This reference serves as an introduction to newcomers to mechanochemistry, and encourages more experienced researchers to broaden their knowledge and discover novel applications in the field.
Download or read book Metal Oxide Nanocomposites written by B. Raneesh and published by John Wiley & Sons. This book was released on 2021-02-17 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxide Nanocomposites: Synthesis and Applications summarizes many of the recent research accomplishments in the area of metal oxide-based nanocomposites. This book focussing on the following topics: Nanocomposites preparation and characterization of metal oxide nanocomposites; synthesis of core/shell metal oxide nanocomposites; multilayer thin films; sequential assembly of nanocomposite materials; semiconducting polymer metal oxide nanocomposites; graphene-based metal and metal oxide nanocomposites; carbon nanotube–metal–oxide nanocomposites; silicon mixed oxide nanocomposites; gas semiconducting sensors based on metal oxide nanocomposites; metal ]organic framework nanocomposite for hydrogen production and nanocomposites application towards photovoltaic and photocatalytic.
Download or read book High Energy Ball Milling written by Małgorzata Sopicka-Lizer and published by Elsevier. This book was released on 2010-05-24 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mechanochemical processing is a novel and cost effective method of producing a wide range of nanopowders. It involves the use of a high energy ball mill to initiate chemical reactions and structural changes. High energy ball milling: Mechanochemical processing of nanopowders reviews the latest techniques in mechanochemistry and how they can be applied to the synthesis and processing of various high-tech materials.Part one discusses the basic science of mechanochemistry with chapters on such topics as the mechanism and kinetics of mechanochemical processes, kinetic behaviour in mechanochemically-induced structural and chemical transformations and materials design through mechanochemical processing. Part two reviews mechanochemical treatment of different materials including synthesis of complex ceramic oxides, production of intermetallic compound powders, synthesis of organic compounds, synthesis of metallic-ceramic composite powders and activation of covalent bond-based materials. Part three covers mechanochemical processes in metal powder systems and other applications with coverage of topics such as plating and surface modification using ultrasonic vibrations, activated powders as precursors for spark plasma sintering, titanium dioxide photocatalyst synthesis by mechanochemical doping and synthesis of materials for lithium-ion batteries.With its distinguished editor and international team of contributors, High energy ball milling: Mechanochemical processing of nanopowders is a standard reference for all those involved in the production of ceramic and metallic components using sintering and other powder metallurgy techniques to produce net shape components. - Examines the latest techniques in mechanochemistry and how they can be applied to the synthesis and processing of various high-tech materials - Discusses the basic science of mechanochemistry including kinetic behaviour, processes and mechanisms and materials design through mechanochemical processing - Reviews mechanochemical treatment of different materials including synthesis of ceramic oxides, organic compounds and metallic-ceramic composite powders
Download or read book Green Techniques for Organic Synthesis and Medicinal Chemistry written by Wei Zhang and published by John Wiley & Sons. This book was released on 2018-01-18 with total page 1127 pages. Available in PDF, EPUB and Kindle. Book excerpt: An updated overview of the rapidly developing field of green techniques for organic synthesis and medicinal chemistry Green chemistry remains a high priority in modern organic synthesis and pharmaceutical R&D, with important environmental and economic implications. This book presents comprehensive coverage of green chemistry techniques for organic and medicinal chemistry applications, summarizing the available new technologies, analyzing each technique’s features and green chemistry characteristics, and providing examples to demonstrate applications for green organic synthesis and medicinal chemistry. The extensively revised edition of Green Techniques for Organic Synthesis and Medicinal Chemistry includes 7 entirely new chapters on topics including green chemistry and innovation, green chemistry metrics, green chemistry and biological drugs, and the business case for green chemistry in the generic pharmaceutical industry. It is divided into 4 parts. The first part introduces readers to the concepts of green chemistry and green engineering, global environmental regulations, green analytical chemistry, green solvents, and green chemistry metrics. The other three sections cover green catalysis, green synthetic techniques, and green techniques and strategies in the pharmaceutical industry. Includes more than 30% new and updated material—plus seven brand new chapters Edited by highly regarded experts in the field (Berkeley Cue is one of the fathers of Green Chemistry in Pharma) with backgrounds in academia and industry Brings together a team of international authors from academia, industry, government agencies, and consultancies (including John Warner, one of the founders of the field of Green Chemistry) Green Techniques for Organic Synthesis and Medicinal Chemistry, Second Edition is an essential resource on green chemistry technologies for academic researchers, R&D professionals, and students working in organic chemistry and medicinal chemistry.
Download or read book Soft Mechanochemical Synthesis written by G.V. Avvakumov and published by Springer Science & Business Media. This book was released on 2007-05-08 with total page 211 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mechanical methods of the activation of chemical processes are currently widely used for the synthesis of various compounds. The present monograph deals with the development of a novel approach to mechanochemical synthesis based on reactions of solid acids, bases, hydrated compounds, crystal hydrates, basic and acidic salts. This method has been called soft mechanochemical synthesis. The monograph includes the papers published by the present authors. They describe the results of their investigations n the last two decades. New theoretical and experimental data on kinetics and mechanism of soft mechanochemical reactions in the mixtures of compounds mentioned above to give complex oxide compounds are presented. The description of new high energetic and high efficient mills providing effective occurrence of these reactions is delivered. The possibilities of applying soft mechanochemical synthesis for materials used in catalysts, material science, electronics, etc., are discussed. The advantages of the method proposed in comparison with other methods are demonstrated. The monograph is designed for researchers, engineers and technicians engaged in chemical and ceramic industry, for scientists and students specialized in the area of development, and application of new materials.
Download or read book Organic Synthesis written by Belakatte Parameshwarappa Nandeshwarappa and published by BoD – Books on Demand. This book was released on 2020-05-27 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book ‘Organic Synthesis - A Nascent Relook’ is a compendium of the recent progress in all aspects of organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic, green chemistry and medicinal chemistry, polymer chemistry, as well as analytical methods in organic chemistry. The book presents the latest developments in these fields. The chapters are written by chosen experts who are internationally known for their eminent research contributions. Organic synthesis is the complete chemical synthesis of a target molecule. In this book, special emphasis is given to the synthesis of various bioactive heterocycles. Careful selection of various topics in this book will serve the rightful purpose for the chemistry community and the industrial houses at all levels.
Download or read book Polymer Mechanochemistry written by Roman Boulatov and published by Springer. This book was released on 2015-10-17 with total page 443 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.
Download or read book Solvent free Organic Synthesis written by Koichi Tanaka and published by John Wiley & Sons. This book was released on 2009-03-02 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this second edition of a best-selling handbook all the chapters have been completely revised and updated, while four completely new chapters have been added. In order to meet the needs of the practitioner, emphasis is placed on describing precisely the technology and know-how involved. Adopting a didactic and comprehensible approach, the book guides the reader through theory and applications, thus ensuring its warm welcome among the scientific community. An excellent, essential and exhaustive overview.
Download or read book Bimetallic Catalysts written by John H. Sinfelt and published by Wiley-Interscience. This book was released on 1983-09-29 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents an account of the research on bimetallic catalysts. Focuses attention on the possibility of influencing the selectivity of chemical transformations on metal surfaces and preparing metal alloys in a highly dispersed state. Covers the validation and elucidation of the bimetallic cluster concept. Includes figures and tables.
Download or read book Sustainable Organic Synthesis written by Dr Stefano Protti and published by Royal Society of Chemistry. This book was released on 2021-10-29 with total page 602 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent years have seen huge growth in the area of sustainable chemistry. In order to meet the chemical needs of the global population whilst minimising impacts on health and the environment it is essential to keep reconsidering and improving synthetic processes. Sustainable Organic Synthesis is a comprehensive collection of contributions, provided by specialists in Green Chemistry, covering topics ranging from catalytic approaches to benign and alternative reaction media, and innovative and more efficient technologies.
Download or read book Tribochemistry written by Gerqard Heinicke and published by Oxford University Press, USA. This book was released on 1988-05-12 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides a comprehensive introduction to the scientific and technical aspects of tribochemistry, a field concerned with the chemical reactions initiated by mechanical energy. The relevant theoretical background, recent innovations and results, and the possibilities of expanding industrial applications are covered.
Download or read book Biochar for Environmental Management written by Dr. Johannes Lehmann and published by Earthscan. This book was released on 2009 with total page 449 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Biochar is the carbon-rich product when biomass (such as wood, manure, or crop residues) is heated in a closed container with little or no available air. It can be used to improve agriculture and the environment in several ways, and its stability in soil and superior nutrient-retention properties make it an ideal soil amendment to increase crop yields. In addition to this, biochar sequestration, in combination with sustainable biomass production, can be carbon-negative and therefore used to actively remove carbon dioxide from the atmosphere, with major implications for mitigation of climate change. Biochar production can also be combined with bioenergy production through the use of the gases that are given off in the pyrolysis process.This book is the first to synthesize the expanding research literature on this topic. The book's interdisciplinary approach, which covers engineering, environmental sciences, agricultural sciences, economics and policy, is a vital tool at this stage of biochar technology development. This comprehensive overview of current knowledge will be of interest to advanced students, researchers and professionals in a wide range of disciplines"--Provided by publisher.
Download or read book Biomass Fractionation Technologies for a Lignocellulosic Feedstock Based Biorefinery written by S.I. Mussatto and published by Elsevier. This book was released on 2016-02-18 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomass Fractionation Technologies for a Lignocellulosic Feedstock-based Biorefinery reviews the extensive research and tremendous scientific and technological developments that have occurred in the area of biorefinering, including industrial processes and product development using ‘green technologies’, often referred as white biotechnology. As there is a huge need for new design concepts for modern biorefineries as an alternative and amendment to industrial crude oil and gas refineries, this book presents the most important topics related to biomass fractionation, including advances, challenges, and perspectives, all with references to current literature for further study. Presented in 26 chapters by international field specialists, each chapter consists of review text that comprises the most recent advances, challenges, and perspectives for each fractionation technique. The book is an indispensable reference for all professionals, students, and workers involved in biomass biorefinery, assisting them in establishing efficient and economically viable process technologies for biomass fractionation. Provides information on the most advanced and innovative pretreatment processes and technologies for biomass Reviews numerous valuable products from lignocellulose Discusses integration of processes for complete biomass conversion with minimum waste generation Identifies the research gaps in scale-up Presents an indispensable reference for all professionals, students, and workers involved in biomass biorefinery, assisting them in establishing efficient and economically viable process technologies for biomass fractionation
