Download or read book Deuterium isotope effects in photochemical 1 5 hydrogen shift written by James Plott Roberts and published by . This book was released on 1976 with total page 144 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Deuterium and Shift Calculation written by U. Fleischer and published by Springer. This book was released on 1991 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1931 Vrey, Brickwedde, and Murphy discovered the hydrogen isotope deuterium. The isotopic enrichment was found to arise from the fact that the electrolysis oflight water is faster than of heavy water [1,2]. This success showed that although different isotopes of an element behave identically from a chemical standpoint the different isotopic masses nevertheless lead to both isotope effects on equilibrium as well as on rate constants of chemical reactions. Soon, ratios of equilibrium constants of isotopic reactions were called "equilibrium isotope effects" (EIE), ratios of isotopic rate constants "kinetic isotope effects" (KIE). Isotope effects have been found to be especially large for those elements which are directly involved in bond breaking and bond formation during the reaction studied [3]. Such effects are, therefore, referred to as "primary". Isotopic substitution in atomic sites which maintain all chemical bonds with their neighbors during the reaction of interest leads then only to smaller "secondary" isotope effects. Because of the unique mass relation between the different hydrogen isotopes hydrogen/deuterium isotope effects are particularly large and have attracted most attention. The largest contributions to these effects arise from changes in the vibrational frequencies of the reactants. The theory of equilibrium isotope effects has been founded by Vrey [4] and Bigeleisen [5,6] and has widely been accepted [3].

Download or read book Deuterium Isotope Effects on the Carbon 13 Chemical Shifts of Carbocations written by Venchei Edward Koh and published by . This book was released on 1989 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Entropic control of photochemical reactivity and deuterium isotope effects in the Norrish Type II reaction of Aryl Alkyl Ketones written by Daniel Richard Kory and published by . This book was released on 1974 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Deuterium Isotope Effects in Chemistry and Biology written by David Kritchevsky and published by . This book was released on 1960 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Masters Theses in the Pure and Applied Sciences written by Wade H. Shafer and published by Springer Science & Business Media. This book was released on 2013-11-21 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: Masters Theses in the Pure and Applied Sciences was first conceived, published, and dis seminated by the Center for lnformation and Numerica/ Data Analysis and Synthesis (C/NDAS) * at Purdue University in 1957, starting its coverage of theses with the academic year 1955. Beginning with Volume 13, the printing and dissemination phases of the ac tivity were transferred to University Microfilms/Xerox of Ann Arbor, Michigan, with the thought that such an arrangement would be more beneficia! to the academic and general scientific and technical community. After fi ve years of this joint undertaking we had concluded that it was in the interest of ali concerned if the printing and distribution of the volume were handled by an international publishing house to assure improved service and broader dissemination. Hence, starting with Volume 18, Masters Theses in the Pure and App/ied Sciences has been disseminated on a worldwide basis by Plenum Publishing Corporation of New York, and in the same year the coverage was broadened to include Canadian universities. Ali back issues can also be ordered from Plenum. We have reported in Volume 21 (thesis year 1976) a total of 10,586 theses titles from 25 Canadian and 219 United States universities. We are sure that this broader base for theses titles reported will greatly enhance the value of this important annual reference work.

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1976 with total page 658 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Bibliography of Mass Spectroscopy Literature for 1971 written by and published by . This book was released on 1973 with total page 626 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Photochromism Molecules and Systems written by Heinz Dürr and published by Elsevier. This book was released on 2003-03-12 with total page 1221 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photochromism is simply defined as the light induced reversible change of colour. The field has developed rapidly during the past decade as a result of attempts to improve the established materials and to discover new devices for applications.As photochromism bridges molecular, supramolecular and solid state chemistry, as well as organic, inorganic and physical chemistry, such a treatment requires a multidisciplinary approach and a broad presentation. The first edition (1990) provided an enormous amount of new concepts and data, such as the presentation of main families based on the pericyclic reaction mechanism, the review of new families, some bimolecular photocycloadditions and some promising systems. This new edition provides an efficient entry into this flourishing field, with the core content retained from the original work to provide a basic introduction into the different subjects. *Second edition of a work first published in 1990, now revised due to constant development of research. *Including updated lists of references (1989-2001), offering immediate access to recent developments.*Providing great basic interest and high application potential bringing scientists together from chemistry, physics and engineering.

Download or read book Isotopes in Molecular Rearrangements written by E. Buncel and published by Elsevier Science & Technology. This book was released on 1975 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Bibliography of Mass Spectroscopy Literature for 1970 written by and published by . This book was released on 1972 with total page 900 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Hydrogen Deuterium Isotope Effects in Electrochemical Proton Transfer written by Mark Salomon and published by . This book was released on 1964 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Energy Research Abstracts written by and published by . This book was released on 1980 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Catalog of National Bureau of Standards Publications 1966 1976 written by United States. National Bureau of Standards. Technical Information and Publications Division and published by . This book was released on 1978 with total page 844 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1974 with total page 1036 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Catalog of National Bureau of Standards Publications 1966 1976 written by United States. National Bureau of Standards and published by . This book was released on 1978 with total page 844 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book INIS Atomindex written by and published by . This book was released on 1985 with total page 1526 pages. Available in PDF, EPUB and Kindle. Book excerpt: