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Book Determination of the Thermodynamic Properties of Liquid Metal Solutions at High Temperatures

Download or read book Determination of the Thermodynamic Properties of Liquid Metal Solutions at High Temperatures written by S. K. Tarby and published by . This book was released on 1968 with total page 37 pages. Available in PDF, EPUB and Kindle. Book excerpt: The transportation method was used to determine the vapor pressure of silver above pure liquid silver and above molten Ag-Si alloys in the temperature range of 1450 to 1600C. The experimental values of the vapor pressure of pure liquid silver were related to temperature and a complete thermodynamic description of liquid Ag-Si alloys was achieved. (Author).

Book Thermodynamic Properties of Liquid Metal Solutions in the Cesium mercury System

Download or read book Thermodynamic Properties of Liquid Metal Solutions in the Cesium mercury System written by Albert Cornelius Antoine and published by . This book was released on 1969 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermodynamic properties of liquid cesium-mercury solutions.

Book Research in Progress

Download or read book Research in Progress written by and published by . This book was released on 1967 with total page 756 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book The Thermophysical Properties of Metallic Liquids

Download or read book The Thermophysical Properties of Metallic Liquids written by Takamichi Iida and published by Oxford University Press. This book was released on 2015-10-15 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first volume provides the basic matters needed for understanding the thermophysical properties of metallic liquids and for developing reliable models to accurately predict the thermophysical properties of almost all metallic elements in the liquid state, together with methods for quantitative assessment of models/equations. The authors also review the structure of metallic liquids, which is based on the theory of liquids, followed by density, volume expansivity, thermodynamic properties (evaporation enthalpy, vapour pressure, heat capacity), sound velocity, surface tension,viscosity, diffusion, and electrical and thermal conductivities. Finally, the essential points of methods used for measuring these experimental data are presented.

Book Thermodynamic Properties of Liquid Metal Solutions in the Cesium mercury System

Download or read book Thermodynamic Properties of Liquid Metal Solutions in the Cesium mercury System written by Albert C. Antoine and published by . This book was released on 1969 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Scientific and Technical Aerospace Reports

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1987 with total page 1390 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.

Book Aqueous Systems at Elevated Temperatures and Pressures

Download or read book Aqueous Systems at Elevated Temperatures and Pressures written by Roberto Fernandez-Prini and published by Elsevier. This book was released on 2004-07-06 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: The International Association for the Properties of Water and Steam (IAPWS) has produced this book in order to provide an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures. These systems are central to many areas of scientific study and industrial application, including electric power generation, industrial steam systems, hydrothermal processing of materials, geochemistry, and environmental applications. The authors’ goal is to present the material at a level that serves both the graduate student seeking to learn the state of the art, and also the industrial engineer or chemist seeking to develop additional expertise or to find the data needed to solve a specific problem. The wide range of people for whom this topic is important provides a challenge. Advanced work in this area is distributed among physical chemists, chemical engineers, geochemists, and other specialists, who may not be aware of parallel work by those outside their own specialty. The particular aspects of high-temperature aqueous physical chemistry of interest to one industry may be irrelevant to another; yet another industry might need the same basic information but in a very different form. To serve all these constituencies, the book includes several chapters that cover the foundational thermophysical properties (such as gas solubility, phase behavior, thermodynamic properties of solutes, and transport properties) that are of interest across numerous applications. The presentation of these topics is intended to be accessible to readers from a variety of backgrounds. Other chapters address fundamental areas of more specialized interest, such as critical phenomena and molecular-level solution structure. Several chapters are more application-oriented, addressing areas such as power-cycle chemistry and hydrothermal synthesis. As befits the variety of interests addressed, some chapters provide more theoretical guidance while others, such as those on acid/base equilibria and the solubilities of metal oxides and hydroxides, emphasize experimental techniques and data analysis. - Covers both the theory and applications of all Hydrothermal solutions - Provides an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures - The presentation of the book is understandable to readers from a variety of backgrounds

Book Measurement of Thermal Properties of Solid and Liquid Metals at High Temperatures

Download or read book Measurement of Thermal Properties of Solid and Liquid Metals at High Temperatures written by Lev Petrovich Filippov and published by . This book was released on 1969* with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Measurement of Thermal Properties of Solid and Liquid Metals at High Temperatures

Download or read book Measurement of Thermal Properties of Solid and Liquid Metals at High Temperatures written by L. P. Filippov and published by . This book was released on 1969 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: General problems of the procedure and the experimental technique; Steady methods for measuring the heat conductivity of metals; Non-steady methods for measuring thermal properties; Heat capacity of metals; Heat conductivity of metals.

Book Chemical and Thermodynamic Properties at High Temperatures

Download or read book Chemical and Thermodynamic Properties at High Temperatures written by Congrès international de chimie pure et appliquée and published by . This book was released on 1961 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Handbook of Thermophysical Properties of Metals at High Temperatures

Download or read book Handbook of Thermophysical Properties of Metals at High Temperatures written by Vladislav Evgenʹevich Zinovʹev and published by . This book was released on 1996 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt: A compendium of findings about such characteristics of metals at high temperature as density, thermal expansion, heat capacity, diffusivity, elastic properties, transport coefficients, electrical resistance, thermal conductivity, absolute thermoelectric power, and the Hall coefficient. After explain

Book Determination of Fundamental Thermodynamic Properties of Alkali Alkaline Earth Elements in Liquid Metals for Recovery from Molten Salt Solutions

Download or read book Determination of Fundamental Thermodynamic Properties of Alkali Alkaline Earth Elements in Liquid Metals for Recovery from Molten Salt Solutions written by Nathan Douglas Smith and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In the nuclear industry, uranium is recovered from used nuclear fuel using a process known as electrorefining in which a metallic used nuclear fuel anode is oxidized into molten LiCl-KCl-UCl3 electrolyte and pure U is preferentially reduced onto an inert cathode. While electrorefiner systems facilitate the recycling of substantial amounts of uranium from used nuclear fuel, they also contribute to the production of nuclear waste due to the build-up of dangerous elements including 90Sr and 137Cs in the molten salt electrolyte as they are more active in the salt than U and will therefore oxidize out of the anode before U. The accumulation of Sr and Cs in the electrolyte presents a problem as Sr and Cs isotopes have high heat densities and produce large amounts of highly ionizing radiation; these hazards combined with difficulty in removing the highly stable Sr and Cs from the electrolyte necessitates frequent replacement and disposal of the electrolyte, which then contributes to the overall volume of nuclear waste. This dissertation focuses on evaluating the viability of using liquid metal electrodes as a method for electrochemical separation of Sr and Cs from LiCl-KCl-based molten salts due to their strong atomic interactions with alkali/alkaline-earth elements, which cause a shift in relative stability of the alkali/alkaline-earths in the electrolyte. Thermodynamic properties, including activities, partial molar entropies, and partial molar enthalpies, were determined using electromotive force measurements for the Sr-Bi, Sr-Sb, and Sr-Sn binary systems in order to elucidate the strength of interactions between Sr and each liquid metal. By combining the fundamental thermochemical data with phase characterization of each of the binary systems using X-ray diffraction (XRD) and differential scanning calorimetry (DSC), a comprehensive understanding of both thermodynamic phase behavior was developed for all three binary systems. Activities as low as aSr = 10-13 at xSr = 0.04 at T = 888 K were measured as well as liquid state solubilities as high as 40 mol% at 988 K. Experimental data was used as input data towards computational efforts involving first-principles calculations as well as the CALPHAD technique in the case of the Sr-Sb system to develop an improved Sr-Sb phase diagram and provide further basis for the use of computational models in elucidating strongly interacting binary systems. Attempts to remove Sr from molten salt electrolyte using an electrochemical cell with liquid metal (Bi, Sb, Sn) cathodes were successful, with post-mortem elemental analysis of the electrodes confirming significant quantities of Sr (4.0-6.5 mol%) deposited into Bi and Sb. Furthermore, deposition results correlated well with the deposition behavior predicted from the aforementioned electromotive force measurements, inviting the possibility of using liquid metal electrodes as a method for selectively removing Sr from molten LiCl-KCl electrolyte and for reducing the total volume of nuclear waste left accumulating in on-site repositories throughout the US.

Book Nuclear Science Abstracts

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1975-03 with total page 988 pages. Available in PDF, EPUB and Kindle. Book excerpt: