Download or read book Detection of Polycyclic Aromatic Hydrocarbons in an Axisymmetric Laminar diffusion Methane air Flame Through Measurements of Visible Laser induced Fluorescence written by Maximino Dufflocq FLores and published by . This book was released on 1988 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Laser induced Fluorescence Measurements of Vapor phase Polycyclic Aromatic Hydrocarbons I Evaluation of One and Two photon Excitation Processes for Mixture Analysis II Flame Temperature Measurements Using the Anomalous Fluorescence of Pyrene written by Diane LeAnna Peterson and published by . This book was released on 1988 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Laser Induced Fluorescence Measurements and Modeling of Nitric Oxide in Counterflow Diffusion Flames written by National Aeronautics and Space Administration (NASA) and published by Createspace Independent Publishing Platform. This book was released on 2018-06-27 with total page 202 pages. Available in PDF, EPUB and Kindle. Book excerpt: The feasibility of making quantitative nonintrusive NO concentration ([NO]) measurements in nonpremixed flames has been assessed by obtaining laser-induced fluorescence (LIF) measurements of [NO] in counterflow diffusion flames at atmospheric and higher pressures. Comparisons at atmospheric pressure between laser-saturated fluorescence (LSF) and linear LIF measurements in four diluted ethane-air counterflow diffusion flames with strain rates from 5 to 48/s yielded excellent agreement from fuel-lean to moderately fuel-rich conditions, thus indicating the utility of a model-based quenching correction technique, which was then extended to higher pressures. Quantitative LIF measurements of [NO] in three diluted methane-air counterflow diffusion flames with strain rates from 5 to 35/s were compared with OPPDIF model predictions using the GRI (version 2.11) chemical kinetic mechanism. The comparisons revealed that the GRI mechanism underpredicts prompt-NO by 30-50% at atmospheric pressure. Based on these measurements, a modified reaction rate coefficient for the prompt-NO initiation reaction was proposed which causes the predictions to match experimental data. Temperature measurements using thin filament pyrometry (TFP) in conjunction with a new calibration method utilizing a near-adiabatic H2-air Hencken burner gave very good comparisons with model predictions in these counterflow diffusion flames. Quantitative LIF measurements of [NO] were also obtained in four methane-air counterflow partially-premixed flames with fuel-side equivalence ratios (phi(sub B)) of 1.45, 1.6, 1.8 and 2.0. The measurements were in excellent agreement with model predictions when accounting for radiative heat loss. Spatial separation between regions dominated by the prompt and thermal NO mechanisms was observed in the phi(sub B) = 1.45 flame. The modified rate coefficient proposed earlier for the prompt-NO initiation reaction improved agreement between code predictions and measurements in the re

Download or read book Laser Imaging of Chemistry flowfield Interactions written by Joel E. Harrington and published by . This book was released on 19?? with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt: Models of detailed flame chemistry and soot formation are based upon experimental results obtained in steady, laminar flames. For successful application of these descriptions to turbulent combustion, it is instructive to test predictions against measurements in time-varying flowfields. This paper reports the use of optical methods to examine soot production and oxidation processes in a co-flowing, axisymmetric CH(4)/air diffusion flame in which the fuel flow rate is acoustically forced to create a time-varying flowfield. For a particular forcing condition in which tip clipping occurs (0.75 V loudspeaker excitation), elastic scattering of vertically polarized light from the soot particles increases by nearly an order of magnitude with respect to that observed for a steady flame with the same mean fuel flow rate. The visible flame luminosity and laser-induced fluorescence attributed to polycyclic aromatic hydrocarbons (PAH) are also enhanced. Peak soot volume fractions, as measured by time-resolved laser extinction/tomography at 632.8 and 454.5 mm and calibrated laser-induced incandescence (LII), show a factor of 4-5 enhancement in this flickering flame. The LII method is found to track the soot volume fraction closely and to give better signal-to-noise than the extinction measurements in both the steady and time-varying flowfields. A Mie analysis suggests that most of the enhanced soot production results from the formation of larger particles in the time-varying flowfield.

Download or read book The Application of Laser Diagnostics to the Measurement of Concentration and Temperature in Practical Methane air Flames written by Quang-Viet Nguyen and published by . This book was released on 1995 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Investigation of Premixed Sooting Flames by Combined Laser Induced Incandescence and Laser Induced Fluorescence written by Jaclyn Dunn and published by . This book was released on 2013 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This study applies the techniques of laser induced incandescence (LII) and laser induced fluorescence (LIF) to investigate laminar sooting flames of premixed ethylene air. The approach involves using three different excitation wavelengths, together with temporally and spectrally resolved detection, generating a rich dataset concerning the formation of soot and polycyclic aromatic hydrocarbons (PAHs). Both prompt and delayed detection are used to perform LII when exciting with short wavelengths, both with issues involved. Delayed detection gives an underestimation of soot volume fraction at low heights in the flame, as a result of particle size effects. Prompt detection gives overestimation of soot volume fraction due to fluorescence in the measurement volume. It is shown that care must be taken with either method and through evaluation of the associated errors this study shows delayed detection provides a more accurate measure of soot volume fraction. The ability to obtain the fluorescence signals over a range of heights above burner and stoichiometries is demonstrated. The approach relies on heating the soot particles equivalently with three excitation wavelengths so the LII contribution to the signals can be subtracted, leaving only fluorescence. Fluorescence profiles obtained show similar features to those seen in the literature for invasive measurements, including a reduction in the fluorescence signal generated by 283 nm excitation at intermediate heights above the burner surface followed by a re-increase. Although the data do not allow species-selective measurements of PAHs, these in-situ measurements allow inferences to be drawn about changing concentration of different size classes of these precursors to soot formation. Finally the method of obtaining subtracting the LII contribution to signals was used to obtain fluorescence spectra both for 283 nm and 532 nm excitation. This showed the possibility that fluorescence can yield useful information that it is otherwise impossible to obtain in-situ under sooting conditions.

Download or read book Laser Induced Fluorescence Study of the Heterogeneous Interaction of Polycyclic Aromatic Hydrocarbons with Aqueous Surfaces microform Adsorption and Reaction with Gas phase Ozone written by Baagi Thema Mmereki and published by Library and Archives Canada = Bibliothèque et Archives Canada. This book was released on 2005 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: We have also measured the kinetics and products of a reaction between gas-phase ozone and anthracene adsorbed at the air-aqueous interface. The reactions at the "uncoated" air-water interface and at an interface consisting of a monolayer of various organic compounds were studied. In all the cases, the reaction follows a Langmuir-Hinshelwood mechanism, in which ozone first adsorbs to the air-aqueous interface, and then reacts with adsorbed anthracene. For typical atmospheric ozone concentrations, the estimated reactive uptake coefficient ranges from 2 x 10-8 to 3 x 10-7 depending on the nature of the air-aqueous interface. Smaller (C4, C6) carboxylic acids at the interface inhibit the reaction (compared to the "clean" water surface); 1-octanol enhances it. Under some circumstances, oxidation by ozone on aqueous surfaces may be more important in the atmosphere than gas phase oxidation by OH radicals. The fate of atmospheric semi-volatile organic compounds (SOCs) such as polycyclic aromatic hydrocarbons (PAHs) depends, in part, on their distribution between the gas phase and particulate phases, and oxidation reactions. In the daytime troposphere, photochemically produced OH radicals dominate these reactions, whereas chlorine atoms may contribute to the oxidation of certain PAHs in coastal areas. In the dark, oxidation by nitrate radicals (NO3) may also be important, whereas ozone can contribute to the oxidation both during the day and at night. We have developed a laser-induced fluorescence (LIF) method to study adsorption and oxidation of PAHs at the air-aqueous interface. This method allows to directly probe the mechanisms and extent of PAH uptake on aqueous surfaces. The kinetics of the adsorption of anthracene and pyrene onto "pure" water and water coated with an organic film were measured. The surface uptake coefficients of both PAHs are estimated to be on the order of 10-5, and increase by a factor of 2--3 for uptake to the 1-octanol coated water surface. However, the surface uptake of pyrene to a hexanoic-acid-coated aqueous surface does not display this enhancement. Resolved fluorescence spectra of pyrene adsorbed onto 1-octanol-coated surfaces indicate that pyrene is in a less polar environment than when adsorbed at the hexanoic-acid-coated surfaces.

Download or read book Laser saturated Fluorescence Measurements in Laminar Sooting Diffusion Flames written by Changlie Wey and published by . This book was released on 1993 with total page 22 pages. Available in PDF, EPUB and Kindle. Book excerpt: The hydroxyl radical is known to be one of the most important intermediate species in the combustion processes. The hydroxyl radical has also been considered a dominant oxidizer of soot particles in flames. In this investigation the hydroxyl concentration profiles in sooting diffusion flames were measured by the laser-saturated fluorescence (LSF) method. The temperature distributions in the flames were measured by the two-line LSF technique and by thermocouple. In the sooting region the OH fluorescence was too weak to make accurate temperature measurements. The hydroxyl fluorescence profiles for all four flames presented herein show that the OH fluorescence intensities peaked near the flame front. The OH fluorescence intensity dropped sharply toward the dark region of the flame and continued declining to the sooting region. The OH fluorescence profiles also indicate that the OH fluorescence decreased with increasing height in the flames for all flames investigated. Varying the oxidizer composition resulted in a corresponding variation in the maximum OH concentration and the flame temperature. Furthermore, it appears that the maximum OH concentration for each flame increased with increasing flame temperature.

Download or read book Oh Planar Laser Induced Fluorescence Measurements for the Study of High Pressure Flames written by Nasa Technical Reports Server (Ntrs) and published by BiblioGov. This book was released on 2013-07 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt: Planar laser induced fluorescence (PLIF) is used by the Combustion Branch at the NASA Glenn Research Center (NASA Glenn) to assess the characteristics of the flowfield produced by aircraft fuel injectors. To improve and expand the capabilities of the PLIF system new equipment was installed. The new capabilities of the modified PLIF system are assessed by collecting OH PLIF in a methane/air flame produced by a flat flame burner. Specifically, the modifications characterized are the addition of an injection seeder to a Nd: YAG laser pumping an optical parametric oscillator (OPO) and the use of a new camera with an interline CCD. OH fluorescence results using the injection seeded OPO laser are compared to results using a Nd: YAG pumped dye laser with ultraviolet extender (UVX). Best settings of the new camera for maximum detection of PLIF signal are reported for the controller gain and microchannel plate (MCP) bracket pulsing. Results are also reported from tests of the Dual Image Feature (DIF) mode of the new camera which allows image pairs to be acquired in rapid succession. This allows acquisition of a PLIF image and a background signal almost simultaneously. Saturation effects in the new camera were also investigated and are reporte

Download or read book Laser Diagnostics for Combustion Temperature and Species written by A. C. Eckbreth and published by Routledge. This book was released on 1988 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Simultaneous Particle Imaging Velocimetry and OH Planar Laser Induced Fluorescence Measurements in an Unsteady Counterflow Propane Air Diffusion Flame written by and published by . This book was released on 2000 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt: To study the transient response of a diffusion flame to an unsteady flowfield, quantitative measurements of velocity, using particle-imaging velocimetry, and OH measurements, using planar laser-induced fluorescence, were made simultaneously in an oscillating counterflow diffusion flame. These non-intrusive measurements were performed to spatially and temporally resolve flowfield and flame characteristics as a function of initial steady strain rate and forcing frequency. For the forcing frequencies considered in this study, the strain rate fluctuations were found to lag the velocity fluctuations, but the phase difference decreased with increasing forcing frequency. At lower forcing frequencies, the width of the OH field responded quasi-steadily, but as the forcing frequency increased, the OH field showed transient effects. The dilatation velocity, defined as the difference between the minimum velocity in the preheat zone and the maximum velocity in the reaction zone, was used as a flame temperature indicator. The dilatation velocity revealed that the phase difference between the velocity and the temperature increased with increasing forcing frequency, confirming the existence of a diffusion limited response. The results presented here help to illuminate the interconnecting relationships between the chemistry, fluid dynamics, and reactant transport times.

Download or read book Comparison of In Situ Laser Induced Fluorescence LIF Measurements of Petroleum Hydrocarbons in Soils with Conventional Laboratory Measurements written by and published by . This book was released on 1995 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This presentation reports the results of a comprehensive field validation effort in which measurements from the cone penetrometer deployed LIF sensor are compared directly with results from conventional laboratory-based chemical analyses of samples collected using traditional methods. To minimize spatial and temporal variability associated with sampling, discrete samples were collected immediately after push measurements by overboring the push hole with an auger and collecting soil samples with a split spoon sampler. Secondary fluorescence measurements were made on splits of the laboratory samples to provide direct comparison with laboratory results. All discrete samples were analyzed by EPA Methods 418.1, Total Recoverable Petroleum Hydrocarbons (TRPH) and DHS Method 8015-Modified, TPH. At some sites samples were also analyzed for SVOC, EPA Method 8270, and/or an enhanced 8270 that quantifies 40 individual polynuclear aromatic hydrocarbons (PAHs).

Download or read book Laser induced Fluorescence Radical Measurements in Partially Premixed Bunsen type Methane Flames written by Norbert H. Heberle and published by . This book was released on 1996 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Temperature Profile Determination for Low Pressure Laminar Methane Flames from OH Laser induced Fluorescence written by and published by . This book was released on 2007 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Detection of Chlorinated Hydrocarbons in Combustion Systems written by Charles Stewart McEnally and published by . This book was released on 1993 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Analysis of Gas Phase Polycyclic Aromatic Hydrocarbon Mixtures by Laser Induced Fluorescence written by and published by . This book was released on 2011 with total page 105 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Development of a Laser Induced Fluorescence Technique for the Analysis of Organic Air Pollutants written by Patricia B. C. Forbes and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants which are of concern due to their potential human toxicity. They are formed during numerous combustion processes, including biomass burning and diesel vehicular emissions, which are of relevance in developing countries. A novel analytical screening method for atmospheric polycyclic aromatic hydrocarbons (PAHs) was developed in this study based on laser induced fluorescence (LIF) of samples on quartz multi-channel polydimethylsiloxane (PDMS) traps. A tunable dye laser with a frequency doubling crystal provided the excitation radiation, and a double monochromator with a photomultiplier tube detected emitted fluorescence. The method allowed for the rapid (