Download or read book Chemical vapour deposition of boron carbon thin films from organoboron precursors written by Maiwulidan (Mewlude) Yimamu (Imam) and published by Linköping University Electronic Press. This book was released on 2016-01-13 with total page 29 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron-carbon (BxC) thin films enriched in 10B are potential neutron converting layers for 10Bbased solid-state neutron detectors given the good neutron absorption cross-section of 10B atoms in the thin film. Chemical Vapour Deposition (CVD) of such films faces the challenge that the maximum temperature tolerated by the aluminium substrate is 660 °C and low temperature CVD routes for BxC films are thus needed. This thesis presents the use of two different organoboron precursors, triethylboron –B(C2H5)3 (TEB) and trimethylboron – B(CH3)3 (TMB) as single-source precursors for CVD of BxC thin films. The CVD behaviour of TEB in thermal CVD has been studied by both BxC thin film deposition and quantum chemical calculations of the gas phase chemistry at the corresponding CVD conditions. The calculations predict that the gas phase reactions are dominated by ?-hydride eliminations of C2H4 to yield BH3. In addition, a complementary bimolecular reaction path based on H2-assisted C2H6 elimination to BH3 is also present at lower temperatures in the presence of hydrogen molecules. A temperature window of 600 – 1000 °C for deposition of X-ray amorphous BxC films with 2.5 ? x ? 4.5 is identified showing good film density (2.40 – 2.65 g/cm3) which is close to the bulk density of crystalline B4C, 2.52 g/cm3 and high hardness (29 – 39 GPa). The impurity level of H is lowered to < 1 at. % within the temperature window. Plasma chemical vapour deposition has been studied using TMB as single-source precursor in Ar plasma for investigating BxC thin film deposition at lower temperature than allowed by thermal CVD and further understanding of thin film deposition process. The effect of plasma power, total pressure, TMB and Ar gas flow on film composition and morphology are investigated. The highest B/C ratio of 1.9 is obtained at highest plasma power of 2400 W and TMB flow of 7 sccm. The H content in the films seems constant at 15±5 at. %. The B-C bond is dominant in the films with small amount of C-C and B-O bonds, which are likely due to the formation of amorphous carbon and surface oxidation, respectively. The film density is determined as 2.16±0.01 g/cm3 and the internal compressive stresses are measured to be <400 MPa.

Download or read book Semiconducting Aromatic Boron Carbide Films for Neutron Detection and Photovoltaic Applications written by Adeola O. Oyelade and published by . This book was released on 2019 with total page 102 pages. Available in PDF, EPUB and Kindle. Book excerpt: Semiconducting aromatic-boron carbide composite/alloyed films formed by plasma enhanced chemical vapor deposition from carborane and aromatic precursors have been demonstrated to be excellent detectors for thermal neutrons because of the large 10B cross section. The electronic properties of these films derived from XPS show that the properties of boron carbide can be tuned by co-deposition of aromatic compounds and carborane. Aromatic doping results in narrower indirect band gaps (1.1 - 1.7 eV vs ̃3 eV for orthocarborane-derived boron carbide without aromatics) and average charge transport lifetimes (as long as 2.5 ms for benzene-orthocarborane and 1.5 - 2.5 ms for indole-orthocarborane) that are superior to those of boron carbide (35 μs). The films also show enhanced electron-hole separation that is also superior to those of boron carbide where the states at the top of the valence band is made of aromatic components while states at the bottom of the conduction band is a combination of aromatic and carborane moeities. These properties result in greatly enhanced (̃850%) charge collection, relative to films without aromatic content, in thermal neutron exposures at zero-bias, and are gamma-blind. Such films are therefore excellent candidates for zero-bias neutron detector applications. These properties also show little variation with increasing aromatic content beyond a critical concentration, indicating that at some point, excess aromatic results in the formation of regions of polymerized aromatic within the film, rather than in additional carborane/aromatic linkages. While previous studies on these aromatic-boron carbide materials indicate the potential for neutron detection due to the narrowed band gap, enhanced electron-hole separation and charge transport lifetimes compared to the boron carbide counterpart, the mechanisms of charge transport and photoconductivity (important for photovoltaic applications) of these materials have remained unexplored. Properties such as narrowed band gap, efficient electron-hole separation and long charge transport lifetimes, are also desirable in photovoltaic applications. This, plus ease of fabrication and environmental robustness makes aromatic-boron carbide films promising candidates for photovoltaic applications. Plasma enhanced chemical vapor deposition (PECVD) has been used to synthesize these aromatic-boron carbide composite films by co-deposition of pyridine, aniline or indole with orthocarborane/metacarborane. Film chemical composition and bonding were characterized by X-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS), variable angle spectroscopic ellipsometry (VASE) and (in collaboration with Dowben Group at UNL) charge transport and photoconductivity measurements. Results show narrowed band gaps (indirect) where the top of the valence band is made up of the aromatic moiety and the conduction band minimum us made of aromatic and carborane moeities, improved charge carrier mobilities that is stoichiometry and frequency dependent (aniline-orthocarborane films). Photoconductivity measurement results obtained from ̃2.6:1 indole-orthocarborane film show fourth quadrant conductivity. I(V) curves indicate a photocurrent of 2.36 μA at zero bias, with an appreciable open-circuit voltage of 1V. The ability for these aromatic-boron carbide films to operate at zero bias for both neutron detection and photovoltaic applications is an excellent advantage that indicates low cost of operation of these materials.

Download or read book Structure and Function of Food Engineering written by Ayman Amer Eissa and published by BoD – Books on Demand. This book was released on 2012-08-22 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book conveys many significant messages for the food engineering and allied professions: the importance of working in multidisciplinary teams, the relevance of developing food engineering based on well-established principles, the benefits of developing the field by bringing together experts from industry, academia and government, and the unparalleled advantage of working as globally as possible in the understanding, development, and applications of food engineering principles. I am delighted to welcome this book to the Series and I am convinced colleagues from all parts of the world will gain great value from it.

Download or read book Wood Composites written by Martin P Ansell and published by Woodhead Publishing. This book was released on 2015-07-24 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent progress in enhancing and refining the performance and properties of wood composites by chemical and thermal modification and the application of smart multi-functional coatings have made them a particular area of interest for researchers. Wood Composites comprehensively reviews the whole field of wood composites, with particular focus on their materials, applications and engineering and scientific advances, including solutions inspired biomimetrically by the structure of wood and wood composites. Part One covers the materials used for wood composites and examines wood microstructure, and wood processing and adhesives for wood composites. Part Two explores the many applications of wood composites, for example plywood, fibreboard, chipboard, glulam, cross-laminated timber, I-beams and wood-polymer composites. The final part investigates advances in wood composites and looks at the preservation and modification of wood composites, environmental impacts and legislative obligations, nano-coatings and plasma treatment, biomimetic composite materials, the integration of wood composites with other materials and carbonized and mineralized wood composites. Comprehensively reviews the entire field of wood composites in a single volume Examines recent progress in enhancing and refining the performance and properties of wood composites by chemical and thermal modification and the application of smart multi-functional coatings Explores the range of wood composites, including both new and traditional products

Download or read book Service Life Prediction written by Service Life Prediction Symposium and published by . This book was released on 2005 with total page 431 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book ICRRM 2019 System Reliability Quality Control Safety Maintenance and Management written by Vinit Kumar Gunjan and published by Springer. This book was released on 2019-06-13 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Content of this proceedings discusses emerging trends in structural reliability, safety and disaster management, covering topics like total quality management, risk maintenance and design for reliability. Some papers also address chemical process reliability, reliability analysis and engineering applications in chemical process equipment systems and includes a chapter on reliability evaluation models of chemical systems. Accepted papers from 2019 International Conference on Reliability, Risk Maintenance and Engineering Management (ICRRM 2019) are part of this conference proceeding. It offers useful insights to road safety engineers, disaster management professionals involved in product design and probabilistic methods in manufacturing systems.