Download or read book Corrosion Inhibition Performance of Sulfur and Nitrogen Based Environmentally Friendly Inhibitors for CO2 Absorption Plants written by Prathap Iyapazham Vaigunda Suba and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Performance Evaluation of Condiments as Environmentally Friendly Corrosion Inhibitors for Amine Based Carbon Dioxide Absorption Process written by Sockalingam Sekkappan and published by . This book was released on 2018 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Corrosion of process equipment and piping in the amine-based carbon dioxide (CO2) absorption process causes considerable expenditures for maintenance and repair. The addition of effective corrosion inhibitors to the amine solutions is a common practice for corrosion mitigation. Despite their inhibition effectiveness, those corrosion inhibitors used in the amine-based CO2 absorption process are not environmentally friendly and require costly waste handling and disposal. To reduce such cost and prepare for more stringent environmental regulations for chemical uses and disposal, this work investigated the feasibility of using condiments as environmentally friendly corrosion inhibitors in the amine-based CO2 absorption process. In this study, five condiments including powders of garlic, mustard, horseradish, onion and turmeric were selected and evaluated for their corrosion inhibition performance on carbon steel (CS1018) in the environment of 5.0 kmol/m3 aqueous solutions of monoethanolamine (MEA) saturated with dissolved CO2. The evaluation was carried out in corrosion experiments that employed cyclic and poteniodynamic polarization and electrochemical impedance spectroscopy for corrosion measurement and analysis. Results show that the powders of garlic, mustard, horseradish, onion showed great promise for corrosion reduction in both MEA-CO2 and MEA-CO2-oxygen (O2) solutions. They performed well with inhibition efficiencies in the range of 80- 95% even at elevated temperatures and the presence of process contaminants (i.e., chloride and oxalate) which were found to slightly affect the inhibition performance. These four condiments were proved to be mixed-type (anodic and cathodic) corrosion inhibitors that protected the metal surface by undergoing endothermic physical and chemical adsorption with the Langmuir adsorption isotherm. Sulfur, nitrogen, phosphorus functional groups were the primary contributors to the inhibition effectiveness. Unlike these four condiments, the powder of turmeric was not promising as it yielded lower inhibition efficiency and induced pitting corrosion for most tested conditions.
Download or read book Environmentally Friendly Corrosion Inhibitors for the Amine Based CO2 Absorption Process written by Sureshkumar Srinivasan and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Screening and Evaluating Environmentally Friendly Corrosion Inhibitors for Amine Based CO2 Absorption Process written by Sureshkumar Srinivasan and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This chapter evaluated the performance of environmentally friendly organic corrosion inhibitors on carbon steel in the amine-based carbon dioxide (CO2) absorption process. The evaluation was experimentally conducted using electrochemical techniques in 5.0 kmol/m3 monoethanolamine (MEA) solutions in the absence and presence of process contaminants, namely formate and chloride, at 80°C and 0.55 mol/mol CO2 loading. The results show, in the absence of process contaminants, that 2-aminobenzene sulfonic acid, 3-aminobenzene sulfonic acid, 4-aminobenzene sulfonic acid, sulfapyridine, and sulfolane yielded 85-92% corrosion inhibition efficiencies, while sulfanilamide yielded the lowest efficiency of 20-42%. Sulfolane was the only tested inhibitor whose performance could be maintained in chloride- and formate-containing MEA solutions. On the contrary, the performance of 3-aminobenzene sulfonic acid and sulfapyridine was decreased by chloride. The performance of all the tested aminobenzene sulfonic acids was compromised by formate.
Download or read book Corrosion Inhibition Performance of Methionine for CO2 Absorption Plants written by Balaji Udayappan and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic corrosion inhibitors including heavy metals have been widely used in the carbon dioxide (CO2) absorption process for corrosion control. However, they are not environmentally friendly causing costly handling and disposal costs. This work therefore evaluated corrosion inhibition performance of an organic amino acid compound, namely Methionine (MTI) which is less toxic, more readily biodegradable, and has lower potential for bioaccumulation in aquatic organisms compared to common amine absorption solvents. The evaluation was experimentally implemented using electrochemical and weight loss methods. Carbon steel (CS1018) and 5.0 kmol/m3 Monoethanolamine (MEA) purged with 85% CO2 and 15% oxygen (O2) were used as tested material and absorption solution, respectively. The electrochemical results showed that at solution temperatures up to 80oC, MTI effectively reduced corrosion rates of CS1018 with maximum inhibition efficiencies of 83.56% ± 1.82% under a static condition (0 rpm) and 74.96% ± 0.95% under a dynamic condition (1500 rpm). Its inhibition performance was found to increase with inhibitor concentration and solution temperature but decrease with rotational speed. MTI acted as a mixed-type inhibitor and exhibited pitting tendency. The optimal MTI concentrations were 1500 ppm at 0 rpm and 2000 ppm at 1500 rpm. The post data analysis involving adsorption isotherm and activation thermodynamic properties revealed that MTI protected metal surface by undergoing spontaneous and endothermic physical adsorption. Its adsorption characteristic matched well with the Langmuir adsorption isotherm, thereby suggesting that MTI formed a protective monolayer on the metal surface. The results of quantum chemical analysis suggested MTI has higher affinity, polarizability, and electron donating ability than MEA. III The results of weight loss experiments carried out for up to 28 days showed that at 120oC, 5 bar and 1500 rpm, MTI was able to reduce corrosion rates of CS1018 to below 1 mmpy. The inhibition efficiencies were up to 78.7% for carbon steel specimens fully immersed in the MEA solutions, 53.5% for those partially immersed in the MEA solution and partially exposed to vapor, and 85.6% for those fully exposed to vapor. Pits were observed on carbon steel specimens fully immersed in both uninhibited and MTI inhibited solutions.
Download or read book Corrosion Inhibitors Principles and Recent Applications written by Mahmood Aliofkhazraei and published by BoD – Books on Demand. This book was released on 2018-04-04 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: To protect metals or alloys from corrosion, some methods can be used such as isolating the structure from the aggressive media or compensating the loss of electrons from the corroded structure. The use of corrosion inhibitors may include organic and inorganic compounds that adsorb on the metallic structure to isolate it from its surrounding media to decrease oxidation-reduction processes. This book collects new developments about corrosion inhibitors and their recent applications.
Download or read book Corrosion Inhibition Performance of Copper Carbonate in CO2 Absorption Process Using Aqueous Solution of Monoethanolamine written by Immanuelraj Soosaiprakasam and published by . This book was released on 2007 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Corrosion is one of the most severe operational problems in CO2 absorption processes, which use aqueous solutions of alkanolamines, especially when carbon steel is used for plant construction. Corrosion inhibitors are widely applied used in this process to suppress severe corrosion to an acceptable level. However, currently available corrosion inhibitors are heavy metals, which are toxic to human health and the environment, making solvent handling and waste disposal more difficult and costly. This work evaluated a low-toxic corrosion inhibitor, copper carbonate (CuCO3), as a replacement for toxic corrosion inhibitors. An inhibition evaluation was performed on copper carbonate by examining its parametric effects on the corrosion rate and corrosion behavior of carbon steel.
Download or read book The Cost of Corrosion in China written by Baorong Hou and published by Springer Nature. This book was released on 2019-09-26 with total page 953 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book comprehensively covers corrosion and corrosion protection in China in the areas including infrastructure, transportation, energy, water environment, as well as manufacturing and public utilities. Furthermore, it presents a major consulting project of Chinese Academy of Engineering, which was the largest corrosion investigation project in Chinese history, including the corresponding methods, processes and corrosion protection strategies, and provides valuable information for numerous industries. Sharing essential insights into corrosion prediction and decision-making, this book will help to decrease costs and extend the service life of equipment and facilities; accordingly, it will benefit scientists and engineers working on corrosion research and protection, as well as economists and government employees.
Download or read book Novel Corrosion Inhibitors for Protection from CO2 Corrosion written by Hany M. Abd El-Lateef and published by LAP Lambert Academic Publishing. This book was released on 2012 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon dioxide (CO2) corrosion is of great concern in oil and gas production, transportation and processing. Despite the fact that steel has low resistance to CO2 environments, it is widely used in the petroleum industry mainly due to economical reasons. The use of corrosion inhibitors is very important in the protection of steels. Most of the inhibitors used in petroleum industry are organic compounds containing multiple bonds in their molecules that mainly contain nitrogen, sulphur, and/or oxygen atoms through which they get adsorbed on the metal surface. However, most of these substances are toxic and using them is harmful for both human health and environment. Therefore, in this work, we accomplished synthesis of new environment friendly effective corrosion inhibitors for oil and gas industry in the protection of equipment and pipelines transporting multiphase systems based on vegetable oils. Vegetable oils are of the greatest interest because of its technological properties, accessibility, and relatively low price. The performed research is indicating that the vegetable oil can be good raw material for preparation of "environmentally friendly" corrosion inhibitors.
Download or read book Green Corrosion Inhibitors written by V. S. Sastri and published by John Wiley & Sons. This book was released on 2012-02-14 with total page 267 pages. Available in PDF, EPUB and Kindle. Book excerpt: A book to cover developments in corrosion inhibitors is long overdue. This has been addressed by Dr Sastri in a book which presents fundamental aspects of corrosion inhibition, historical developments and the industrial applications of inhibitors. The book deals with the electrochemical principles and chemical aspects of corrosion inhibition, such as stability of metal complexes, the Hammett equation, hard and soft acid and base principle, quantum chemical aspects and Hansch' s model and also with the various surface analysis techniques, e.g. XPS, Auger, SIMS and Raman spectroscopy, that are used in industry for corrosion inhibition. The applications of corrosion inhibition are wide ranging. Examples given in this book include: oil and gas wells, petrochemical plants, steel reinforced cement, water cooling systems, and many more. The final chapters discuss economic and environmental considerations which are now of prime importance. The book is written for researchers in academia and industry, practicing corrosion engineers and students of materials science, engineering and applied chemistry.
Download or read book Green Inhibition of Mild Steel Corrosion in a Carbon Dioxide Saturated Saline Solution written by Elron Edgar Gomes and published by . This book was released on 2015 with total page 189 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Mild steel is extensively used in equipment such as pipelines and machinery by many industries, where it is exposed to corrosive environments. Dissolved carbon dioxide (CO2) can be found in produced water and results in severe corrosion due to the formation of carbonic acid. CO2 corrosion presents not only an economic loss but also an environmental and safety risk. Most industries use synthetic inhibitors, which are effective in reducing corrosion, but are also toxic and persistent. This has led to stricter regulations and thus, there is a need for alternative inhibitors which can replace them but not exhibit their undesired characteristics. The aqueous extracts of Fig leaves (FLE), Calotropis procera (CPLE) and Eggplant peels (EPPE) were investigated as novel corrosion inhibitors for mild steel in a CO2-saturated 3.5wt% NaCl solution using various electrochemical techniques such as linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS) and cyclic sweep (CS). The results showed that the corrosion rate is decreasing and inhibition efficiency is increasing as the concentration of inhibitor increased. Corrosion inhibition efficiencies of 90-95% were obtained using low dosage of the green inhibitors. FLE, CPLE and EPPE proved to be effective inhibitors and are compared to the performance of two commercially available inhibitors, A (green inhibitor) and B (synthetic inhibitor). Polarization studies show that FLE, CPLE and EPPE act as mixed inhibitors. The adsorption data was analyzed using various adsorption isotherm models and the results at temperatures of 25, 40, 50 and 70°C have shown that the adsorption behavior of FLE, CPLE and EPPE is best described by the Langmuir adsorption isotherm. The conclusion drawn from this work is that the FLE, CLE and ELE inhibitors proved to be effective inhibitors when compared to Inhibitor A. Inhibitor B proved to be a much more effective inhibitor than the others due to its synergistic mix of active ingredients."--Abstract.
Download or read book Corrosion in CO2 Absorption Process Using Aqueous Monoethanolamine piperazine Solution written by Manjula Nainar and published by . This book was released on 2007 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work explores the promise of aqueous solutions of blended monoethanolamine (MEA) and piperazine (PZ) as a cost-effective solvent for carbon dioxide (CO2) capture from industrial flue gas streams with respect to addressing corrosion, which is regarded as one of the most severe operational problems in typical CO2 capture plants. Two types of corrosion experiments were carried out in bench-scale setups, electrochemical tests for short-term exposure and weight loss tests for long-term exposure. The results show that the blended MEA/PZ solutions are more corrosive than the MEA solutions. The corrosion rate of carbon steel increases with concentration of PZ, total amine concentration, CO2 loading of solution, solution temperature, the presence of heat stable salts, and the presence of the proprietary oxidative degradation inhibitor (Inhibitor A provided by the University of Texas at Austin). Among the tested heat-stable salts, formate is the most corrosive salt, followed by acetate, oxalate, and thiosulfate in the absence of oxygen (O2), while acetate is the most corrosive salt followed by formate, oxalate, and thiosulfate in the presence of O2. Based on the level of corrosion rate found in the MEA/PZ system, corrosion control is required during plant operation to suppress the corrosion rate of carbon steel to below an acceptable level. Sodium metavanadate (NaVO3) and copper carbonate (CuCO3) were proven to be effective corrosion inhibitors with inhibition performance of up to 94-98%. Dissolved O2 is required in the solution to maintain active Cu2 or V5+, which, thus, prevents the metallic copper (Cu) from plating out or the formation of other oxidative states of vanadate. The performance of these two inhibitors can be deteriorated by the presence of heat-stable salts in the solutions.
Download or read book Corrosion Inhibitors in the Oil and Gas Industry written by Viswanathan S. Saji and published by John Wiley & Sons. This book was released on 2020-06-02 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides comprehensive coverage of corrosion inhibitors in the oil and gas industries Considering the high importance of corrosion inhibitor development for the oil and gas sectors, this book provides a thorough overview of the most recent advancements in this field. It systematically addresses corrosion inhibitors for various applications in the oil and gas value chain, as well as the fundamentals of corrosion inhibition and interference of inhibitors with co-additives. Corrosion Inhibitors in the Oil and Gas Industries is presented in three parts. The first part on Fundamentals and Approaches focuses on principles and processes in the oil and gas industry, the types of corrosion encountered and their control methods, environmental factors affecting inhibition, material selection strategies, and economic aspects of corrosion. The second part on Choice of Inhibitors examines corrosion inhibitors for acidizing processes, inhibitors for sweet and sour corrosion, inhibitors in refinery operations, high-temperature corrosion inhibitors, inhibitors for challenging corrosive environments, inhibitors for microbiologically influenced corrosion, polymeric inhibitors, vapor phase inhibitors, and smart controlled release inhibitor systems. The last part on Interaction with Co-additives looks at industrial co-additives and their interference with corrosion inhibitors such as antiscalants, hydrate inhibitors, and sulfide scavengers. -Presents a well-structured and systematic overview of the fundamentals and factors affecting corrosion -Acts as a handy reference tool for scientists and engineers working with corrosion inhibitors for the oil and gas industries -Collectively presents all the information available on the development and application of corrosion inhibitors for the oil and gas industries -Offers a unique and specific focus on the oil and gas industries Corrosion Inhibitors in the Oil and Gas Industries is an excellent resource for scientists in industry as well as in academia working in the field of corrosion protection for the oil and gas sectors, and will appeal to materials scientists, electrochemists, chemists, and chemical engineers.
Download or read book Uhlig s Corrosion Handbook written by Robert Winston Revie and published by . This book was released on 2011 with total page 1253 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book serves as a reference for engineers, scientists, and students concerned with the use of materials in applications where reliability and resistance to corrosion are important. It updates the coverage of its predecessor, including coverage of: corrosion rates of steel in major river systems and atmospheric corrosion rates, the corrosion behavior of materials such as weathering steels and newer stainless alloys, and the corrosion behavior and engineering approaches to corrosion control for nonmetallic materials. New chapters include: high-temperature oxidation of metals and alloys, nanom.
Download or read book Inhibition of Carbon Steel Corrosion in Closed loop water Heating cooling Systems Using Sodium Caprylate as an Environmentally friendly Corrosion Inhibitor written by Ipsita Bordoloi and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: "Carbon steel (CS) is widely used in water transporting systems because of its exceptional mechanical properties. However, CS is highly prone to corrosion, and uniform corrosion is the most common form of corrosion that affects CS. The internal corrosion of CS equipment is the main reason behind the failure of a closed loop water heating/cooling system. Water quality parameters like dissolved salts and gases, low pH, high temperature, galvanic and microbial activity greatly affect the rate of internal corrosion. Thus, it is important to mitigate internal corrosion of CS. One common way of mitigating corrosion is by using corrosion inhibitors. However, the commercially available corrosion inhibitors are found to be toxic and current research is focused on developing environmentally-friendly corrosion inhibitors.The objective of this work is to investigate the possibility of using sodium caprylate (SC) as an environmentally-friendly corrosion inhibitor for closed-loop-water heating/cooling system with CS as the substrate (material of construction) and the Montreal tap water as the electrolyte, under various conditions; concentration of SC, water temperature and pH, and time. Four electrochemical techniques and scanning electron microscopy were employed in the study.The results revealed that SC offered a 96% corrosion inhibition efficiency at 10mM concentration and at pH 8 and room temperature (295 K). The inhibition efficiency was found to be SC concentration dependent. Two distinctive regions of efficiency (lower/high) were identified, with the sharp transition occurring when going from 6.28mM to 6.3mM of SC in the water. The corresponding low-to-high corrosion inhibition efficiency transition can be linked to the abrupt change in surface concentration and orientation of SC. Experiments at varying temperature revealed that SC can also efficiency inhibit corrosion up to 333K. The inhibitor can also efficiently inhibit corrosion in the pH range form 7-10 pH. The kinetics study showed that adsorption SC onto the CS surface is very quick (within a couple of minutes). Furthermore, surface analysis study using SEM showed that for CS kept in 10 mM SC solution for 30 days at 295 K, there was negligible corrosion as compared to the sample that was kept in the inhibitor-free solution. In conclusion, SC can efficiently be used as a corrosion inhibitor for water heating/cooling systems made of CS, up to 333K." --
Download or read book Environmentally Sustainable Corrosion Inhibitors written by Chaudhery Mustansar Hussain and published by Elsevier. This book was released on 2021-09-15 with total page 475 pages. Available in PDF, EPUB and Kindle. Book excerpt: Environmentally Sustainable Corrosion Inhibitors: Fundamentals and Industrial Applications covers the latest research developments in environmentally friendly, sustainable corrosion inhibitors. The book addresses the fundamental characteristics, synthesis, characterization and mechanisms of corrosion inhibitors. In addition, it presents a chronological overview of the growth of the field, with numerous examples of its broad-ranging industrial applications in a.o. food, the environment, electronics, and the oil and gas industries. The book concludes with discussions about commercialization and economics. This is an indispensable reference for chemical engineers and chemists working in R&D and academia who want to learn more about environmentally-friendly, sustainable corrosion inhibitors systems. Explains how to use environmentally-friendly, sustainable corrosion inhibitors in modern industry and manufacturing Promotes corrosion inhibitors as a prime option for sustainable and transformational opportunities Provides up-to-date reference material, including websites of interest and information on the latest research
Download or read book Petroleum Abstracts Literature and Patents written by and published by . This book was released on 1990 with total page 1416 pages. Available in PDF, EPUB and Kindle. Book excerpt:
