Download or read book Controls on the Trace Metal Chemistry of Foraminiferal Calcite and Aragonite written by Sarah Jane Brown and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Study of Biological and Physical Controls on the Trace Metal Content of Calcite and Aragonite written by Robert B. Lorens and published by . This book was released on 1978 with total page 846 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Study of Biological and Physical Controls on the Trace Metal Content of Calcite and Aragonite written by Robert B. Lorens and published by . This book was released on 1978 with total page 810 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Environmental and Growth Rate Effects on Trace Element Incorporation to Calcite and Aragonite written by Jeremy M. Weremeichik and published by . This book was released on 2016 with total page 112 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subsumed work of this dissertation is comprised of three independent but interrelated studies which seek to further the understanding of processes which govern the coprecipitation of trace elements with calcite and aragonite minerals. These studies investigate the effects of: 1) pressure on crystal morphology and trace element incorporation to aragonite; 2) growth rate on uranium partitioning between calcite and fluid; 3) aqueous Mg/Ca on the magnesium partitioning to low-magnesium calcite. The importance of this work is to determine how the environment of formation and growth rate influences the geochemistry of CaCO3 in order to improve existing paleoproxies and develop new ones. In the first study a series of experiments were conducted at 1, 25, 75, 100, and 345 bars of nitrogen – this range covers pressures at the oceanic floor. Aragonite precipitation was induced by the one-time addition of a Na2CO3 solution to an artificial seawater. Results suggest that oceanic floor pressures could affect the crystallization of CaCO3 by altering mineralogical composition and aragonite crystal size. In the second study calcite crystallized from NH4Cl-CaCl2-U solution by diffusion of CO2. The calcite growth rate was monitored by sequential spiking of the calciteprecipitating fluids with REE dopants. The resulting crystals were analyzed using Secondary Ion Mass Spectrometry (SIMS). Results showed that the partitioning of uranium increases with increasing growth rate. Growth entrapment model (GEM) and unified uptake kinetics model (UUKM) explain the obtained data. In the third study CaCO3 precipitated in NaCl solution by continuous addition of CaCl2, MgCl2, and either Na2CO3 or NaHCO3. The Mg/Ca of the fluid was adjusted in an attempt to produce calcite where Mg/Ca would match Mg/Ca in foraminifera shells. It was observed that multiple CaCO3 polymorphs precipitated from fluids at high pH (Na2CO3 doping experiments). This result underscores the potential control of pH and/or supersaturation state on CaCO3 polymorph precipitated from low Mg/Ca solutions. Calcite was the only mineral crystallized at low pH (NaHCO3 doping experiments). It was determined that Mg partition coefficient between calcite and fluid (KMg) negatively correlates with Mg/Ca(Fluid) when it exceeds 0.5 mol/mol; no systematic correlation was observed when 0.05
Download or read book Analysis of Trace Elements for Determining the Stability of Calcite and Aragonite written by J. Eian Harm and published by . This book was released on 1997 with total page 52 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Stable Isotope and Trace Element Composition of Foraminiferal Calcite written by Bärbel Hönisch and published by . This book was released on 2002 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book An Examination of Trace Element Concentrations Across Calcite aragonite Transitions in a Madagascan Stalagmite written by Kaylee Brent and published by . This book was released on 2017 with total page 25 pages. Available in PDF, EPUB and Kindle. Book excerpt: Calcite and aragonite speleothems have been used for the past few decades to provide paleoclimate information, but in speleothems of mixed mineralogy the signal of mineral changes can complicate understanding of climate signals also present. This mineral signal must therefore be examined and controlled for. In this work, ICP-MS (inductively-coupled plasma mass spectrometry) analysis of trace element (strontium and magnesium) incorporation into calcium carbonate provides additional evidence for a shift in CaCO3 polymorphs identified via XRD (xray diffraction) analysis of speleothem AB-2 from Anjohibe Cave, Madgascar. The ICP-MS Sr/Ca data qualitatively supports the Sr/Ca data collected by the XRF core scanner, exhibiting a sharp decrease in value across the identified mineral transition. A corresponding increase in Mg/Ca revealed by the ICP-MS provides further evidence for a change from aragonite to calcite at this location. This mineralogical change occurred between 870-880 CE (+/- 13 years) is nearly concurrent with a shift in [delta]13C isotopes that was identified in previous work on this speleothem and attributed to an ecological shift in dominant photosynthetic pathways (Bums et al 2016). A second, control section was identified as pure calcite by XRD analysis, but revealed Mg/Ca and Sr/Ca ratios characteristic of mineralogical transitions, suggesting that there may have been layers of aragonite that have recrystallized to calcite since deposition.
Download or read book Ion Partitioning in Ambient Temperature Aqueous Systems written by H. Stoll and published by The Mineralogical Society of Great Britain and Ireland. This book was released on 2010-11-15 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Understanding in detail the ion partitioning in mineralwater interactions is of fundamental importance to geochemical studies and ultimately to society. The solid-solution properties of minerals are a significant part of the complexity, and also the importance, of these ion-partitioning reactions.
Download or read book Stabilization of Aragonite to Low Mg Calcite written by Ihsan Shakir Al-Aasm and published by . This book was released on 1984 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Bibliography of Technical Reports 1983 written by and published by . This book was released on 1984 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: The technical reports prepared by the Woods Hole Oceanographic Institution in 1983 are listed in this bibliography. Inquiries about availability of extra copies will be handled on an individual basis. Initial distribution of the reports is controlled by the funding agencies. Reports are available through the National Technical Information Service (Springfield, Virginia 22161). NTIS order numbers are included with each report listed or can be obtained through the Document Library.
Download or read book Boron Proxies in Paleoceanography and Paleoclimatology written by Bärbel Hönisch and published by John Wiley & Sons. This book was released on 2019-05-13 with total page 241 pages. Available in PDF, EPUB and Kindle. Book excerpt: Anthropogenic carbon dioxide emissions do not only warm our planet but also acidify our oceans. It is currently unclear to which degree Earth’s climate and marine life will be impacted by these changes but information from Earth history, particularly the geochemical signals of past environmental changes stored in the fossil remains of marine organisms, can help us predict possible future changes. This book aims to be a primer for scientists who seek to apply boron proxies in marine carbonates to estimate past seawater carbonate chemistry and atmospheric pCO2. Boron proxies (δ11B and B/Ca) were introduced nearly three decades ago, with subsequent strides being made in understanding their mechanistic functioning. This text reviews current knowledge about the aqueous systematics, the inorganic and biological controls on boron isotope fractionation and incorporation into marine carbonates, as well as the analytical techniques for measurement of boron proxies. Laboratory and field calibrations of the boron proxies are summarized, and similarities between modern calibrations are explored to suggest estimates for proxy sensitivities in marine calcifiers that are now extinct. Example applications illustrate the potential for reconstructing paleo-atmospheric pCO2 from boron isotopes. Also explored are the sensitivity of paleo-ocean acidity and pCO2 reconstructions to boron isotope proxy systematics that are currently less well understood, including the elemental and boron isotopic composition of seawater through time, seawater alkalinity, temperature and salinity, and their collective impact on the uncertainty of paleo-reconstructions. The B/Ca proxy is based on the same mechanistic principles as the boron isotope proxy, but empirical calibrations suggest seawater pH is not the only controlling factor. B/Ca therefore has the potential to provide a second carbonate parameter that could be paired with δ11B to fully constrain the ocean carbonate system, but the associated uncertainties are large. This text reviews and examines what is currently known about the B/Ca proxy systematics. As more scientists embark on characterizing past ocean acidity and atmospheric pCO2, Boron in Paleoceanography and Paleoclimatology provides a resource to introduce geoscientists to the opportunities and complications of boron proxies, including potential avenues to further refine them.
Download or read book Sediments Diagenesis and Sedimentary Rocks written by F.T. Mackenzie and published by Elsevier. This book was released on 2005-11-22 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers the formation and biogeochemistry of a variety of important sediment types from their initial formation through their conversion (diagenesis) to sedimentary rocks. The volume deals with the chemical, mineralogical, and isotopic properties of sediments and sedimentary rocks and their use in interpreting the environment of formation and subsequent events in the history of sediments, and the nature of the ocean-atmosphere system through geological time. Reprinted individual volume from the acclaimed Treatise on Geochemistry, (10 Volume Set, ISBN 0-08-043751-6, published in 2003). Comprehensive and authoritative scope and focus Reviews from renowned scientists across a range of subjects, providing both overviews and new data, supplemented by extensive bibliographies Extensive illustrations and examples from the field
Download or read book Carbonates written by Richard J. Reeder and published by Walter de Gruyter GmbH & Co KG. This book was released on 2018-12-17 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 11 of Reviews in Mineralogy attempts to synthesize our present understanding of certain aspects of the mineralogy and chemistry of the rock-forming carbonates. This review follows, by ten years, a major assessment of (sedimentary) carbonate minerals by Lippmann (1973). There is only minor overlap of subject material, and I hope that this difference reflects fairly how this field has developed. In this volume, some of the papers are general (i.e., those addressing crystal chemistry and phase relations), and they provide overviews of a fundamental nature and are of interest to many. Others are more specialized in coverage and generally reflect the different approaches used in carbonate geochemistry. The final chapter introduces transmission electron microscopy, a relatively new and powerful technique for mineralogical research that has great potential in carbonate research.
Download or read book The Origin of Clay Minerals in Soils and Weathered Rocks written by Bruce B. Velde and published by Springer Science & Business Media. This book was released on 2008-07-18 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: Of huge relevance in a number of fields, this is a survey of the different processes of soil clay mineral formation and the consequences of these processes concerning the soil ecosystem, especially plant and mineral. Two independent systems form soil materials. The first is the interaction of rocks and water, unstable minerals adjusting to surface conditions. The second is the interaction of the biosphere with clays in the upper parts of alteration profiles.
Download or read book Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards written by and published by . This book was released on 1997 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: Theses on any subject submitted by the academic libraries in the UK and Ireland.
Download or read book Roles of Organic Matter in Sediment Diagenesis written by Donald L. Gautier and published by . This book was released on 1986 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Handbook of Environmental Isotope Geochemistry written by Mark Baskaran and published by Springer Science & Business Media. This book was released on 2011-10-13 with total page 944 pages. Available in PDF, EPUB and Kindle. Book excerpt: Applications of radioactive and stable isotopes have revolutionized our understanding of the Earth and near-earth surface processes. The utility of the isotopes are ever-increasing and our sole focus is to bring out the applications of these isotopes as tracers and chronometers to a wider audience so that they can be used as powerful tools to solve environmental problems. New developments in this field remain mostly in peer-reviewed journal articles and hence our goal is to synthesize these findings for easy reference for students, faculty, regulators in governmental and non-governmental agencies, and environmental companies. While this volume maintains its rigor in terms of its depth of knowledge and quantitative information, it contains the breadth needed for wide variety problems and applications in the environmental sciences. This volume presents all of the newer and older applications of isotopes pertaining to the environmental problems in one place that is readily accessible to readers. This book not only has the depth and rigor that is needed for academia, but it has the breadth and case studies to illustrate the utility of the isotopes in a wide variety of environments (atmosphere, oceans, lakes, rivers and streams, terrestrial environments, and sub-surface environments) and serves a large audience, from students and researchers, regulators in federal, state and local governments, and environmental companies.
