Download or read book Constant Radical written by Jenny Chamberlain and published by . This book was released on 2017 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Handbook of Radical Polymerization written by Krzysztof Matyjaszewski and published by John Wiley & Sons. This book was released on 2003-04-14 with total page 934 pages. Available in PDF, EPUB and Kindle. Book excerpt: Klassische und moderne Verfahren der radikalischen Polymerisation: In diesem handlichen Band finden Sie Antworten auf theoretische und praktische Fragen. Neben grundlegenden Ausführungen zur Einteilung radikalischer Polymere sind Angaben über die wichtigsten experimentellen Verfahren zur Synthese, Reinigung und Charakterisierung von Polymeren enthalten. Interessante Zugabe: ein Abriß der Geschichte der Radikalkettenpolymerisation.
Download or read book Fundamentals of Controlled living Radical Polymerization written by Nicolay V. Tsarevsky and published by Royal Society of Chemistry. This book was released on 2013 with total page 379 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides an in-depth history, description, and mechanistic understanding of each of the controlled/living radical polymerization techniques and practical details necessary to carry out the reactions.
Download or read book The Chemistry of Radical Polymerization written by Graeme Moad and published by Elsevier. This book was released on 2006 with total page 667 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book commences with a general introduction outlining the basic concepts of radical polymerization. This is followed by a chapter on radical reactions that is intended to lay the theoretical ground-work for the succeeding chapters on initiation, propagation and termination.
Download or read book Radical Reactions in Organic Synthesis written by Samir Z. Zard and published by Oxford University Press, USA. This book was released on 2003 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction and some general concepts. -- General principles: chain reactions based on stannane chemistry. -- Further chain reactions of stannanes. -- Organo-silicon, -germanium, and -mercury hydrides. -- The Barton decarboxylation and related reactions. -- Atom and group transfer reactions. -- The persistent radical effect: non-chain processes. -- Redox processes. -- Some concluding remarks.
Download or read book Ion Radical Organic Chemistry written by Zory Vlad Todres and published by CRC Press. This book was released on 2008-10-20 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: Consolidating knowledge from a number of disciplines, Ion-Radical Organic Chemistry: Principles and Applications, Second Edition presents the recent changes that have occurred in the field since the publication of the first edition in 2003. This volume examines the formation, transformation, and application of ion-radicals in typical conditions of organic synthesis. Avoiding complex mathematics, the author explains the principles of ion-radical organic chemistry and presents an overview of organic ion-radical reactions. He reviews methods of determining ion-radical mechanisms and controlling ion-radical reactions. Wherever applicable, the text addresses issues relating to ecology and biomedical concerns as well as inorganic participants of the ion-radical organic reactions. After reviewing the nature of organic ion-radicals and their ground-state electronic structure, the book discusses their formation, the relationship between electronic structure and reactivity, mechanism and regulation of reactions, stereochemical aspects, synthetic opportunities, and practical applications. Additional topics include electronic and opto-electronic devices, organic magnets and conductors, lubricants, other materials, and reactions of industrial or biomedical importance. The book concludes by providing an outlook on possible future development in this field. Researchers and practitioners engaged in active work on synthetic or mechanistic organic chemistry and its practical applications will find this text to be invaluable in both its scope and its depth.
Download or read book Organosilanes in Radical Chemistry written by Chryssostomos Chatgilialoglu and published by John Wiley & Sons. This book was released on 2004-02-13 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years silicon-centered radicals have played an important role in organic synthesis, polymer chemistry and material sciences. The aim of this book is to offer for the first time a description of silyl radicals within an interdisciplinary context, connecting structural characteristics and chemical properties to their application in different areas of chemistry. The first time different aspects of silyl radicals have been brought together Excellent reference tool for experienced practitioners ofradical and/or silicon chemistry Presents various aspects of these intermediates in an original, comprehensive fashion This book is essential for anyone working in free radical and/orsilicon chemistry as well as for those who want to approach these fields for the first time.
Download or read book Advanced Free Radical Reactions for Organic Synthesis written by and published by Elsevier. This book was released on 2004-01-14 with total page 271 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical reactions have become increasingly important and a very attractive tool in organic synthesis in the last two decades, due to their powerful, selective, specific, and mild reaction abilities. Advanced Free Radical Reactions for Organic Synthesis reviews information on all types of practical radical reactions, e.g. cyclizations, additions, hydrogen-atom abstractions, decarboxylation reactions. The book usefully provides experimental details for the most important reactions as well as numerous references to the original literature. By covering both the fundamentals and synthetic applications it is therefore suitable for both new and experienced researchers, chemists, biochemists, natural product chemists and graduate students. This title is the definitive guide to radical chemistry for all scientists. Introduces and reviews the use of radicals to perform synthetic transformations Practical details are provided for the most important methods Numerous references to the original literature
Download or read book The Journal of Physical Chemistry written by and published by . This book was released on 1909 with total page 762 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Handbook of Free Radical Initiators written by E. T. Denisov and published by John Wiley & Sons. This book was released on 2005-01-14 with total page 903 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.
Download or read book Free Radical Chemistry written by D. C. Nonhebel and published by CUP Archive. This book was released on 1974-01-31 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Radical and Radical Ion Reactivity in Nucleic Acid Chemistry written by Michael D. Greenberg and published by John Wiley & Sons. This book was released on 2009-09-22 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive coverage of radical reactive intermediates in nucleic acid chemistry and biochemistry The Wiley Series on Reactive Intermediates in Chemistry and Biology investigates reactive intermediates from the broadest possible range of disciplines. The contributions in each volume offer readers fresh insights into the latest findings, emerging applications, and ongoing research in the field from a diverse perspective. The chemistry and biochemistry of reactive intermediates is central to organic chemistry and biochemistry, and underlies a significant portion of modern synthetic chemistry. Radical and Radical Ion Reactivity in Nucleic Acid Chemistry provides the only comprehensive review of the chemistry and biochemistry of nucleic acid radical intermediates. With contributions by world leaders in the field, the text covers a broad range of topics, including: A discussion of the relevant theory Ionization of DNA Nucleic acid sugar radicals Halopyrimidines Oxidative, reductive, and low energy electron transfer Electron affinity sensitizers Photochemical generative of reactive oxygen species Reactive nitrogen species Enediyne rearrangements Phenoxyl radicals A unique compilation on the cutting edge of our understanding, Radical and Radical Ion Reactivity in Nucleic Acid Chemistry provides an unparalleled resource to student and professional researchers in such fields as organic chemistry, biochemistry, molecular biology, and physical chemistry, as well as the industries associated with these disciplines.
Download or read book Radical Polymerization written by Michael Buback and published by John Wiley & Sons. This book was released on 2007-06-27 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume from the successful Macromolecular Symposia series presents the contributions from the IUPAC-sponsored International Symposium on "Radical Polymerization: Kinetics and Mechanism", held in Il Ciocco, Italy, in September, 2006. This was the fourth within the series of so-called SML conferences, which are the major scientific forum for addressing kinetic and mechanistic aspects of free-radical polymerization and controlled radical polymerization. SML IV again marked an important step forward toward the better understanding of the kinetics and mechanism of radical polymerization, which is extremely relevant for both conventional and controlled radical polymerization and for people in academia as well as in industry. Here, top international authors, such as K. Matyjaszewski, T. P. Davis and T. Fukuda, present their latest research. The five major themes covered were: Fundamentals of free-radical polymerization, heterogeneous polymerization, controlled radical polymerization, polymer reaction engineering, and polymer characterization.
Download or read book Nanocomposite Structures and Dispersions written by Ignac Capek and published by Elsevier. This book was released on 2019-07-20 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanocomposite Structures and Dispersions deals with the preparation of gelled, branched and crosslinked nanostructured polymers in the solution free radical polymerization and controlled/living radical polymerization and polymer and composite nanoparticles and nanostructures in disperse systems, the kinetics of direct and inverse disperse polymerizations (microemulsion, miniemulsion, emulsion, dispersion and suspension polymerization), the bottom-up approach building of functionalized nanoparticles, modelling of radical microemulsion polymerization, the characterization of traditional and non-traditional polymer dispersions, the collective properties of nanomaterials and their (bio)applications. This book is designed to bridge that gap and offers several unique features. First, it is written as an introduction to and survey of nanomaterials with a careful balance between basics and advanced topics. Thus, it is suitable for both beginners and experts, including graduate and upper-level undergraduate students. Second, it strives to balance the colloidal aspects of nanomaterials with physical principles. Third, the book highlights nanomaterial based architectures including composite or hybrid conjugates rather than only isolated nanoparticles. A number of ligands have been utilized to biodecorate the polymer and composite nanocarriers. Finally, the book provides an in depth discussion of important examples of reaction mechanisms of bottom-up building of functionalized nanoparticles, or potential applications of nanoarchitectures, ranging from physical to chemical and biological systems. Free radical (controlled) polymerization, branching, crosslinking and gelling Kinetics and mechanism of polymer nanoparticles formation Modelling of radical polymerization in disperse systems Polymer, composite and metal nanoparticles, nanostructures and nanomaterials Smart nanostructures, biodecorated particles, nanocarriers and therapeutics
Download or read book Carbon Centered Free Radicals and Radical Cations written by Malcolm D. Forbes and published by John Wiley & Sons. This book was released on 2010-01-22 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using these critically important intermediates. Carbon-Centered Free Radicals and Radical Cations begins with a short history of the field of free radical chemistry, and then covers: A discussion of the relevant theory Mechanistic chemistry, with an emphasis on synthetic utility Molecular structure and mechanism, focusing on computational methods Spectroscopic investigations of radical structure and kinetics, including demonstrations of spin chemistry techniques such as CIDNP and magnetic field effects Free radical chemistry in macromolecules Each chapter, written by one or more leading experts, explains difficult concepts clearly and concisely, with references to facilitate further investigation of individual topics. The authors were selected in order to provide insight into a broad range of topics, including small molecule synthesis, polymer degradation, computational chemistry as well as highly detailed experimental work in the solid, liquid, and gaseous states. This volume is essential for students or researchers interested in building their understanding of the role of carbon-centered radical intermediates in complex systems and how they may be used to develop a broad range of useful products.
Download or read book The Radical Republicans written by Hans L. Trefousse and published by Knopf. This book was released on 2014-10-29 with total page 668 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the story of the men who, as political realists, fought for the cause of racial reform in America before, during, and after the Civil War. Charles Sumner, Thaddeus Stevens, Benjamin F. Wade, and Zachariah Chandler are the central figures in Mr. Trefousse's study of the Radical Republicans who steered a course between the extreme abolitionists on the one hand and the more cautious gradualists on the other, as they strove to break the slaveholder's domination of the federal government andthen to wrest from the postbellum South an acknowledgment of the civil rights of the Negro. The author delineates their key role in founding the Republican party and follows their struggle to keep the party firm in its opposition to the expansion of slavery, to commit it to emancipation, and finally to make it the party of racial justice. This is the story as well of the tangled relationship of the Radical Republicans with Abraham Lincoln—a relationship of both quarrels and mutual support. The author stresses the similarity between Lincoln's ultimate aims and those of the Radical Republicans, demonstrating that without Lincoln's support Sumner and his colleagues could never have accomplished their ends—and that without their help Lincoln might not have succeeded in crushing the rebellion and putting an end to the slavery. And he argues that by 1865 Lincoln's Reconstruction policies were nearing those of the Radicals and that, had he lived, they would not have broken with him as they did with his successor. Lincoln's assassination left the Radicals with no means to translate their demands into effective action. Their efforts to remake the South in such a way as to secure justice for the Negro brought them into conflict with President Johnson, in whose impeachment they played a leading role. Although they succeeded in initiating congressional Reconstruction and adding the fourteenth and fifteenth amendments to the Constitution, the Radicals lost power after the failure of the Johnson impeachment. Mr. Trefousse shows how, despite their declining influence throughout the 1870s, their accomplishments helped make possible—a century later—the resumption of the struggle for civil rights.
Download or read book Free Radical Induced DNA Damage and Its Repair written by Clemens Sonntag and published by Springer Science & Business Media. This book was released on 2006-03-20 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: The free-radical chemistry of DNA had been discussed in some detail in 1987 in my book The Chemical Basis of Radiation Biology. Obviously, the more recent developments and the concomitant higher level of understanding of mechanistic details are missing. Moreover, in the living cell, free-radical DNA damage is not only induced by ionizing radiation, but free-radical-induced DNA damage is a much more general phenomenon. It was, therefore, felt that it is now timely to review our present knowledge of free-radical-induced DNA damage induced by all conceivable free-radical-generating sources. Originally, it had been thought to include also a very important aspect, the repair of DNA damage by the cell’s various repair enzymes. Kevin Prise (Cancer Campaign, Gray Laboratory, L- don) was so kind to agree to write this part. However, an adequate description of this strongly expanding area would have exceeded the allocated space by much, and this section had to be omitted. The directors of the Max-Planck-Institut für Strahlenchemie (now MPI für Bioanorganische Chemie), Karl Wieghardt and Wolfgang Lubitz, kindly allowed me to continue to use its facilities after my retirement in 2001. Notably, our - brarian, Mrs. Jutta Theurich, and her right-hand help, Mrs. Rosemarie Schr- er, were most helpful in getting hold of the literature. I thank them very much. Without their constant help, this would have been very difficult indeed.
