Download or read book Compounds of the Transition Elements Involving Metal Metal Bonds written by D. L. Kepert and published by Elsevier. This book was released on 2016-06-06 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: Compounds of the Transition Elements Involving Metal-Metal Bonds focuses on compounds of the transition elements involving metal-metal bonds. Emphasis is on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. Factors that influence the formation, stability, and properties of such compounds, as well as their application in various fields of chemistry and physics, are discussed. This book is divided into four sections and begins with a classification of metal-metal bonds and some of the physical and chemical methods used to study them, including X-ray crystallography, magnetic susceptibility and electron spin resonance, nuclear spin resonance, Mössbauer measurements, infrared and Raman spectroscopy, visible and ultraviolet spectroscopy, mass spectrometry, electrical conductivity, electrochemistry, and chemical reactivity. Factors influencing the strength of metal-metal bonds in metals and compounds are also examined. The remaining sections deal with metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. This monograph will be a useful resource for inorganic chemists.
Download or read book Compounds of the Transition Elements Involving Metal metal Bonds written by David L. Kepert and published by Pergamon. This book was released on 1975 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: Compounds of the Transition Elements Involving Metal-Metal Bonds deals with compounds of the transition elements involving metal-metal bonds, with particular emphasis on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. Factors that influence the formation, stability, and properties of such compounds, as well as their application in various fields of chemistry and physics, are discussed. This book is divided into four sections and begins with a classification of metal-metal bonds and some of the physical and chemical methods used to study them, inc...
Download or read book Organometallic Chemistry of the Transition Elements written by Florian P. Pruchnik and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry belongs to the most rapidly developing area of chemistry today. This is due to the fact that research dealing with the structure of compounds and chemical bonding has been greatly intensified in recent years. Additionally, organometallic compounds have been widely utilized in catalysis, organic synthesis, electronics, etc. This book is based on my lectures concerning basic organometallic chemistry for fourth and fifth year chemistry students and on my lectures concerning advanced organometallic chemistry and homogeneous catalysis for Ph.D. graduate students. Many recent developments in the area of organometallic chemistry as weIl as homogeneous catalysis are presented. Essential research results dealing with a given class of organometallic compounds are discussed briefly. Results of physicochemical research methods of various organometallic compounds as weIl as their synthesis, properties, structures, reactivities, and applications are discussed more thoroughly. The selection of tabulated data is arbitrary because, often, it has been impossible to avoid omissions. Nevertheless, these data can be very helpful in understanding properties of organometaIlic compounds and their reactivities. All physical data are given in SI units; the interatomic distances are given in pm units in figures and tables. I am indebted to Professor S. A. Duraj for translating and editing this book. His remarks, discussions, and suggestions are greatly appreciated. I also express gratitude to Virginia E. Duraj for editing and proofreading.
Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2018-10-03 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Download or read book Inorganic Reactions and Methods The Formation of Bonds to Transition and Inner Transition Metals written by A. P. Hagen and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 727 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boasting numerous industrial applications, inorganic chemistry forms the basis for research into new materials and bioinorganic compounds such as calcium that act as biological catalysts. Now complete, this highly acclaimed series presents current knowledge in all areas of inorganic chemistry, including chemistry of the elements; organometallic, polymeric and solid-state materials; and compounds relevant to bioinorganic chemistry.
Download or read book Compounds of Transition Metals written by Michael Dub and published by Springer. This book was released on 2013-12-01 with total page 845 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this Compilation has been to provide a comprehensive, non critical source of information concerning organometallic compounds. The scope is limited to the compounds containing at least one carbon-metal bond. The information includes methods of preparation, properties, chemical reactions and applications. The First Edition comprised the literature from 1937 to 1958. The Second Edition is completely revised and extended through 1964. The literature prior to 1937 was thoroughly covered by E. Krause and A. von Grosse in 11 11 Die Chemie der metall-organischen Verbindungen, Verlag von Gebrueder Borntraeger, Berlin, 1937. Our work consists of three volumes. Volume I contains derivatives of the transition metals of Groups III through VIII of the Periodic Table. Volume II contains derivatives of germanium, tin and lead. Volume Ill contains derivatives of arsenic, antimony and bismuth. The Compilation is based on searches through Chemical Abstracts. The collection of references for 1964 was completed before the Subject Indexes to Volumes 60 and 61 of the Abstracts were available; thus some omissions in the coverage of that year are possible. We have attempted to make the coverage of the literature complete in order that the Compilation may have best utility to the chemist, chemical engineer, patent attorney and editor. In the interest of brevity, certain numerical data are omitted, but references to the original literature are given. Yield data are rounded to two significant figures. Wherever possible, tables have been used. The entries in the Bibliography section include references to Chemical Abstracts.
Download or read book Introduction to Metal Complex Chemistry written by M. Tsutsui and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Plenum Press series, Monographs in Inorganic Chemistry, is intended to fill an obvious need for high-level surveys of recent research in that area, particularly in matters which go beyond the traditional or classical bound aries of the subject. The study of n-bonding of hydrocarbon groups (and their derivatives) to metals is exactly that kind of subject, for it provides a new way of understanding the behavior of metals (which constitute four-fifths of all the chemical elements). In addition, n-bonding has expanded the intriguing area of organometallic chemistry threefold, bringing in all the transition metals, the lanthanides, and the actinides. So much has been discovered and developed in the area of n-bonded "complexes" of the metals that important new industrial processes based on such substances have been developed. A truly comprehensive review of all n-bonded compounds of the metals would now result in an impossibly large and expensive volume, and would require monthly revision. Instead, the present authors have wisely decided to write a survey which outlines the general aspects of preparation, properties, structure, reactions, and uses of such compounds-a survey which can serve as a textbook, but which can also lead the more experienced practitioner to the most advanced literature on the subject. They have clarified and condensed the subject by means of good organization and a liberal use of diagrams-features which will please the general reader.
Download or read book Quantum Chemistry The Challenge of Transition Metals and Coordination Chemistry written by A. Veillard and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last twenty years, developments of the ab initio metho dologies and of the computing capacities have progressively turned quantum chemistry into a predictive tool for molecular systems involving only light elements. The situation appears less advanced for systems containing transition metal elements where specific difficulties arise, like those 1inked to the quasi-degeneracy of the lowest atomic states. Correlation effects, which are important only for quantitative accuracy in the treatment of molecules made of light elements, need sometimes to be considered even for a qualitative des cription of transition metals systems (like the multiple metal-metal bond). The treatment of atoms of a high atomic number has necessited the development of model potential methods. These difficulties ex acerbate for systems containing several trans ition atoms a correct description of the dichromium molecule Crz still represents a challenge to quantum chemists. Yet many advances have been made recently in the theoretical treatment of these systems, despite the fact that our understanding still remains disparate with a variety of models and methodologies used more or less successfully (one-electron models, explicitly correlated ab initio methods, density functional formalisms). For these reasons, a NATO Advanced Research Workshop was organized to review in detail the state-of-the-art techniques and at the same time the most common applications. These encompass many fields including the spectroscopy of diatomics and small aggregates, structure and reactivity problems in organometallic chemistry, the cluster surface analogy with its implications for heterogeneous catalysis and the description of extended structures.
Download or read book Transition Metal Compounds written by Sajjad Haider and published by BoD – Books on Demand. This book was released on 2021-06-09 with total page 121 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explores synthesis, structural changes, properties, and potential applications of transition metal (TM) compounds. Over three sections, chapters cover such topics as the synthesis of pentoxide vanadium (V2O5), the effect of TM compounds on structural, dielectric properties and high-temperature superconductors, and TM-doped nanocrystals (NCs).
Download or read book Transition Metal Compounds written by Daniel I. Khomskii and published by Cambridge University Press. This book was released on 2014-10-23 with total page 501 pages. Available in PDF, EPUB and Kindle. Book excerpt: Describing all aspects of the physics of transition metal compounds, this book provides a comprehensive overview of this unique and diverse class of solids. Beginning with the basic concepts of the physics of strongly correlated electron systems, the structure of transition metal ions, and the behaviours of transition metal ions in crystals, it goes on to cover more advanced topics such as metal-insulator transitions, orbital ordering, and novel phenomena such as multiferroics, systems with oxygen holes, and high-Tc superconductivity. Each chapter concludes with a summary of key facts and concepts, presenting all the most important information in a consistent and concise manner. Set within a modern conceptual framework, and providing a complete treatment of the fundamental factors and mechanisms that determine the properties of transition metal compounds, this is an invaluable resource for graduate students, researchers and industrial practitioners in solid state physics and chemistry, materials science, and inorganic chemistry.
Download or read book Molecular Metal Metal Bonds written by Stephen T. Liddle and published by John Wiley & Sons. This book was released on 2016-03-16 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.
Download or read book The Heavy Transition Elements written by S. A. Cotton and published by John Wiley & Sons. This book was released on 1975 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemistry Of Transition Elements written by M. Satake & Y. Mido and published by Discovery Publishing House. This book was released on 2010 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: The Properties of Transition Elements, Titanium, Zirconium and Hafnium Group IV A, Vanadium, Niobium and Tantalum Group V A, Chromium, Molybdenum and Tungsten Group VI A, Manganese, Technetium and Rhenium Group VII A, Iron, Cobalt and Nickel, The Platinum Metals, Copper, Silver and Gold Group IB, Analytical and Biological Aspects of Transition Metals, Coordination Compounds, Lanthanides & Actinides.
Download or read book Concepts in Transition Metal Chemistry written by Eleanor Crabb and published by . This book was released on 2010 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt: An introduction to transition metals, examining the behaviour of the metals and their aqueous ions and complexes, complete with The Periodic Table DVD.
Download or read book Metal Ligand Multiple Bonds written by William A. Nugent and published by Wiley-Interscience. This book was released on 1988-11-14 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only comprehensive one-volume text/reference on metal-ligand multiple bonds. Stresses the unified nature of the field and includes handy new tabulations of data. The flow within each subtopic is oxygen to nitrogen to carbon. Coverage is up-to-date--virtually every subtopic leads to interesting questions for future research. Presents information otherwise scattered through hundreds of publications.
Download or read book Transition Metals in the Synthesis of Complex Organic Molecules written by Louis S. Hegedus and published by University Science Books. This book was released on 1999 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
Download or read book Crystal Chemistry and Semiconduction in Transition Metal Binary Compounds written by J Suchet and published by Elsevier. This book was released on 2012-12-02 with total page 401 pages. Available in PDF, EPUB and Kindle. Book excerpt: Crystal Chemistry and Semiconduction in Transition Metal Binary Compounds provides information pertinent to semiconductor materials. This book discusses the different semiconduction mechanisms in special compounds, including rare earth compounds or transition metals, vitreous or liquid substances, and organic semiconductors. Organized into three parts encompassing 11 chapters, this book starts with an overview of the basic principles of chemistry, such as the periodic table and the structure of the atom. This text then discusses the substances in which atomic magnetic moment exists, and whose transport properties are not typically metallic. Other chapters examine the experimental work on the electrical conductibility of compounds of transition metals, actinides, or rare earths. This book discusses as well the theoretical concepts necessary for the construction of approximate models to estimate the properties of compounds. The final chapter deals with the modulation of visible or infrared light, which is the only application of magneto- and electro-optical effects. This book is a valuable resource for research scientists, engineers, and teachers.
