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Book Absorption Based Post Combustion Capture of Carbon Dioxide

Download or read book Absorption Based Post Combustion Capture of Carbon Dioxide written by Paul Feron and published by Woodhead Publishing. This book was released on 2016-05-27 with total page 816 pages. Available in PDF, EPUB and Kindle. Book excerpt: Absorption-Based Post-Combustion Capture of Carbon Dioxide provides a comprehensive and authoritative review of the use of absorbents for post-combustion capture of carbon dioxide. As fossil fuel-based power generation technologies are likely to remain key in the future, at least in the short- and medium-term, carbon capture and storage will be a critical greenhouse gas reduction technique. Post-combustion capture involves the removal of carbon dioxide from flue gases after fuel combustion, meaning that carbon dioxide can then be compressed and cooled to form a safely transportable liquid that can be stored underground. - Provides researchers in academia and industry with an authoritative overview of the amine-based methods for carbon dioxide capture from flue gases and related processes - Editors and contributors are well known experts in the field - Presents the first book on this specific topic

Book Carbon Dioxide Removal from Coal Fired Power Plants

Download or read book Carbon Dioxide Removal from Coal Fired Power Plants written by C. Hendriks and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: 1. 1. Greenhouse gas emissions and climate change . . . . . . . . . . . . . . 3 1. 1. 1. Emissions and concentrations of greenhouse gases 3 1. 1. 2. Impact of increasing greenhouse gases concentration 4 1. 2. Options to reduce carbon dioxide emissions 5 1. 2. 1. Carbon dioxide removal 8 1. 3. Scope of the thesis 10 1. 4. Outline of the thesis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 1. 4. 1. General evaluation method. . . . . . . . . . . . . . . . . . . . . . . 12 1. 4. 2. Some notes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 II. Simulation and optimization of carbon dioxide recovery from the flue gases of a coal-fired power plant using amines 14 Abstract 19 2. 1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 2. 2. The chemical absorption process. . . . . . . . . . . . . . . . . . . . . . . . 22 2. 2. 1. General process description. . . . . . . . . . . . . . . . . . . . . . . 22 2. 2. 2. Types of absorbent 23 2. 2. 3. Effects of flue gas contaminants 24 2. 3. Simulation of the scrubber in ASPEN PLUS . . . . . . . . . . . . . . . . . 25 2. 3. 1. ASPEN PLUS for flow sheet simulation 26 2. 3. 2. Simulation of the performance for the base-case design . . 26 the scrubber . . . . . . . . . . . . . . . . . . . . . . 29 2. 3. 3. Optimization of 2. 3. 4. Design and results 32 2. 3. 5. Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 2. 4. Integration of the scrubber in the power plant 35 2. 4. 1. Power loss caused by steam extraction 36 2. 4. 2. Power saved by avoiding preheating boiler feed water . . . 38 2. 4. 3. Power consumption by the carbon dioxide scrubber . . . . . 38 2. 4. 4. Power consumption for carbon dioxide compression . . . . . 38 2. 4. 5. Calculation of plant efficiency losses " . . . . . . . . . . . . . . 39 2. 5.

Book Carbon Dioxide Emission Management in Power Generation

Download or read book Carbon Dioxide Emission Management in Power Generation written by Prof. Lars O. Nord and published by John Wiley & Sons. This book was released on 2020-04-27 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides an engaging and clearly structured source of information on the capture and storage of CO2 Designed to bridge the gap between the many disciplines involved in carbon dioxide emission management, this book provides a comprehensive yet easy-to-understand introduction to the subject of CO2 capture. Fit for graduate students, practicing process engineers, and others interested in the subject, it offers a clear understanding and overview of thermal power plants in particular and of carbon dioxide capture and storage (CCS) in general. Carbon Dioxide Emission Management in Power Generation starts with a discussion of the greenhouse effect, climate change, and CO2 emissions as the rationale for the concept of CCS. It then looks at the long-term storage of CO2. A chapter covering different fossil fuels, their usage, and properties comes next, followed by sections on: CO2 generation, usage and properties; power plant technologies; theory of gas separation; power plant efficiency calculations; and classification of CO2 capture methods. Other chapters examine: CO2 capture by gas absorption and other gas separation methods; removing carbon from the fuel; pre- and post-combustion CO2 capture in power cycles; and oxy-combustion CO2 capture in power cycles. -Discusses both CO2 capture technologies as well as power generation technologies -Bridges the gap between many different disciplines?from scientists, geologists and engineers, to economists -One of the few books that covers all the different sciences involved in the capture and storage of CO2 -Introduces the topic and provides useful information to the academic as well as professional reader Carbon Dioxide Emission Management in Power Generation is an excellent book for students who are interested in CO2 capture and storage, as well as for chemists in industry, environmental chemists, chemical engineers, geochemists, and geologists.

Book Oxy Fuel Combustion for Power Generation and Carbon Dioxide  CO2  Capture

Download or read book Oxy Fuel Combustion for Power Generation and Carbon Dioxide CO2 Capture written by L Zheng and published by Elsevier. This book was released on 2011-02-26 with total page 397 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxy-fuel combustion is currently considered to be one of the major technologies for carbon dioxide (CO2) capture in power plants. The advantages of using oxygen (O2) instead of air for combustion include a CO2-enriched flue gas that is ready for sequestration following purification and low NOx emissions. This simple and elegant technology has attracted considerable attention since the late 1990s, rapidly developing from pilot-scale testing to industrial demonstration. Challenges remain, as O2 supply and CO2 capture create significant energy penalties that must be reduced through overall system optimisation and the development of new processes.Oxy-fuel combustion for power generation and carbon dioxide (CO2) capture comprehensively reviews the fundamental principles and development of oxy-fuel combustion in fossil-fuel fired utility boilers. Following a foreword by Professor János M. Beér, the book opens with an overview of oxy-fuel combustion technology and its role in a carbon-constrained environment. Part one introduces oxy-fuel combustion further, with a chapter comparing the economics of oxy-fuel vs. post-/pre-combustion CO2 capture, followed by chapters on plant operation, industrial scale demonstrations, and circulating fluidized bed combustion. Part two critically reviews oxy-fuel combustion fundamentals, such as ignition and flame stability, burner design, emissions and heat transfer characteristics, concluding with chapters on O2 production and CO2 compression and purification technologies. Finally, part three explores advanced concepts and developments, such as near-zero flue gas recycle and high-pressure systems, as well as chemical looping combustion and utilisation of gaseous fuel.With its distinguished editor and internationally renowned contributors, Oxy-fuel combustion for power generation and carbon dioxide (CO2) capture provides a rich resource for power plant designers, operators, and engineers, as well as academics and researchers in the field. - Comprehensively reviews the fundamental principles and development of oxy-fuel combustion in fossil-fuel fired utility boilers - Provides an overview of oxy-fuel combustion technology and its role in a carbon-constrained environment - Introduces oxy-fuel combustion comparing the economics of oxy-fuel vs. post-/pre-combustion CO2 capture

Book Negative Emissions Technologies and Reliable Sequestration

Download or read book Negative Emissions Technologies and Reliable Sequestration written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2019-04-08 with total page 511 pages. Available in PDF, EPUB and Kindle. Book excerpt: To achieve goals for climate and economic growth, "negative emissions technologies" (NETs) that remove and sequester carbon dioxide from the air will need to play a significant role in mitigating climate change. Unlike carbon capture and storage technologies that remove carbon dioxide emissions directly from large point sources such as coal power plants, NETs remove carbon dioxide directly from the atmosphere or enhance natural carbon sinks. Storing the carbon dioxide from NETs has the same impact on the atmosphere and climate as simultaneously preventing an equal amount of carbon dioxide from being emitted. Recent analyses found that deploying NETs may be less expensive and less disruptive than reducing some emissions, such as a substantial portion of agricultural and land-use emissions and some transportation emissions. In 2015, the National Academies published Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration, which described and initially assessed NETs and sequestration technologies. This report acknowledged the relative paucity of research on NETs and recommended development of a research agenda that covers all aspects of NETs from fundamental science to full-scale deployment. To address this need, Negative Emissions Technologies and Reliable Sequestration: A Research Agenda assesses the benefits, risks, and "sustainable scale potential" for NETs and sequestration. This report also defines the essential components of a research and development program, including its estimated costs and potential impact.

Book Cost Analysis of Controlling Carbon Dioxide Flue Gas Emissions from Canadian Power Utilities

Download or read book Cost Analysis of Controlling Carbon Dioxide Flue Gas Emissions from Canadian Power Utilities written by Canada. Environment Canada and published by . This book was released on 1992 with total page 80 pages. Available in PDF, EPUB and Kindle. Book excerpt: Evaluation of currently available technologies for removing and disposing of carbon dioxide from fossil fuel power plants, including their feasibility, stage of development, effect on the environment, and applicability in Canada. The most feasible technologies were then incorporated into a utility computer simulation model (CANSIM) in which it was assumed that the CO2 is removed by a solvent, compressed, and disposed of either by injection to deep ocean or by precipitation of carbonates from brine aquifers. Costs of the technologies are also included.

Book CO2 Capture

Download or read book CO2 Capture written by Fabrice Lecomte and published by Editions TECHNIP. This book was released on 2010 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt: CO2 capture and geological storage (CCS) is now recognised as being one of the pathways that can be implemented to reduce CO2 emissions and fight against global warming. But where, how and at what price can CO2 be captured? This book attempts to provide the answers to these questions, reviewing the state of the art of the technologies required. It presents the three main pathways considered in which the CO2 capture technologies are expected to be implemented, respectively: the post-combustion pathway, in which the CO2 contained in industrial flue gases is extracted; the oxy-combustion pathway, in which combustion is performed in oxygen to obtain flue gases with high CO2 concentration; and lastly the pre-combustion pathway, in which carbon is extracted from the initial fuel to generate hydrogen, whose combustion will produce only water vapour. The book introduces, for each pathway, the technologies currently available and those under development. It is intended for everyone wanting to gain a better understanding of the mechanisms implemented in CO2 capture operations, as well as the technological and economic challenges to be met to ensure that the costs generated by these operations are no longer an obstacle to their worldwide generalisation.Contents: 1. Why capture and store CO2? Global warming. How to reduce CO2 emissions. Main links of the CCS chain. 2. Where capture CO2? CO2 fixed emission sources worldwide. Fixed sources in France. CO2 capture potential in France. 3. Post-Combustion CO2 capture. Principles and stakes. Characteristics of post-combustion flue gases. Separation techniques potentially suitable for post-combustion CO2 capture. Technologies under development for post-combustion CO2 Capture. CO2 conditioning. Conclusion. 4. Oxy-combustion CO2 capture. Principles and stakes. Oxy-combustion. Chemical looping combustion. CO2 conditioning. Demonstrations. 5. Pre-combustion CO2 capture. Principles and stakes. Syngas production. Water-gas shift reaction. CO2 extraction. CO2 conditioning. Hydrogen combustion. Integrated power production processes with pre-combustion CO2 capture. 6. Capture and store CO2: at what cost? Calculation bases. CO2 capture costs. CO2 transport costs. CO2 storage costs. Trend in the cost of the CCS chain - Power production. Variability of CCS chain costs. Application to existing installations. Conclusion. Appendix.

Book Climate Intervention

    Book Details:
  • Author : National Research Council
  • Publisher : National Academies Press
  • Release : 2015-06-17
  • ISBN : 0309305322
  • Pages : 235 pages

Download or read book Climate Intervention written by National Research Council and published by National Academies Press. This book was released on 2015-06-17 with total page 235 pages. Available in PDF, EPUB and Kindle. Book excerpt: The signals are everywhere that our planet is experiencing significant climate change. It is clear that we need to reduce the emissions of carbon dioxide and other greenhouse gases from our atmosphere if we want to avoid greatly increased risk of damage from climate change. Aggressively pursuing a program of emissions abatement or mitigation will show results over a timescale of many decades. How do we actively remove carbon dioxide from the atmosphere to make a bigger difference more quickly? As one of a two-book report, this volume of Climate Intervention discusses CDR, the carbon dioxide removal of greenhouse gas emissions from the atmosphere and sequestration of it in perpetuity. Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration introduces possible CDR approaches and then discusses them in depth. Land management practices, such as low-till agriculture, reforestation and afforestation, ocean iron fertilization, and land-and-ocean-based accelerated weathering, could amplify the rates of processes that are already occurring as part of the natural carbon cycle. Other CDR approaches, such as bioenergy with carbon capture and sequestration, direct air capture and sequestration, and traditional carbon capture and sequestration, seek to capture CO2 from the atmosphere and dispose of it by pumping it underground at high pressure. This book looks at the pros and cons of these options and estimates possible rates of removal and total amounts that might be removed via these methods. With whatever portfolio of technologies the transition is achieved, eliminating the carbon dioxide emissions from the global energy and transportation systems will pose an enormous technical, economic, and social challenge that will likely take decades of concerted effort to achieve. Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration will help to better understand the potential cost and performance of CDR strategies to inform debate and decision making as we work to stabilize and reduce atmospheric concentrations of carbon dioxide.

Book Energy Efficient Solvents for CO2 Capture by Gas Liquid Absorption

Download or read book Energy Efficient Solvents for CO2 Capture by Gas Liquid Absorption written by Wojciech M. Budzianowski and published by Springer. This book was released on 2016-12-01 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reviews and characterises promising single-compound solvents, solvent blends and advanced solvent systems suitable for CO2 capture applications using gas-liquid absorption. Focusing on energy efficient solvents with minimal adverse environmental impact, the contributions included analyse the major technological advantages, as well as research and development challenges of promising solvents and solvent systems in various sustainable CO2 capture applications. It provides a valuable source of information for undergraduate and postgraduate students, as well as for chemical engineers and energy specialists.

Book Carbon Capture

    Book Details:
  • Author : Jennifer Wilcox
  • Publisher : Springer Science & Business Media
  • Release : 2012-03-28
  • ISBN : 1461422140
  • Pages : 337 pages

Download or read book Carbon Capture written by Jennifer Wilcox and published by Springer Science & Business Media. This book was released on 2012-03-28 with total page 337 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book approaches the energy science sub-field carbon capture with an interdisciplinary discussion based upon fundamental chemical concepts ranging from thermodynamics, combustion, kinetics, mass transfer, material properties, and the relationship between the chemistry and process of carbon capture technologies. Energy science itself is a broad field that spans many disciplines -- policy, mathematics, physical chemistry, chemical engineering, geology, materials science and mineralogy -- and the author has selected the material, as well as end-of-chapter problems and policy discussions, that provide the necessary tools to interested students.

Book CO2 Removal from Flue Gases in Power Generation

Download or read book CO2 Removal from Flue Gases in Power Generation written by and published by . This book was released on 2004 with total page 69 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Advanced CO2 Capture Technologies

Download or read book Advanced CO2 Capture Technologies written by Shin-ichi Nakao and published by Springer. This book was released on 2019-05-07 with total page 90 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarises the advanced CO2 capture technologies that can be used to reduce greenhouse gas emissions, especially those from large-scale sources, such as power-generation and steel-making plants. Focusing on the fundamental chemistry and chemical processes, as well as advanced technologies, including absorption and adsorption, it also discusses other aspects of the major CO2 capture methods: membrane separation; the basic chemistry and process for CO2 capture; the development of materials and processes; and practical applications, based on the authors’ R&D experience. This book serves as a valuable reference resource for researchers, teachers and students interested in CO2 problems, providing essential information on how to capture CO2 from various types of gases efficiently. It is also of interest to practitioners and academics, as it discusses the performance of the latest technologies applied in large-scale emission sources.

Book CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

Download or read book CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS written by and published by . This book was released on 2002 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fossil fuels used for power generation, transportation, and by industry are the primary source of anthropogenic CO2 emissions to the atmosphere. Much of the CO2 emission reduction effort will focus on large point sources, with fossil fuel fired power plants being a prime target. The CO2 content of power plant flue gas varies from 4% to 9% (vol), depending on the type of fossil fuel used and on operating conditions. Although new power generation concepts that may result in CO2 control with minimal economic penalty are under development, these concepts are not generally applicable to the large number of existing power plants.

Book Carbon Dioxide Emission Management in Power Generation

Download or read book Carbon Dioxide Emission Management in Power Generation written by Olav Bolland and published by Wiley-VCH. This book was released on 2020-04-03 with total page 1050 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides an engaging and clearly structured source of information on the capture and storage of CO2 Designed to bridge the gap between the many disciplines involved in carbon dioxide emission management, this book provides a comprehensive yet easy-to-understand introduction to the subject of CO2 capture. Fit for graduate students, practicing process engineers, and others interested in the subject, it offers a clear understanding and overview of thermal power plants in particular and of carbon dioxide capture and storage (CCS) in general. Carbon Dioxide Emission Management in Power Generation starts with a discussion of the greenhouse effect, climate change, and CO2 emissions as the rationale for the concept of CCS. It then looks at the long-term storage of CO2. A chapter covering different fossil fuels, their usage, and properties comes next, followed by sections on: CO2 generation, usage and properties; power plant technologies; theory of gas separation; power plant efficiency calculations; and classification of CO2 capture methods. Other chapters examine: CO2 capture by gas absorption and other gas separation methods; removing carbon from the fuel; pre- and post-combustion CO2 capture in power cycles; and oxy-combustion CO2 capture in power cycles. -Discusses both CO2 capture technologies as well as power generation technologies -Bridges the gap between many different disciplines?from scientists, geologists and engineers, to economists -One of the few books that covers all the different sciences involved in the capture and storage of CO2 -Introduces the topic and provides useful information to the academic as well as professional reader Carbon Dioxide Emission Management in Power Generation is an excellent book for students who are interested in CO2 capture and storage, as well as for chemists in industry, environmental chemists, chemical engineers, geochemists, and geologists.

Book Carbon Capture Technologies for Gas Turbine Based Power Plants

Download or read book Carbon Capture Technologies for Gas Turbine Based Power Plants written by Hamidreza Gohari Darabkhani and published by Elsevier. This book was released on 2022-09-24 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon Capture Technologies for Gas-Turbine-Based Power Plants explores current progress in one of the most capable technologies for carbon capture in gas-turbine-based power plants. It identifies the primary benefits and shortcomings of oxy-fuel combustion CO2 capture technology compared to other capture technologies such as pre-combustion and post-combustion capture. This book examines over 20 different oxy-combustion turbine (oxyturbine) power cycles by providing their main operational parameters, thermodynamics and process modelling, energy and exergy analysis and performance evaluation. The conventional natural gas combined cycle (NGCC) power plant with post-combustion capture used as the base-case scenario. The design procedure and operational characteristics of a radial NOx-less oxy-fuel gas turbine combustor are presented with CFD simulation and performance analysis of the heat exchanger network and turbomachinery. Overview of oxygen production and air separation units (ASU) and CO2 compression and purification units (CPU) are also presented and discussed. The most advanced stages of development for the leading oxyturbine power cycles are assessed using techno-economic analysis, sensitivity, risk assessments and levelized cost of energy (LCOE) and analysing technology readiness level (TRL) and development stages. The book concludes with a road map for the development of future gas turbine-based power plants with full carbon capture capabilities using the experiences of the recently demonstrated cycles. - Analyzes more than 20 models of oxyturbine power cycles, identifying the main parameters regarding their operation, process and performance simulations and energy and exergy analysis - Provides techno-economic analysis, TRL, sensitivity and risk analysis, LCOE and stages of development for oxy-combustion turbine power plants - Presents the design procedure and CFD simulation of a radial NOx-less oxy-fuel gas turbine combustor exploring its influence on heat exchanger network and turbomachinery - Supports practitioners, policymakers and energy industry managers seeking pathways to convert coal-fired power plants to gas-fired plants with zero CO2 emission

Book Carbon Capture and Storage Including Coal fired Power Plants

Download or read book Carbon Capture and Storage Including Coal fired Power Plants written by Todd P. Carington and published by . This book was released on 2010 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nationally-recognised studies and our contacts with a diverse group of industry representatives, non-governmental organisations, and academic researchers show that key barriers to CCS deployment include (1) underdeveloped and costly CO2 capture technology and (2) regulatory and legal uncertainties over CO2 capture, injection, and storage. Among the key technological barriers are a lack of experience in capturing significant amounts of CO2 from power plants and the significant cost of capturing CO2, particularly from existing coal-fired power plants, which are the single largest source of CO2 emissions in the United States. Compounding these technological issues are regulatory and legal uncertainties, including uncertainty regarding liability for CO2 leakage and ownership of CO2 once injected. According to the IPCC, the National Academy of Sciences, and other knowledgeable authorities, another barrier is the absence of a national strategy to control CO2 emissions (emissions trading plan, CO2 emissions tax, or other mandatory control of CO2 emissions), without which the electric utility industry has little incentive to capture and store its CO2 emissions. Moreover, according to key agency officials, the absence of a national strategy has also deterred their agencies from addressing other important practical issues, such as resolving how stored CO2 would be treated in a future CO2 emissions trading plan.

Book Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks

Download or read book Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: UOP LLC, a Honeywell Company, in collaboration with Professor Douglas LeVan at Vanderbilt University (VU), Professor Adam Matzger at the University of Michigan (UM), Professor Randall Snurr at Northwestern University (NU), and Professor Stefano Brandani at the University of Edinburgh (UE), supported by Honeywell's Specialty Materials business unit and the Electric Power Research Institute (EPRI), have completed a three-year project to develop novel microporous metal organic frameworks (MOFs) and an associated vacuum-pressure swing adsorption (vPSA) process for the removal of CO2 from coal-fired power plant flue gas. The project leveraged the team's complementary capabilities: UOP's experience in materials development and manufacturing, adsorption process design and process commercialization; LeVan and Brandani's expertise in high-quality adsorption measurements; Matzger's experience in syntheis of MOFs and the organic components associated with MOFs; Snurr's expertise in molecular and other modeling; Honeywell's expertise in the manufacture of organic chemicals; and, EPRI's knowledge of power-generation technology and markets. The project was successful in that a selective CO2 adsorbent with good thermal stability and reasonable contaminant tolerance was discovered, and a low cost process for flue gas CO2 capture process ready to be evaluated further at the pilot scale was proposed. The team made significant progress toward the current DOE post-combustion research targets, as defined in a recent FOA issued by NETL: 90% CO2 removal with no more than a 35% increase in COE. The team discovered that favorable CO2 adsorption at more realistic flue gas conditions is dominated by one particular MOF structure type, M/DOBDC, where M designates Zn, Co, Ni, or Mg and DOBDC refers to the form of the organic linker in the resultant MOF structure, dioxybenzenedicarboxylate. The structure of the M/DOBDC MOFs consists of infinite-rod secondary building units bound by DOBDC resulting in 1D hexagonal pores about 11 angstroms in diameter. Surface areas range from 800 to 1500 sq m/g for the different MOFs. Mg/DOBDC outperformed all MOF and zeolite materials evaluated to date, with about 25 wt% CO2 captured by this MOF at flue gas conditions ((almost equal to)0.13 atm CO2 pressure, 311K). In simulated flue gas without oxygen, the zero-length (ZLC) system was very useful in quickly simulating the effect of long term exposure to impurities on the MOFs. Detailed adsorption studies on MOF pellets have shown that water does not inhibit CO2 adsorption for MOFs as much as it does for typical zeolites. Moreover, some MOFs retain a substantial CO2 capacity even with a modest water loading at room temperature. Molecular modeling was a key activity in three areas of our earlier DOE/NETL-sponsored MOF-based research on CC. First, the team was able to effectively simulate CO2 and other gas adsorption isotherms for more than 20 MOFs, and the knowledge obtained was used to help predict new MOF structures that should be effective for CO2 adsorption at low pressure. The team also showed that molecular modeling could be utilized to predict the hydrothermal stability of a given MOF. Finally, the team showed that low moisture level exposure actually enhanced the CO2 adsorption performance of a particular MOF, HKUST-1.