Download or read book CO2 Adsorption Equilibria on 5A and 13X Molecular Sieves at Elevated Carrier Gas Pressures written by David T. Croft and published by . This book was released on 1997 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: An automated volumetric isotherm system capable of measuring adsorption equilibria of trace levels of contaminants from 1 to 10,000 ppm in carrier gas up to 3.5 x 10(exp 6) Pa has been developed. The system is a modified version of the volumetric isotherm system previously published by Mahle, et al. The system is used to measure isotherm data for CO2, a typical contaminant in both separation and purification processes, adsorbed on two commercially available adsorbents, 5A molecular sieve and 13X molecular sieve. These data are measured in the presence of air at pressures of 1.0 x 10(exp 5) Pa, 5.0 x 10 to the 5th power Pa, 2.5 x 10(exp 6) Pa, and at temperatures of 278 K, 298 K, and 317 K. Results show that air adsorbed at elevated pressures reduces the amount of CO2 adsorbed at a given partial pressure and temperature for both adsorbents. The effect of adsorbed air on the CO2 loading is greater for 5A molecular sieve than for the 13X molecular sieve. Data are correlated using the Dubinin- Radushkevich Equation, which fits the data very well at low pressure but becomes increasingly less representative at elevated pressures.
Download or read book CO2 Adsorption Equilibria on 5A and 13X Molecular Sieves at Elevated Carrier Gas Pressures written by David T. Croft and published by . This book was released on 1997 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Gas Adsorption Studies on Zeolithic Molecular Sieves written by William Owen Daly and published by . This book was released on 1977 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mathematical models for adsorption processes require experimental data on adsorption equilibria and kinetics. An experimental programme was carried out to obtain adsorption isotherm data for oxygen, nitrogen and carbon dioxide on Laporte 4A and 5A molecular sieve pellets and loose crystals over a range of temperatures from -78.5 to 50 C. Adsorption isotherms for oxygen and nitrogen on 4A and 5A pellets at pressures up to 95 bar were measured using a volumetric technique. Low pressure adsorption isotherms and rate data for oxygen, nitrogen and carbon dioxide were measured at pressures up to 1 bar using a gravimetric apparatus. Adsorption isotherm data were analysed using the well known Langmuir, Volmer and Hill-de Boer isotherm models and a new model proposed by the author.The Hill-de Boer model and the new model provided more satisfactory interpretations of the isotherm data. The four models were used to predict binary 02 -N2 equilibria on 5A sieves and the results were compared with published experimental data. Once again the Hill-de Boer model and the new model predicted more realistic results. Experimental rate data were measured by subjecting a small adsorbent sample to small step changes in gas pressure. The resulting transient response curves relating fractional uptake to time were analysed using Fick's law (assuming uniform spherical and cubic particles) to produce values of effective reduced diffusivities over ranges of temperature and concentration. The isotherm and diffusivity data were used to obtain limiting diffusivities at low concentrations which were correlated using Arrhenius type expressions.
Download or read book Development of Design Information for Molecular sieve Type Regenerative CO2 removal Systems written by R. M. Wright and published by . This book was released on 1973 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Equilibrium and Mass Transfer Behaviour of CO2 Adsorption on Zeolites Carbon Molecular Sieve and Activated Carbons written by Md Ariful Islam Sarker and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Adsorption Equilibria Between Oxygen nitrogen Mixtures and Linde Molecular Sieve 5 A written by Rachid Rahmani and published by . This book was released on 1978 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Sorption of Methane and Methane carbon Dioxide Mixtures of 5A and 13X Molecular Sieves at High Pressures and Ambient Temperatures Determined by Elution Chromatography written by Paul Douglas Rolniak and published by . This book was released on 1976 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Adsorption and Diffusion of Oxygen Nitrogen Methane and Argon in Molecular Sieve Carbons written by Yi Hua Ma and published by . This book was released on 1990 with total page 97 pages. Available in PDF, EPUB and Kindle. Book excerpt: Equilibrium adsorption and diffusion data for oxygen, nitrogen, methane and argon in carbon molecular sieves 3A and 5A at 0C, 30C and 50C were obtained at pressures up to 13 Bar using a high-pressure Cahn electrobalance. On a molar basis, methane had the highest adsorption capacity among the four gases studied both in 3A and 5A molecular sieve carbons. Oxygen and nitrogen had approximately the same equilibrium adsorption capacity. Equilibrium adsorption data were represented by a Langmuir equation and the Vacancy Solution Model (VSM). The VSM appears to give a good fit of the experimental data while the representation of the experimental data by the Langmuir equation showed deviation, especially at high pressures. The isosteric heats of adsorption were found to increase slightly with an increase in surface coverage. The values were slightly higher on 3A than on 5A for all the gases except argon. Kinetic data showed that oxygen has the highest diffusion rate and methane the lowest. Diffusivities increased with temperature. Keywords: Adsorption; Diffusion rate; Molecular sieve carbons; Langmuir equation; Vacancy solution model; Kinetic data; Isotherm; Isosteric heat of adsorption. (JES).
Download or read book Adsorption written by Jozsef Toth and published by CRC Press. This book was released on 2002-05-10 with total page 887 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text offers an overview of the recent theoretical and practical results achieved in gas-solid, liquid-solid and gas-liquid adsorption research.
Download or read book Adsorption Equilibria of Non Ideal and Azeotropic Gas Mixtures on Molecular Sieve and Activated Carbon at High Pressures written by B. Markmann and published by . This book was released on 1997 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Report of Investigations written by and published by . This book was released on 1963 with total page 938 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Selective Adsorption and Recovery of Sulfur Dioxide from Industrial Gases by Using Synthetic Zeolites written by D. A. Martin and published by . This book was released on 1963 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Some Generalized Probability Distributions with Special Reference to the Mineral Industries written by Alla D. Mah and published by . This book was released on 1963 with total page 688 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Gas Adsorption Equilibria written by Jürgen U. Keller and published by Springer Science & Business Media. This book was released on 2006-06-23 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is intended to present for the first time experimental methods to measure equilibria states of pure and mixed gases being adsorbed on the surface of solid materials. It has been written for engineers and scientists from industry and academia who are interested in adsorption based gas separation processes and/or in using gas adsorption for characterization of the porosity of solid materials. This book is the result of a fruitful collaboration of a theoretician (JUK) and an experimentalist (RS) over more than twelve years in the field of gas adsorption systems at the Institute of Fluid- and Thermodynamics (IFT) at the University of Siegen, Siegen, Germany. This collaboration resulted in the development of several new methods to measure not only pure gas adsorption, but gas mixture or coadsorption equilibria on inert porous solids. Also several new theoretical results could be achieved leading to new types of so-called adsorption isotherms based on the concepts of molecular association and – phenomenologically speaking – on that of thermodynamic phases of fractal dimension. Naturally, results of international collaboration of the authors over the years (1980-2000) also are included.
Download or read book Sorption Enhanced Reaction Processes written by Alírio E. Rodrigues and published by Wspc (Europe). This book was released on 2017-08 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book investigates the development of sorption enhanced reaction processes (SERPs) with detailed modelling and simulation, design and operation of units. SERPs are processes intensified by combining adsorption and reaction, reaction and membranes or reaction/adsorption/membranes in a single unit in order to overcome thermodynamic limitations of conversion in reversible reactions. The focus here is on gas phase and liquid phase processes involving different technologies, including pressure swing adsorptive reactors, membrane reactors and simulated moving bed reactors. Emphasis is also given to presenting data and practical applications of SERP products. Sorption Enhanced Reaction Processes provides undergraduate and graduate students of chemistry and chemical engineering, researchers and industrial engineers with a clear path towards process development of SERP, whatever the area of application.
Download or read book Advanced CO2 Capture Technologies written by Shin-ichi Nakao and published by Springer. This book was released on 2019-05-07 with total page 83 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarises the advanced CO2 capture technologies that can be used to reduce greenhouse gas emissions, especially those from large-scale sources, such as power-generation and steel-making plants. Focusing on the fundamental chemistry and chemical processes, as well as advanced technologies, including absorption and adsorption, it also discusses other aspects of the major CO2 capture methods: membrane separation; the basic chemistry and process for CO2 capture; the development of materials and processes; and practical applications, based on the authors’ R&D experience. This book serves as a valuable reference resource for researchers, teachers and students interested in CO2 problems, providing essential information on how to capture CO2 from various types of gases efficiently. It is also of interest to practitioners and academics, as it discusses the performance of the latest technologies applied in large-scale emission sources.
Download or read book Zeolites and Zeolite like Materials written by Bert Sels and published by Elsevier. This book was released on 2016-07-29 with total page 475 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites and Zeolite-like Materials offers a comprehensive and up-to-date review of the important areas of zeolite synthesis, characterization, and applications. Its chapters are written in an educational, easy-to-understand format for a generation of young zeolite chemists, especially those who are just starting research on the topic and need a reference that not only reflects the current state of zeolite research, but also identifies gaps and opportunities. The book demonstrates various applications of zeolites in heterogeneous catalysis and biomass conversion and identifies the endless possibilities that exist for this class of materials, their structures, functions, and future applications. In addition, it demonstrates that zeolite-like materials should be regarded as a living body developing towards new modern applications, thereby responding to the needs of modern technology challenges, including biomass conversion, medicine, laser techniques, and nanomaterial design, etc. The book will be of interest not only to zeolite-focused researchers, but also to a broad scientific and non-scientific audience. Provides a comprehensive review of the literature pertaining to zeolites and zeolite-like materials since 2000 Covers the chemistry of novel zeolite-like materials such as Metal-Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), hierarchical zeolite materials, new mesoporous and composite zeolite-like micro/mesoporous materials Presents essential information of the new zeolite-like structures, with a balanced coverage of the most important areas of the zeolite research (synthesis, characterization, adsorption, catalysis, new applications of zeolites and zeolite-like materials) Contains chapters prepared by known specialists who are members of the International Zeolite Association
