Download or read book Chromium II and Vanadium II Reductions of Some Mononuclear and Binuclear Cobalt III Complexes written by Michael Ross Hyde and published by . This book was released on 1973 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Nonbridging Ligand Effects in the Vanadium II Reductions of Some Cobalt III Complexes written by Peter Richard Guenther and published by . This book was released on 1968 with total page 94 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Reduction of Carboxylatopentaamminecobalt III Complexes by Chromium II and Vanadium II Ions written by Martha An Barcalow Barrett and published by . This book was released on 1968 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Vanadium II Reduction of Some Pentaamminecobalt III Complexes and Related Reactions written by Jean Chin-Chun Chen Thomas and published by . This book was released on 1975 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Chromium II and Vanadium II Ion Reductions of Oxyanion and Pyridinecarboxylic Acid Salts of Amminecobalt III Complexes written by David E. Peters and published by . This book was released on 1965 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Preparation and Characterisation of Carboxylato bridged Cobalt III Complexes and the Kinetics of Reduction by Chromium II and Vanadium II written by Keith Lawrence Scott and published by . This book was released on 1972 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Vanadium II Reduction of Mercaptide and Alkoxide Complexes of Cobalt III written by Peter Forrest Eisenhardt and published by . This book was released on 1971 with total page 122 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Competitive Reductions of Cobalt III Complexes by Tris 2 2 dipyridine chromium II Ion written by Bill Lauer and published by . This book was released on 1971 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Synthesis Characterization and Chromium II Reduction of Cobalt III Complexes Containing Thiolate Alcoholate and Thioether Residues written by Michael James Gilroy and published by . This book was released on 1971 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Preparation Characterization and Chromium II Reduction of Pentaamminecobalt III written by Robert J. Balahura and published by . This book was released on 1971 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chromium(II) reduction of a series of pentaammine- cobalt(III) complexes has been studied. A classification into inner- or outer-sphere paths has been made and the position of attack of the reductant on the ligand determined. The oxygen-bonded complexes of formamide, N,N-dimethylform- amide, dimethylsulfoxide, and urea as well as the nitrogen bonded N-cyanoguanidine complex are reduced by means of an outer-sphere mechanism. On the other hand ligand transfer was shown to occur in the reduction of (NH[subscript 3])[subscript 5]CoNHCHO[superscript 2+], (NH[subscript 3])[subscript 5]CoNCNH[superscript 2+], (NH[subscript 3])[subscript 5]CoO[subscript 2]CNH[subscript 2][superscript 2+], (NH[subscript 3])[subscript 5]CoO[subscript 2]CC[subscript 6]H[subscript 4]CN[superscript 2+], and (NH[subscript 3])[subscript 5]CoNCO[superscript 2+]. Both outer- and inner-sphere paths operate in the reduction of the nitrile bonded 4-cyanophenol complex, the inner-sphere path comprising 20% of the overall reaction. For the reduction of the terephthalonitrile complex a classification into an inner- or outer-sphere path cannot be made/ and an outer-sphere electron transfer to the ligand is postulated as the rate-determining step. A large part of the work has been concerned with the characterization of the complexes and Chapter III describes the spectroscopic measurements undertaken as well as the chemical reactions of some of the complexes. The acid dissociation constant of the N isomer of formamidopentaamine- cobalt(III), cyanamidopentaamminecobalt(III), and the nitrile bonded 4-cyanophenol have been determined. The protonation equilibrium constant for carbamatopentaammine- cobalt(III) was also obtained. A kinetic study of the acid hydrolysis of isocyanatopentaamminecobalt(III) to form hexaamminecobalt(III) and carbon dioxide was carried out. The acylation of the cyanamide and 4-cyanophenol complexes was also studied. The results of the kinetic studies of the chromium(II) reductions indicate a possible correlation between the reduction rate and the half-wave potential for the reduction of the free ligand. The studies have led to the following generalizations regarding electron transfer reactions: (1) attack of reductant at a coordinated atom does not occur, (2) the atom attached to chromium(II) in the transition state must have two lone pairs of electrons, and (3) the reducibility of the complexed ligand plays an important role in the detailed mechanism for the transfer of the electron.
Download or read book A Spectrophotometric Study of Certain Cobalt III and Chromium II Complexes written by Ronald Arlen Garber and published by . This book was released on 1964 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Reactions of Some Mononuclear and Binuclear Cobalt III Complexes in Aqueous Solution written by Julian David Edwards and published by . This book was released on 1974 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Inorganic Reaction Mechanisms Part 1 Volume 13 written by John O. Edwards and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.
Download or read book Reduction of E D T A and Related Complexes of Cobalt III by Iron II and Chromium II in Aqueous Solution written by P. B. Wood and published by . This book was released on 1964 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Reductions of Substituted Pyridinepentaamminecobalt III Complexes with Chromium II written by Yen-i Wang and published by . This book was released on 1969 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Kinetics of the Chromium II Reductions of Glycinato and Related Amino Acidato ethylenediamine and Amine Complexes of Cobalt III written by Robert D. Williams and published by . This book was released on 1980 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Index to Theses Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards written by and published by . This book was released on 1974 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt:
