Download or read book Chlorate Reduction in Water Using Advanced Reduction Processes written by Raghavendran Sivasubramanian and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Chlorate is one of the disinfection byproducts when chlorine/chlorine dioxide is used as the primary disinfectant. Excess amounts of chlorate in drinking water above permissible limits are toxic. This study investigated chlorate removal from water by photochemical degradation using advanced reduction processes (ARP). This new class of treatment processes combines a reducing agent and an activation method to generate reducing radicals that can efficiently destroy persistent oxidized contaminants. The effectiveness of combinations of four reducing agents (sulfite, dithionite, sulfide, and ferrous iron) and three UV light sources (UV-L, UV-M, and UV-B) were evaluated for chlorate removal. Dithionite irradiated by broad-band UVB lamp having the output between 280 nm and 320 nm with peak energy at 312 nm (UV-B) showed the highest chlorate removal. In pursuit of finding the optimum ARP conditions, the process variables including pH, reducing agent dose, initial chlorate concentration and light intensity were investigated. Dithionite/UV-B ARP was effective at weakly acidic conditions less than pH 5, and chlorate removal occurred in two steps. The first was an initial rapid decrease in chlorate concentration that occurred before initiating UV irradiation and was attributed to reaction with dithionite decomposition products. Bisulfite or metabisulfite in equilibrium with bisulfite are believed to be the decomposition products responsible for chlorate reduction. The second step was a slow decrease during UV irradiation that is caused by radicals produced by photolysis of the products of dithionite decomposition. The major product of chlorate destruction was chloride, with negligible amounts of chlorite produced. The electronic version of this dissertation is accessible from http://hdl.handle.net/1969.1/155465

Download or read book Chlorate Reduction in Water with Porous Nickel Catalysts written by Andrew J. Frierdich and published by . This book was released on 2006 with total page 29 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Advanced Reduction Processes a New Class of Treatment Processes written by Bhanu Prakash Vellanki and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A new class of treatment processes called Advanced Reduction Processes (ARP) has been proposed. The ARPs combine activation methods and reducing agents to form highly reactive reducing radicals that degrade oxidized contaminants. Batch screening experiments were conducted to identify effective ARP by applying several combinations of activation methods (ultraviolet light, ultrasound, electron beam, microwaves) and reducing agents (dithionite, sulfite, ferrous iron, sulfide) to degradation of five target contaminants (perchlorate, nitrate, perfluorooctanoic acid, 2,4 dichlorophenol, 1,2 dichloroethane) at 3 pH levels (2.4, 7.0, 11.2). These experiments identified the combination of sulfite activated by ultraviolet light produced by a low pressure mercury vapor lamp as an effective ARP. More detailed kinetic experiments were conducted with nitrate and perchlorate as target compounds and nitrate was found to degrade more rapidly than perchlorate. The effects of pH, sulfite concentration, and light intensity on perchlorate and nitrate degradation were investigated. The effectiveness of the sulfite/UV-L treatment process improved with increasing pH for both perchlorate and nitrate.

Download or read book Alternative Disinfectants and Oxidants Guidance Manual written by and published by . This book was released on 1999 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Advanced Oxidation Processes for Water Treatment written by Mihaela I. Stefan and published by IWA Publishing. This book was released on 2017-09-15 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Oxidation Processes (AOPs) rely on the efficient generation of reactive radical species and are increasingly attractive options for water remediation from a wide variety of organic micropollutants of human health and/or environmental concern. Advanced Oxidation Processes for Water Treatment covers the key advanced oxidation processes developed for chemical contaminant destruction in polluted water sources, some of which have been implemented successfully at water treatment plants around the world. The book is structured in two sections; the first part is dedicated to the most relevant AOPs, whereas the topics covered in the second section include the photochemistry of chemical contaminants in the aquatic environment, advanced water treatment for water reuse, implementation of advanced treatment processes for drinking water production at a state-of-the art water treatment plant in Europe, advanced treatment of municipal and industrial wastewater, and green technologies for water remediation. The advanced oxidation processes discussed in the book cover the following aspects: - Process principles including the most recent scientific findings and interpretation. - Classes of compounds suitable to AOP treatment and examples of reaction mechanisms. - Chemical and photochemical degradation kinetics and modelling. - Water quality impact on process performance and practical considerations on process parameter selection criteria. - Process limitations and byproduct formation and strategies to mitigate any potential adverse effects on the treated water quality. - AOP equipment design and economics considerations. - Research studies and outcomes. - Case studies relevant to process implementation to water treatment. - Commercial applications. - Future research needs. Advanced Oxidation Processes for Water Treatment presents the most recent scientific and technological achievements in process understanding and implementation, and addresses to anyone interested in water remediation, including water industry professionals, consulting engineers, regulators, academics, students. Editor: Mihaela I. Stefan - Trojan Technologies - Canada

Download or read book Application of the UV Chlorine Advanced Oxidation Process for Drinking Water Treatment written by Ding Wang and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Advanced Physicochemical Treatment Processes written by Lawrence K. Wang and published by Springer Science & Business Media. This book was released on 2007-11-10 with total page 697 pages. Available in PDF, EPUB and Kindle. Book excerpt: The past thirty years have witnessed a growing worldwide desire that po- tive actions be taken to restore and protect the environment from the degr- ing effects of all forms of pollution—air, water, soil, and noise. Because pollution is a direct or indirect consequence of waste, the seemingly idealistic demand for “zero discharge” can be construed as an unrealistic demand for zero waste. However, as long as waste continues to exist, we can only attempt to abate the subsequent pollution by converting it to a less noxious form. Three major questions usually arise when a particular type of pollution has been id- tified: (1) How serious is the pollution? (2) Is the technology to abate it ava- able? and (3) Do the costs of abatement justify the degree of abatement achieved? This book is one of the volumes of the Handbook of Environmental Engineering series. The principal intention of this series is to help readers f- mulate answers to the last two questions above. The traditional approach of applying tried-and-true solutions to specific pollution problems has been a major contributing factor to the success of en- ronmental engineering, and has accounted in large measure for the establi- ment of a “methodology of pollution control. ” However, the realization of the ever-increasing complexity and interrelated nature of current environmental problems renders it imperative that intelligent planning of pollution abatement systems be undertaken.

Download or read book Advanced Oxidation Technologies written by Marta I. Litter and published by CRC Press. This book was released on 2014-03-03 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Oxidation Technologies (AOTs) or Processes (AOPs) are relatively new and innovative technologies to remove harmful and toxic pollutants. The most important processes among them are those using light, such as UVC/H2O2, photo-Fenton and heterogeneous photocatalysis with TiO2. These technologies are also relatively low-cost and therefore useful for countries under development, where the economical resources are scarcer than in developed countries. This book provides a state-of-the-art overview on environmental applications of Advanced Oxidation Technologies (AOTs) as sustainable, low-cost and low-energy consuming treatments for water, air, and soil. It includes information on innovative research and development on TiO2 photocatalytic redox processes, Fenton, Photo-Fenton processes, zerovalent iron technology, and others, highlighting possible applications of AOTs in both developing and industrialized countries around the world in the framework of “A crosscutting and comprehensive look at environmental problems”. The book is aimed at professionals and academics worldwide, working in the areas of water resources, water supply, environmental protection, and will be a useful information source for decision and policy makers and other stakeholders working on solutions for environmental problems.

Download or read book Ultraviolet Irradiation Combined with Chlorine Dioxide Pre oxidation for Disinfection By product Control written by Paula Campesino and published by . This book was released on 2020 with total page 83 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of ultraviolet (UV) light and chlorine dioxide (ClO2) as an advanced oxidation process (AOP) has been investigated at the bench-scale to understand the effects of their use on disinfection by-product (DBP) formation potential (FP) in chlorinated groundwater (GW) and surface water (SW) supplies. Two GWs and two SWs of varying qualities were subject to a series of AOP treatment sequences at the bench scale: sodium hypochlorite, to serve as a baseline; ClO2-Cl2, UV-Cl2, and UV-ClO2-Cl2. In these treatment sequences, Cl2 is used as a primary and secondary disinfectant. Several water quality parameters were measured throughout the experiments, including chlorite (ClO2−) and chlorate (ClO3−) when ClO2 was used for process testing. Total trihalomethane (TTHM) FP curves were developed for each experiment along with the 7-day haloacetic acid (HAA) FP. The treatment sequence UV-ClO2 followed by Cl2 addition for GW supplies was shown to remove between 8 and 35 percent of the TTHM FP as compared to little to no change in formation potential with UV treatment alone followed by Cl2 addition. The SW supplies resulted in reductions between 16 and 27 percent for the treatment sequence UV-ClO2 followed by Cl2, approximately double the reduction from ClO2 alone followed by Cl2. GW treatment using the UV-ClO2 AOP followed by Cl2 was found to increase HAA formation, in one case by almost 50 percent compared to the baseline HAA concentrations. The research indicated the reduction of DBP FP AOP effectiveness to reduce DBP formation was highly dependent on the specific source water type and quality.

Download or read book Activated Carbon Adsorption written by Roop Chand Bansal and published by CRC Press. This book was released on 2005-05-24 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: High surface area, a microporous structure, and a high degree of surface reactivity make activated carbons versatile adsorbents, particularly effective in the adsorption of organic and inorganic pollutants from aqueous solutions. Activated Carbon Adsorption introduces the parameters and mechanisms involved in the activated carbon adsorption

Download or read book Standard Methods of Chemical Analysis written by Wilfred Welday Scott and published by . This book was released on 1917 with total page 912 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Advanced Ozonation Processes for Water and Wastewater Treatment written by Hongbin Cao and published by Royal Society of Chemistry. This book was released on 2022-07-15 with total page 317 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ozone has been actively and widely employed in water and wastewater treatment, but the utilization of ozone alone is insufficient for purifying and disinfecting water to the emission standard of real-world situations because of its selective oxidation behaviour. With the assistance of catalysts (especially heterogeneous catalysts) and coupling with other effective technologies such as the Fenton process, photocatalysis, electrocatalysis, ultrasound, microwave, and ceramic membranes, ozone can be effectively activated into more powerful reactive oxygen species (especially hydroxyl radicals). These combined technologies lead to an enhanced efficiency and complete mineralization capability that open up the method for more practical applications. Advanced Ozonation Processes for Water and Wastewater Treatment introduces the state-of-the-art catalysts used in catalytic ozonation and various combined processes with ozone. The reaction mechanisms, process kinetics, structure–property–activity relationships of catalysts, effects of operation parameters in these processes and the present state of practical applications and future trends are also discussed, making this a useful reference both for water treatment professionals and for those researching ozonation processes.

Download or read book Monitored Natural Attenuation of Inorganic Contaminants in Ground Water written by and published by . This book was released on 2007 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: V.3 ... consists of individual chapters that describe 1) the conceptual background for radionuclides, including tritium, radon, strontium, technetium, uranium, iodine, radium, thorium, cesium, plutonium-americium and 2) data requirements to be met during site characterization.

Download or read book Biological Remediation of Explosive Residues written by Shree Nath Singh and published by Springer Science & Business Media. This book was released on 2013-08-04 with total page 406 pages. Available in PDF, EPUB and Kindle. Book excerpt: Microbial degradation, Phytoremediation, Remediation, Explosive residues, Biotransformation, Mineralization, Degradative Enzymes, Degradation Pathways, Energetics, Soil contamination, Water contamination.

Download or read book In Situ Bioremediation of Perchlorate in Groundwater written by Hans F. Stroo and published by Springer Science & Business Media. This book was released on 2008-12-02 with total page 281 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the late 1970s and early 1980s, our nation began to grapple with the legacy of past disposal practices for toxic chemicals. With the passage in 1980 of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), commonly known as Superfund, it became the law of the land to remediate these sites. The U. S. Department of Defense (DoD), the nation’s largest industrial organization, also recognized that it too had a legacy of contaminated sites. Historic operations at Army, Navy, Air Force, and Marine Corps facilities, ranges, manufacturing sites, shipyards, and depots had resulted in widespread contamination of soil, groundwater, and sediment. While Superfund began in 1980 to focus on remediation of heavily contaminated sites largely abandoned or neglected by the private sector, the DoD had already initiated its Installation Restoration Program in the mid 1970s. In 1984, the DoD began the Defense Environmental Restoration Program (DERP) for contaminated site assessment and remediation. Two years later, the U. S. Congress codified the DERP and directed the Secretary of Defense to carry out a concurrent program of research, development, and demonstration of innovative remediation technologies. As chronicled in the 1994 National Research Council report, “Ranking Hazardous-Waste Sites for Remedial Action”, our early estimates on the cost and suitability of existing technologies for cleaning up contaminated sites were wildly optimistic. Original estimates, in 1980, projected an average Superfund cleanup cost of a mere $3.

Download or read book Perchlorate in the Environment written by Edward Todd Urbansky and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 299 pages. Available in PDF, EPUB and Kindle. Book excerpt: Based on a symposium sponsored by the Environmental Division of the American Chemical Society, Perchlorate in the Environment is the first comprehensive book to address perchlorate as a potable water contaminant. The two main topics are: analytical chemistry (focusing on ion chromatography and electrospray ionization mass spectrometry), and treatment or remediation. Also included are topics such as ion exchange, phytoremediation, bacterial reduction of perchlorate, bioreactors, and in situ bioremediation. To provide complete coverage, background chapters on fundamental chemistry, toxicology, and reulatory issues are also included. The authors are environmental consultants, government researchers, industry experts, and university professors from a wide array of disciplines.

Download or read book Ground Water Recharge Using Waters of Impaired Quality written by National Research Council and published by National Academies Press. This book was released on 1994-02-01 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: As demand for water increases, water managers and planners will need to look widely for ways to improve water management and augment water supplies. This book concludes that artificial recharge can be one option in an integrated strategy to optimize total water resource management and that in some cases impaired-quality water can be used effectively as a source for artificial recharge of ground water aquifers. Source water quality characteristics, pretreatment and recharge technologies, transformations during transport through the soil and aquifer, public health issues, economic feasibility, and legal and institutional considerations are addressed. The book evaluates three main types of impaired quality water sourcesâ€"treated municipal wastewater, stormwater runoff, and irrigation return flowâ€"and describes which is the most consistent in terms of quality and quantity. Also included are descriptions of seven recharge projects.