Download or read book Aqueous Systems at Elevated Temperatures and Pressures written by Roberto Fernandez-Prini and published by Elsevier. This book was released on 2004-07-06 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: The International Association for the Properties of Water and Steam (IAPWS) has produced this book in order to provide an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures. These systems are central to many areas of scientific study and industrial application, including electric power generation, industrial steam systems, hydrothermal processing of materials, geochemistry, and environmental applications. The authors' goal is to present the material at a level that serves both the graduate student seeking to learn the state of the art, and also the industrial engineer or chemist seeking to develop additional expertise or to find the data needed to solve a specific problem. The wide range of people for whom this topic is important provides a challenge. Advanced work in this area is distributed among physical chemists, chemical engineers, geochemists, and other specialists, who may not be aware of parallel work by those outside their own specialty. The particular aspects of high-temperature aqueous physical chemistry of interest to one industry may be irrelevant to another; yet another industry might need the same basic information but in a very different form. To serve all these constituencies, the book includes several chapters that cover the foundational thermophysical properties (such as gas solubility, phase behavior, thermodynamic properties of solutes, and transport properties) that are of interest across numerous applications. The presentation of these topics is intended to be accessible to readers from a variety of backgrounds. Other chapters address fundamental areas of more specialized interest, such as critical phenomena and molecular-level solution structure. Several chapters are more application-oriented, addressing areas such as power-cycle chemistry and hydrothermal synthesis. As befits the variety of interests addressed, some chapters provide more theoretical guidance while others, such as those on acid/base equilibria and the solubilities of metal oxides and hydroxides, emphasize experimental techniques and data analysis.- Covers both the theory and applications of all Hydrothermal solutions - Provides an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures- The presentation of the book is understandable to readers from a variety of backgrounds

Download or read book Chemistry in High temperature Aqueous Solutions written by Brigham Young University and published by . This book was released on 1988 with total page 103 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book High Temperature Aqueous Solutions written by Roberto Fernandez-Prini and published by CRC Press. This book was released on 1991-12-19 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a thorough discussion of the thermodynamics of aqueous solutions and presents tools for analyzing and solving scientific and practical problems arising in this area. It also presents methods that can be used to deal with ionic and nonionic aqueous solutions under sub- or supercritical conditions. Illustrations and tables give examples of procedures employed to predict thermodynamic quantities of the solutions, and an appendix summarizing statistical mechanical equations used to describe the systems is also provided. High-Temperature Aqueous Solutions: Thermodynamic Properties contains essential information for physical chemists, geochemists, geophysicists, chemical technicians, and scientists involved in electric power generation.

Download or read book Chemistry in High Temperature Aqueous Solutions written by and published by . This book was released on 1992 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Advances in High Temperature Chemistry written by Leroy Eyring and published by Elsevier. This book was released on 2013-10-22 with total page 349 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in High Temperature Chemistry, Volume 1 describes the complexities and special and changing characteristics of high temperature chemistry. After providing a brief definition of high temperature chemistry, this nine-chapter book goes on describing the experiments and calculations of diatomic transition metal molecules, as well as the advances in applied wave mechanics that may contribute to an understanding of the bonding, structure, and spectra of the molecules of high temperature interest. The next chapter provides a summary of gaseous ternary compounds of the alkali metals used in high temperature chemistry. This topic is followed by discussions on the thermochemical properties of some simple solids in terms of valence states of the metallic elements and of the electrons in metals, on anions, and in aqueous solutions. Other chapters are concerned with the stepwise bond dissociation energies in a number of polyvalent metal fluorides and the unique possibilities for chemical syntheses, which are available through high temperature species. The final chapters are devoted to the techniques, temperature ranges, and accuracy of high temperature calorimetry. These chapters also include surveys on the nature of thermal plasmas for high temperature chemistry. This book is of benefit to high temperature chemists and specialized engineers.

Download or read book Chemistry in high temperature aqueous solutions written by and published by . This book was released on 1988 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Symposium Chemistry in High temperature Aqueous Solutions written by Brigham Young University and published by . This book was released on 1988 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Chemistry in High Temperature Aqueous Solutions written by Reed M. Izatt and published by . This book was released on 1992 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Aqueous Systems at Elevated Temperatures and Pressures written by Donald Alan Palmer and published by Academic Press. This book was released on 2004 with total page 753 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures.

Download or read book Chemical Thermodynamics of Zirconium written by and published by Elsevier. This book was released on 2005-12-06 with total page 545 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency. It contains a critical review of the literature on thermodynamic data for inorganic compounds of zirconium. A review team, composed of five internationally recognized experts, has critically reviewed all the scientific literature containing chemical thermodynamic information for the above mentioned systems. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.* Critical review of all literature on chemical thermodynamics for compounds and complexes of Zr.* Tables of recommended Selected Values for thermochemical properties* Documented review procedure* Exhaustive bibliography* Intended to meet requirements of radioactive waste management community* Valuable reference source for the physical, analytical and environmental chemist.

Download or read book Solution Thermodynamics and its Application to Aqueous Solutions written by Yoshikata Koga and published by Elsevier. This book was released on 2007-11-12 with total page 311 pages. Available in PDF, EPUB and Kindle. Book excerpt: As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves without resorting to any model system. We thus elucidate the molecular processes in solution, (referred to in this book "mixing scheme), to the depth equal to, if not deeper, than that gained by spectroscopic and other methods. We show that there are three composition regions in aqueous solutions of non-electrolytes, each of which has a qualitatively distinct mixing scheme. The boundary between the adjacent regions is associated with an anomaly in the third derivatives of G. The loci of the anomalies in the temperature-composition field form the line sometimes referred as "Koga line. We then take advantage of the anomaly of a third derivative quantity of 1-propanol in the ternary aqueous solution, 1-propanol – sample species – H2O. We use its induced change as a probe of the effect of a sample species on H2O. In this way, we clarified what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. We also apply the same methodology to ions that have been ranked by the Hofmeister series. We show that the kosmotropes (salting out, or stabilizing agents) are either hydrophobes or hydration centres, and that chaotropes (salting in, or destablizing agents) are hydrophiles. - A new differential approach to solution thermodynamics - A particularly clear elucidation of the mixing schemes in aqueous solutions - A clear understandings on the effects of hydrophobes, hydrophiles, and amphiphiles to H2O - A clear understandings on the effects of ions on H2O in relation to the Hofmeister effect - A new differential approach to studies in muti-component aqueous solutions

Download or read book Interfacial Physical Chemistry of High Temperature Melts written by Kusuhiro Mukai and published by CRC Press. This book was released on 2019-08-02 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt: This English translation of a well-known Japanese book covers interfacial physicochemistry in materials science, especially for iron- and steelmaking processes. Interfacial Physical Chemistry of High-Temperature Melts bridges the gap between the basics and applications of physicochemistry. The book begins with an overview of the fundamentals of interfacial physical chemistry and discusses surface tension, describing the derivation of important equations to guide readers to a deep understanding of the phenomenon. The book then goes on to introduce interfacial properties of high-temperature melts, especially the Marangoni effect, and discusses applications to materials processing at high temperature focusing on recent research results by the author and the co-workers. This book is aimed at researchers, graduate students, and professionals in materials processing. Video clips of in-situ observation including experiments under microgravity condition and x-ray observation are available for download on the publisher's website to allow for a deeper understanding.

Download or read book 1991 Symposium on Chemistry in High temperature Aqueous Solutions written by and published by . This book was released on 1993 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Solution Thermodynamics and Its Application to Aqueous Solutions written by Yoshikata Koga and published by Elsevier. This book was released on 2017-03-28 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solution Thermodynamics and its Application to Aqueous Solutions: A Differential Approach, Second Edition introduces a differential approach to solution thermodynamics, applying it to the study of aqueous solutions. This valuable approach reveals the molecular processes in solutions in greater depth than that gained by spectroscopic and other methods. The book clarifies what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. By applying the same methodology to ions that have been ranked by the Hofmeister series, the author shows that the kosmotropes are either hydrophobes or hydration centers, and that chaotropes are hydrophiles. This unique approach and important updates make the new edition a must-have reference for those active in solution chemistry. - Unique differential approach to solution thermodynamics allows for experimental evaluation of the intermolecular interaction - Incorporates research findings from over 40 articles published since the previous edition - Numerical or graphical evaluation and direct experimental determination of third derivatives, enthalpic and volumetric AL-AL interactions and amphiphiles are new to this edition - Features new chapters on spectroscopic study in aqueous solutions as well as environmentally friendly and hostile water aqueous solutions

Download or read book 1991 symposium on chemistry in high temperature aqueous solutions written by Brigham Young University and published by . This book was released on 1992 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Second International Symposium on Chemistry in High Temperature Aqueous Solutions written by International Symposium on Chemistry in High Temperature Aqueous Solutions and published by . This book was released on 1992 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Guidelines for Phase Separations in High Temperature and Supercritical Water Solutions written by Robert W. Shaw and published by . This book was released on 2000-11 with total page 69 pages. Available in PDF, EPUB and Kindle. Book excerpt: The U.S. Army is developing supercritical water oxidation for destruction of military toxic materials. The properties of high-temperature aqueous solutions are not, in most cases, well known. Understanding the phase behavior of these solutions will facilitate design and efficient operation of high-temperature water reactors. A U.S. Army workshop held at the Forschungzentrum Karlsruhe in July 1999 assembled experts on phase behavior to develop guidelines that, in the absence of more complete knowledge of solution properties, will aid reactor designers and operators. The experts presented papers on model systems, properties of high-temperature aqueous solutions, and chemistry in high-temperature water. Following these presentations, the experts developed some of the desired rules of thumb and made recommendations for research to develop these guidelines further. This workshop report includes the presentation papers, guidelines, and recommendations for research.