Download or read book Chemical Durability and Related Properties of Solidified High level Waste Forms written by International Atomic Energy Agency and published by . This book was released on 1985 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Chemical Durability and Related Properties of Solidified High level Waste Forms written by International Atomic Energy Agency and published by . This book was released on 1985 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Chemical Durability and Related Properties of Solidified High level Waste Forms written by International Atomic Energy Agency and published by . This book was released on 1985 with total page 196 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Radioactive Waste Forms for the Future written by Werner Lutze and published by North Holland. This book was released on 1988 with total page 800 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents a compilation of important information on the full range of radioactive waste forms that have been developed, or at least suggested, for the incorporation of high-level nuclear waste. Many of the results were published in the ''gray literature'' of final reports of national laboratories or in various, generally less available, proceedings volumes. This is the first publication to draw information on nuclear waste forms for high-level wastes together into a single volume. Although borosilicate glass has become the standard waste form, additional research in this compound is still necessary. With improved technology (particularly processing technologies) and with a more detailed knowledge of repository conditions, glasses and second generation waste forms with improved performance properties can be developed. Sustained research programs on nuclear waste form development will yield results that can only add to public confidence and the final, safe disposal of nuclear waste. The aim of this volume is to provide a 'spring board' for these future research efforts. A detailed presentation is given on the properties and performance of non-crystalline waste forms (borosilicate glass, sintered glass, and lead-iron phosphate glass), and crystalline waste forms (Synroc, tailored ceramics, TiO 2 - ceramic matrix, glass-ceramics and FUETAP concrete). A chapter on Novel Waste Forms reviews a number of methods that warrant further development because of their potential superior performance and unique applications. The final chapter includes a tabulated comparison of important waste form properties and an extended discussion on the corrosion process and radiation damage effects for each waste form. Of particular interest is a performance assessment of nuclear waste borosilicate glass and the crystalline ceramic Synroc. This is the first detailed attempt to compare these two important waste forms on the basis of their materials properties. The discussion emphasizes the difficulties in making such a comparison and details the types of data that are required. Each chapter has been written by an expert and includes a current compilation of waste form properties with an extensive list of references. This volume will provide a stimulus for future research as well as useful reference material for scientists working in the field of nuclear waste disposal and materials science.

Download or read book Chemistry and Microstructure of Solidified Waste Forms written by Roger D. Spence and published by CRC Press. This book was released on 1992-12-15 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemistry and Microstructure of Solidified Waste Forms presents a comprehensive summary of mechanisms of immobilization in cementitious waste forms and the effect of waste species on cement chemistry and morphology. The book introduces the well-known chemistry and microstructure of cement pastes, in addition to common mechanisms of immobilization of waste species in cementitious waste forms. The fundamental chemical and microstructural fate of waste species is reviewed, and a technique for studying cementitious waste forms using scanning transmission electron microscopy (STEM) is described with examples of its application. Chemistry and Microstructure of Solidified Waste Forms also presents evidence to prove that chromium in waste becomes part of the cement matrix, and the potentially harmful effect of this process is discussed. Data for interpretations are included so that other researchers can analyze the data and draw their own conclusions. The book also discusses how solubility and solubility theory can be combined with leach theory and diffusion theory to predict the leaching performance of cementitious waste forms. Chemistry and Microstructure of Solidified Waste Forms will prove invaluable to hazardous waste professionals, engineers, environmental engineers, chemical engineers, waste disposal managers, waste form developers and researchers, and regulators.

Download or read book New Developments in Glassy Nuclear Wasteforms written by Michael I. Ojovan and published by Nova Publishers. This book was released on 2007 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt: Based on the authors' recent investigations, this book describes the application of glassy and polyphase composite materials for nuclear waste immobilisation. It introduces immobilisation issues beginning with a short description of nuclear waste types and compositions. Sources of nuclear waste are described including the nuclear fuel cycle, operational and spent nuclear fuel reprocessing waste streams. The glassy waste forms currently being used for high-, intermediate- and low level radioactive waste immobilisation are described. Problems related to immobilisation capacity, process efficiency and long-term radionucleide retention are highlighted. Scientific and technical problems in nuclear waste immobilisation are emphasised in particular long-term waste form stability and durability. Recent developments in advanced nuclear waste forms are described such as glass composite materials (GCM) with higher versatility and waste loading. New immobilisation approaches and technologies are described including advanced cold crucible induction melting (CCM), self sustaining thermochemical immobilisation (SSI), and in-situ self-sintering in deep underground repositories. Long-term durability tests of nuclear waste glasses are outlined and the role of ion-exchange phase in glass corrosion is described in detail.

Download or read book Waste Forms Technology and Performance written by National Research Council and published by National Academies Press. This book was released on 2011-09-05 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Department of Energy's Office of Environmental Management (DOE-EM) is responsible for cleaning up radioactive waste and environmental contamination resulting from five decades of nuclear weapons production and testing. A major focus of this program involves the retrieval, processing, and immobilization of waste into stable, solid waste forms for disposal. Waste Forms Technology and Performance, a report requested by DOE-EM, examines requirements for waste form technology and performance in the cleanup program. The report provides information to DOE-EM to support improvements in methods for processing waste and selecting and fabricating waste forms. Waste Forms Technology and Performance places particular emphasis on processing technologies for high-level radioactive waste, DOE's most expensive and arguably most difficult cleanup challenge. The report's key messages are presented in ten findings and one recommendation.

Download or read book Stabilization and Solidification of Hazardous Radioactive and Mixed Wastes written by Roger D. Spence and published by CRC Press. This book was released on 2004-12-28 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of stabilization and solidification techniques in the field of waste treatment reflects the efforts to better protect human health and the environment with modern advances in materials and technology. Stabilization and Solidification of Hazardous, Radioactive, and Mixed Wastes provides comprehensive information including case studie

Download or read book Stabilization and Solidification of Hazardous Radioactive and Mixed Wastes written by T. Michael Gilliam and published by ASTM International. This book was released on 1992 with total page 505 pages. Available in PDF, EPUB and Kindle. Book excerpt: Annotation Provides current information on the use of stabilization and solidification (S/S), as well as an international perspective on the role of S/S for treating waste residues. Thirty-nine papers by researchers working with S/S technologies from both the low-level radioactive and chemically hazardous waste communities are presented in sections on: regulatory and technical guidance; specialty wastes--organics, ashes, and resins; laboratory-scale leachability studies; laboratory-scale process development; test method development; and large-scale evaluation or demonstration. Member price, $62. Annotation copyrighted by Book News, Inc., Portland, OR.

Download or read book Stabilization solidification of CERCLA and RCRA Wastes written by and published by . This book was released on 1989 with total page 88 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Structural Chemistry of Inorganic Actinide Compounds written by Sergey Krivovichev and published by Elsevier. This book was released on 2006-12-08 with total page 505 pages. Available in PDF, EPUB and Kindle. Book excerpt: Structural Chemistry of Inorganic Actinide Compounds is a collection of 13 reviews on structural and coordination chemistry of actinide compounds. Within the last decade, these compounds have attracted considerable attention because of their importance for radioactive waste management, catalysis, ion-exchange and absorption applications, etc. Synthetic and natural actinide compounds are also of great environmental concern as they form as a result of alteration of spent nuclear fuel and radioactive waste under Earth surface conditions, during burn-up of nuclear fuel in reactors, represent oxidation products of uranium miles and mine tailings, etc. The actinide compounds are also of considerable interest to material scientists due to the unique electronic properties of actinides that give rise to interesting physical properties controlled by the structural architecture of respective compounds. The book provides both general overview and review of recent developments in the field, including such emergent topics as nanomaterials and nanoparticles and their relevance to the transfer of actinides under environmental conditions.* Covers over 2,000 actinide compounds including materials, minerals and coordination polymers* Summarizes recent achievements in the field* Some chapters reveal (secret) advances made by the Soviet Union during the 'Cold war'

Download or read book Design and Operation of High Level Waste Vitrification and Storage Facilities written by International Atomic Energy Agency and published by . This book was released on 1992 with total page 114 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report gives an up to date review of high level waste vitrification and storage facilities currently in an advanced stage of implementation.

Download or read book Radioactive Waste Management written by and published by . This book was released on 1981 with total page 630 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Ceramic glass radioactive waste forms written by C. R. Cooley and published by . This book was released on 1977 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Technical Reports Series written by and published by . This book was released on 1997 with total page 1400 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Environmental Aspects of Stabilization and Solidification of Hazardous and Radioactive Wastes written by Pierre Côté and published by ASTM International. This book was released on 1989 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Annual Report Development and Characterization of Solidified Forms for High level Wastes written by and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Development and characterization of solidified high-level waste forms are directed at determining both process properties and long-term behaviors of various solidified high-level waste forms in aqueous, thermal, and radiation environments. Waste glass properties measured as a function of composition were melt viscosity, melt electrical conductivity, devitrification, and chemical durability. The alkali metals were found to have the greatest effect upon glass properties. Titanium caused a slight decrease in viscosity and a significant increase in chemical durability in acidic solutions (pH-4). Aluminum, nickel and iron were all found to increase the formation of nickel-ferrite spinel crystals in the glass. Four multibarrier advanced waste forms were produced on a one-liter scale with simulated waste and characterized. Glass marbles encapsulated in a vacuum-cast lead alloy provided improved inertness with a minimal increase in technological complexity. Supercalcine spheres exhibited excellent inertness when coated with pyrolytic carbon and alumina and put in a metal matrix, but the processing requirements are quite complex. Tests on simulated and actual high-level waste glasses continue to suggest that thermal devitrification has a relatively small effect upon mechanical and chemical durabilities. Tests on the effects radiation has upon waste forms also continue to show changes to be relatively insignificant. Effects caused by decay of actinides can be estimated to saturate at near 1019 alpha-events/cm3 in homogeneous solids. Actually, in solidified waste forms the effects are usually observed around certain crystals as radiation causes amorphization and swelling of th crystals.