Download or read book Chemical Composition and Origin of Aerosol Particles Involved in Summertime Arctic Cloud Processes written by Eppers Oliver and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemical Composition and Origin of Aerosol Particles Involved in Summertime Arctic Cloud Processes written by Oliver Eppers and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Arctic climate is warming rapidly compared to other regions of the globe with drastic implications for its environment (e.g. sea ice loss). Aerosol particles are an important factor for the energy budget in this polar region as they interact directly or indirectly via cloud formation and processing with solar and terrestrial radiation. However, the interaction between aerosol and clouds in the Arctic is still not fully understood. This study focuses on the occurrence of different aerosol species and their influence on cloud processes in the summertime Arctic. Airborne in-situ measurements of particle composition were conducted in the European Arctic using the single particle mass spectrometer ALABAMA. Ambient aerosol particles and cloud particle residues in the diameter range between 250 nm and 1.6 μm were chemically analyzed. More than 240000 single particle mass spectra were obtained in total during the flights, almost 45000 of them from cloud residuals sampled in clouds. Different particle types were identified by detection of characteristic ion signal markers. This chemical particle analysis was complemented by further measurements of aerosol and cloud properties, trace gases as well as air mass history simulations. This study has found that Arctic cloud residual composition was dominated by triethyl- and/or diethylamine, which were observed for the first time in Arctic aerosol particles. In addition to amines, also sea spray, dicarboxylic acids, nitrate, iodine and elemental carbon were enriched inside the cloud residuals. In contrast, particles in ambient air contained mainly trimethylamine and sea spray inside the boundary layer and ammonium sulfate in the free troposphere. Only little contribution of triethyl- and/or diethylamine to particle composition in ambient air was observed, suggesting these amines were taken up by the cloud droplets from the gas-phase. This hypothesis was further supported by the observed correlation between the ethylated amine fraction and cloud liquid water content indicating their high solubility. Outside the Arctic, a significant contribution of these amines was found in clouds at mid-latitudes as well, suggesting a general importance of amines for cloud processes. Moreover, the cloud residual composition of clouds, which were thermodynamically decoupled from the surface, showed similarities to above-cloud particle composition. Thus, the thermodynamic structure of the clouds seems to play a critical role for the contribution of surface-related aerosol species to Arctic clouds.
Download or read book Aerosol Particles in the Summertime Arctic Lower Troposphere Chemical Composition Sources and Formation written by Franziska Köllner and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Environmental Chemistry of Aerosols written by Ian Colbeck and published by John Wiley & Sons. This book was released on 2008-03-24 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aerosol particles are ubiquitous in the Earth’s atmosphere and are central to many environmental issues such as climate change, stratospheric ozone depletion and air quality. In urban environments, aerosol particles can affect human health through their inhalation. Atmospheric aerosols originate from naturally occurring processes, such as volcanic emissions, sea spray and mineral dust emissions, or from anthropogenic activity such as industry and combustion processes. Aerosols present pathways for reactions, transport, and deposition that would not occur in the gas phase alone. Understanding the ways in which aerosols behave, evolve, and exert these effects requires knowledge of their formation and removal mechanism, transport processes, as well as their physical and chemical characteristics. Motivated by climate change and adverse health effects of traffic-related air pollution, aerosol research has intensified over the past couple of decades, and recent scientific advances offer an improved understanding of the mechanisms and factors controlling the chemistry of atmospheric aerosols. Environmental Chemistry of Aerosols brings together the current state of knowledge of aerosol chemistry, with chapters written by international leaders in the field. It will serve as an authoritative and practical reference for scientists studying the Earth’s atmosphere and as an educational and training resource for both postgraduate students and professional atmospheric scientists.
Download or read book Sea Salt Aerosol Production written by Ernie R. Lewis and published by American Geophysical Union. This book was released on 2004-01-09 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: Published by the American Geophysical Union as part of the Geophysical Monograph Series, Volume 152. Sea salt aerosol (SSA) exerts a major influence over a broad reach of geophysics. It is important to the physics and chemistry of the marine atmosphere and to marine geochemistry and biogeochemistry generally. It affects visibility, remote sensing, atmospheric chemistry, and air quality. Sea salt aerosol particles interact with other atmospheric gaseous and aerosol constituents by acting as sinks for condensable gases and suppressing new particle formation, thus influencing the size distribution of these other aerosols and more broadly influencing the geochemical cycles of substances with which they interact. As the key aerosol constituent over much of Earth's surface at present, and all the more so in pre-industrial times, SSA is central to description of Earth's aerosol burden.
Download or read book Cloud Multi phase Processes and High Alpine Air and Snow Chemistry written by Sandro Fuzzi and published by Springer Science & Business Media. This book was released on 1997-04-18 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: Among the chemical and physical processes involved in the transformation of pollutants between their sources and their ultimate deposition, those associated with clouds, aerosols and precipitation must be rated as the most difficult both to study and to understand. This book presents a variety of recent advances in this field, including the properties and composition of aerosol particles, chemical transformation and scavenging processes, the relationship between liquid-phase chemistry and cloud micro-physics, entrainment, evaporation and deposition, trends in high Alpine pollution, transport processes, and developments in instrumentation. This book is Volume 5 in the ten-volume series on Transport and Chemical Transformation of Pollutants in the Troposphere.
Download or read book Field and Laboratory Perspectives on the Cloud Nucleating Abilities of Aerosol Particles written by Beth Friedman and published by . This book was released on 2014 with total page 151 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aerosol-cloud interactions represent a significant uncertainty with respect to radiative forcing and future climate change. Both particle composition and size play key, yet poorly understood, roles in determining the cloud nucleating capabilities of aerosols. The following describes ambient and laboratory measurements of cloud condensation nuclei (CCN) and ice nuclei (IN) measurements from a variety of sources, with the goal of understanding how composition and size interact in forming cloud droplets and ice crystals and the potential importance of aerosol composition and atmospheric aging processes on constraining uncertainties associated with the cloud nucleating properties of aerosols. Motivated by the anthropogenic emissions of soot particles as well as the potential properties of aged soot particles, ice formation and droplet activation of soot particles of various size and composition were studied. Generated soot particles were coated with a variety of atmospherically relevant acids of varying solubility properties. The particles were also exposed to ozone in order to simulate atmospheric oxidation and aging. A custom-built ice chamber was utilized to show that both uncoated and coated soot particles comparable to those generated in our studies are unlikely to significantly contribute to the global budget of heterogeneous IN at relevant atmospheric temperatures. This result is emphasized by comparison to an efficient ice nucleus, such as mineral dust. Coatings and oxidation by ozone also did not significantly alter the ice nucleation behavior of soot particles but aided in the uptake of water, suggesting the altered composition of a hydrophobic particle is important to take into account for cloud droplet activation. To assess the importance of particle composition in cloud droplet activation, measurements of CCN concentrations, single particle composition, and number size distributions were conducted at a high-elevation research site. The temporal evolution of detailed single particle chemical composition was compared with changes in CCN activation. A variety of particle types were observed; CCN activation largely followed the behavior of the sulfate-containing particle types; biomass burning particles also contained hygroscopic material that impacted CCN activation. The observed particles were largely aged; few local sources contributed to the particle composition due to the high elevation of the site. The results were also interpreted in terms of the assumed hygroscopicity of free tropospheric aerosol. As a further examination of the impacts of aging processes on aerosol hygroscopicity measurements of CCN concentrations, aerosol composition, and number size distributions were conducted during the winter season from of a variety of air masses, including aged marine, continental, and urban sources. Based on the measured chemistry and size properties of the ambient aerosol, CCN concentrations were predicted in order to assess the amount of composition detail necessary to explain droplet activation. Direct measurements of the composition of the activated droplets were also conducted with a novel technique to separate activated droplets from un-activated aerosol. Results suggest the importance of inorganic species in droplet activation, with non-oxidized organic species having negligible impacts on total aerosol hygroscopicity. Using the same novel separation technique, measurements of the single particle composition of activated droplet residual particles were determined at an urban site in the summertime, with similar air mass trajectories as the previous wintertime site, as well as influence from local urban aerosol sources. As a function of atmospheric supersaturation conditions the composition of activated droplet residual particles was compared to the ambient aerosol composition. The study was utilized to determine the level of composition and size detail required to describe droplet activation at a site with similar aged air mass trajectories to the previous study.
Download or read book Laboratory Studies of Processing of Carbonaceous Aerosols by Atmospheric Oxidants Hygroscopicity and CCN Activity of Secondary Processed Primary Organic Aerosols written by and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The atmosphere is composed of a complex mixture of gases and suspended microscopic aerosol particles. The ability of these particles to take up water (hygroscopicity) and to act as nuclei for cloud droplet formation significantly impacts aerosol light scattering and absorption, and cloud formation, thereby influencing air quality, visibility, and climate in important ways. A substantial, yet poorly characterized component of the atmospheric aerosol is organic matter. Its major sources are direct emissions from combustion processes, which are referred to as primary organic aerosol (POA), or in situ processes in which volatile organic compounds (VOCs) are oxidized in the atmosphere to low volatility reaction products that subsequent condense to form particles that are referred to as secondary organic aerosol (SOA). POA and VOCs are emitted to the atmosphere from both anthropogenic and natural (biogenic) sources. The overall goal of this experimental research project was to conduct laboratory studies under simulated atmospheric conditions to investigate the effects of the chemical composition of organic aerosol particles on their hygroscopicity and cloud condensation nucleation (CCN) activity, in order to develop quantitative relationships that could be used to more accurately incorporate aerosol-cloud interactions into regional and global atmospheric models. More specifically, the project aimed to determine the products, mechanisms, and rates of chemical reactions involved in the processing of organic aerosol particles by atmospheric oxidants and to investigate the relationships between the chemical composition of organic particles (as represented by molecule sizes and the specific functional groups that are present) and the hygroscopicity and CCN activity of oxidized POA and SOA formed from the oxidation of the major classes of anthropogenic and biogenic VOCs that are emitted to the atmosphere, as well as model hydrocarbons. The general approach for this project was to carry out reactions of representative anthropogenic and biogenic VOCs and organic particles with ozone (O3), and hydroxyl (OH), nitrate (NO3), and chlorine (Cl) radicals, which are the major atmospheric oxidants, under simulated atmospheric conditions in large-volume environmental chambers. A combination of on-line and off-line analytical techniques were used to monitor the chemical and physical properties of the particles including their hygroscopicity and CCN activity. The results of the studies were used to (1) improve scientific understanding of the relationships between the chemical composition of organic particles and their hygroscopicity and CCN activity, (2) develop an improved molecular level theoretical framework for describing these relationships, and (3) establish a large database that is being used to develop parameterizations relating organic aerosol chemical properties and SOA sources to particle hygroscopicity and CCN activity for use in regional and global atmospheric air quality and climate models.
Download or read book Aerosols in Atmospheric Chemistry written by Yue Zhang and published by American Chemical Society. This book was released on 2022-04-01 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt: The uncertainties in the aerosol effects on radiative forcing limit our knowledge of climate change, presenting us with an important research challenge. Aerosols in Atmospheric Chemistry introduces basic concepts about the characterization, formation, and impacts of ambient aerosol particles as an introduction to graduate students new to the field. Each chapter also provides an up-to-date synopsis of the latest knowledge of aerosol particles in atmospheric chemistry.
Download or read book Atmospheric Aerosol Chemistry written by and published by Walter de Gruyter GmbH & Co KG. This book was released on 2022-04-19 with total page 215 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atmospheric aerosols are an important and a highly complex component of the Earth’s atmosphere that alter the radiative forcing and the chemical composition of the gas phase. These effects have impacts on local air quality and the global climate. Atmospheric Aerosol Chemistry outlines research findings to date in aerosol chemistry and advances in analytical tools used in laboratory studies for studying their surface and bulk reactivity.
Download or read book Heterogeneous and Liquid Phase Processes written by Peter Warneck and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: The "European Experiment on the Transport and Transformation of Environmentally Relevant Trace Constituents over Europe" (EUROTRAC) was established in 1986 to tackle the scientific problem and combine the expertise, knowledge and resources in Europe, in order to apply them over a large region covering the greater part of the continent. EUROTRAC is a coordinated multidisciplinary scientific research project involving field measurements, laboratory studies, instrument development and development of comprehensive computer models for the simulation of the physical and chemical processes in the lower atmosphere.
Download or read book Atmospheric Multiphase Chemistry written by Hajime Akimoto and published by John Wiley & Sons. This book was released on 2020-03-27 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt: An important guide that highlights the multiphase chemical processes for students and professionals who want to learn more about aerosol chemistry Atmospheric Multiphase Reaction Chemistry provides the information and knowledge of multiphase chemical processes and offers a review of the fundamentals on gas-liquid equilibrium, gas phase reactions, bulk aqueous phase reactions, and gas-particle interface reactions related to formation of secondary aerosols. The authors—noted experts on the topic—also describe new particle formation, and cloud condensation nuclei activity. In addition, the text includes descriptions of field observations on secondary aerosols and PM2.5. Atmospheric aerosols play a critical role in air quality and climate change. There is growing evidence that the multiphase reactions involving heterogeneous reactions on the air-particle interface and the reactions in the bulk liquid phase of wet aerosol and cloud/fog droplets are important processes forming secondary aerosols in addition to gas-phase oxidation reactions to form low-volatile compounds. Comprehensive in scope, the book offers an understanding of the topic by providing a historical overview of secondary aerosols, the fundamentals of multiphase reactions, gas-phase reactions of volatile organic compounds, aqueous phase and air-particle interface reactions of organic compound. This important text: Provides knowledge on multiphase chemical processes for graduate students and research scientists Includes fundamentals on gas-liquid equilibrium, gas phase reactions, bulk aqueous phase reactions, and gas-particle interface reactions related to formation of secondary aerosols Covers in detail reaction chemistry of secondary organic aerosols Written for students and research scientists in atmospheric chemistry and aerosol science of environmental engineering, Atmospheric Multiphase Reaction Chemistry offers an essential guide to the fundamentals of multiphase chemical processes.
Download or read book Atmospheric Particles and Nuclei written by Gusztáv Götz and published by Akademiai Kiads. This book was released on 1991 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Ocean Atmosphere Interactions of Gases and Particles written by Peter S. Liss and published by Springer. This book was released on 2013-12-18 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: The oceans and atmosphere interact through various processes, including the transfer of momentum, heat, gases and particles. In this book leading international experts come together to provide a state-of-the-art account of these exchanges and their role in the Earth-system, with particular focus on gases and particles. Chapters in the book cover: i) the ocean-atmosphere exchange of short-lived trace gases; ii) mechanisms and models of interfacial exchange (including transfer velocity parameterisations); iii) ocean-atmosphere exchange of the greenhouse gases carbon dioxide, methane and nitrous oxide; iv) ocean atmosphere exchange of particles and v) current and future data collection and synthesis efforts. The scope of the book extends to the biogeochemical responses to emitted / deposited material and interactions and feedbacks in the wider Earth-system context. This work constitutes a highly detailed synthesis and reference; of interest to higher-level university students (Masters, PhD) and researchers in ocean-atmosphere interactions and related fields (Earth-system science, marine / atmospheric biogeochemistry / climate). Production of this book was supported and funded by the EU COST Action 735 and coordinated by the International SOLAS (Surface Ocean- Lower Atmosphere Study) project office.
Download or read book The Impact of Desert Dust Across the Mediterranean written by Stefano Guerzoni and published by Springer Science & Business Media. This book was released on 1996-11-30 with total page 415 pages. Available in PDF, EPUB and Kindle. Book excerpt: The atmosphere is an important pathway for the transport of continentally-derived material to the oceans. In this respect the Mediterranean Sea is of special importance because its atmosphere receives inputs of anthropogenic aerosols from the north and desert- derived Saharan dusts from the south. The dusts, much of which is transported in the form of seasonal `pulses', have important effects on climate, marine chemistry and sedimentation in the Mediterranean Sea. This volume brings together reviews and specific-topic papers on the following aspects of Saharan dust transport to the Mediterranean Sea: (i) the modelling of Saharan dust transport, (ii) the chemistry and mineralogy of the dusts and their effect on precipitation, (iii) the contribution of the dusts to marine sedimentation, (iv) the aerobiology of the dusts, and (v) climatic implications of Saharan dust transport. The volume is aimed at students and researchers with an interest in the climate, biogeochemistry and geology of the Mediterranean Sea.
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1991 with total page 1460 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.
Download or read book Aerosol Science written by Ian Colbeck and published by John Wiley & Sons. This book was released on 2014-02-03 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: AEROSOL SCIENCE TECHNOLOGY AND APPLICATIONS Aerosols influence many areas of our daily life. They are at the core of environmental problems such as global warming, photochemical smog and poor air quality. They can also have diverse effects on human health, where exposure occurs in both outdoor and indoor environments. However, aerosols can have beneficial effects too; the delivery of drugs to the lungs, the delivery of fuels for combustion and the production of nanomaterials all rely on aerosols. Advances in particle measurement technologies have made it possible to take advantage of rapid changes in both particle size and concentration. Likewise, aerosols can now be produced in a controlled fashion. Reviewing many technological applications together with the current scientific status of aerosol modelling and measurements, this book includes: Satellite aerosol remote sensing The effects of aerosols on climate change Air pollution and health Pharmaceutical aerosols and pulmonary drug delivery Bioaerosols and hospital infections Particle emissions from vehicles The safety of emerging nanomaterials Radioactive aerosols: tracers of atmospheric processes With the importance of this topic brought to the public's attention after the eruption of the Icelandic volcano Eyjafjallajökull, this book provides a timely, concise and accessible overview of the many facets of aerosol science.
