Download or read book Chemical and Electronic Characterization of Copper Indium Gallium Diselenide Thin Film Solar Cells and Correlation of These Characteristics to Solar Cell Operation written by Michael Justin Hetzer and published by . This book was released on 2009 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: This dissertation embodies solid state physics research to understand the basic physical mechanisms underlying the movement of charge inside solar cells, in particular, the high efficiency copper indium gallium diselenide (CIGS) solar cell. The fundamental physics of the operation of these complex polycrystalline alloys remains incompletely understood. CIGS based solar cells have obtained conversion efficiencies of nearly 20%. Solar cells based on this material have been examined in this work using high resolution, atomic scale techniques to better understand the fundamental operation of these solar cells as well as correlating these basic properties to the operation of the finished full solar cell devices. Auger Electron Spectroscopy (AES) measurements of the chemical composition taken with nanometer resolution in an ultra high vacuum secondary electron microscope show evidence for compositional changes at the grain boundaries of the CIGS layer. These findings support theoretical calculations that predict higher solar cell performance as a result. Additionally, measurements have been taken with cathodoluminescence spectroscopy (CLS) studying the band structure locally within the CIGS layers. Significant variation is present in the resulting spectra, even within single grains indicating improved uniformity could be a path to better solar cell operation. Attempts to correlate the chemical composition and the energy band structure using AES and CLS measurements have yielded some interesting initial results but more work remains to be done to obtain a deeper understanding of the physics involved in these solar cells. Correlations have been observed between the energy band structure and the performance parameters of the solar cell, such as efficiency. These results indicate the possibility of alloying between the different layers of the solar cell and also that this intermixing is detrimental to the performance of the solar cell. This work has revealed important fundamental characteristics of these materials regarding changes in the atomic composition and energy band structure and how these changes influence the performance of the CIGS layer.
Download or read book Comprehensive Energy Systems written by Ibrahim Dincer and published by Elsevier. This book was released on 2018-02-07 with total page 5543 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Energy Systems, Seven Volume Set provides a unified source of information covering the entire spectrum of energy, one of the most significant issues humanity has to face. This comprehensive book describes traditional and novel energy systems, from single generation to multi-generation, also covering theory and applications. In addition, it also presents high-level coverage on energy policies, strategies, environmental impacts and sustainable development. No other published work covers such breadth of topics in similar depth. High-level sections include Energy Fundamentals, Energy Materials, Energy Production, Energy Conversion, and Energy Management. Offers the most comprehensive resource available on the topic of energy systems Presents an authoritative resource authored and edited by leading experts in the field Consolidates information currently scattered in publications from different research fields (engineering as well as physics, chemistry, environmental sciences and economics), thus ensuring a common standard and language
Download or read book Preparation and Characterization of Copper Indium Gallium Diselenide Films Used in the Absorber Layers of Thin film Solar Cells written by 陳富珊 and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Characterization of Photocurrent and Voltage Limitations of Copper indium Gallium selenide Thin film Polycrystalline Solar Cells written by Christopher P. Thompson and published by ProQuest. This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Thin film polycrystalline CdS/Cu(In, Ga)(Se, S) 2 solar cells have great potential as a candidate for high efficiency, high throughput, low cost production. Cu(In, Ga)Se 2 devices have laboratory efficiencies approaching 20% and module efficiencies around 11%. However, most progress in device optimization has been the result of empirical studies; little is known about the device defect structure, and even less is known about the control of defects within the Cu(In, Ga)(Se, S) 2 absorber. Despite years of study, the complex nature of the Cu(In, Ga)(Se, S) 2 system has made progress towards a fundamental understanding of device behavior, and limiting defects a slow affair. The goal of this work is to shed further light on the nature of the limitations on photocurrent and voltage. The main topics covered in this thesis are: (1) fitting quantum efficiency curves calculated from an analytical model to measured quantum efficiency curves, and (2) Open circuit voltage temperature measurements. For the first section, series of devices with varying absorber layers will be analyzed, using the minority carrier diffusion length as the only fitting parameter. All other variables within the model will be supplied from direct and indirect measurements. We show that by using quantum efficiency, capacitance-voltage, and current-voltage measurements, we can generate excellent fits using only diffusion length as a fitting parameter. It is found that for Cu(In, Ga)Se 2 devices with E G [approximate]1.2eV, L=1000-1500nm.; for wide bandgap devices, with E G [approximate]1.4eV, L=10-400nm; for devices with E G [approximate]1.2eV, deposited with a low substrate temperature, L=650nm. Wide bandgap devices long wavelength collection is limited by minority carrier diffusion. For the second section, V OC (T) measurements are taken on devices with a wide range of absorbers, including some previously un-measured devices; absorbers grown with a Na deficiency. Analysis will focus on the activation energy of the dominant recombination mechanism, as well as low temperature saturation of V OC . Both of these parameters shed light on the limiting properties of devices. Cu(In, Ga)Se 2 with bandgap ranging from 1.2eV-1.4eV are limited by Shockley Read Hall recombination, and have a ratio of saturation voltage to bandgap of 80%. Lowering the electrical quality of the absorber by depositing the Cu(In, Ga)Se 2 layer at lower substrate temperature decreases the ratio of saturation voltage to bandgap to 64%, as a result of increased bandtail defect states. CuInS 2 devices and Cu(In, Ga)Se 2 devices with low or no Na are limited by hetero-interface recombination, and have a saturation voltage to bandgap ratio of ~60%.
Download or read book Preparation and Characterization of Copper Indium Gallium Diselenide Powders and Films Used in the Absorber Layer of Thin film Solar Cells written by 吳忠憲 and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Preparation and Characterization of Copper Indium Gallium Diselenide and Copper Zinc Tin Sulfide Powders Used as the Absorber of Thin film Solar Cells written by 林詣軒 and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Preparation and Characterization of Silver Copper Indium Gallium Diselenide Thin film Solar Cells written by 吳俊杰 and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Characterization of the Optoelectronic Properties of Copper Indium Gallium Diselenide Solar Cells Using Measurements on Bifacial Devices and Device Modeling written by David Berney Needleman and published by . This book was released on 2007 with total page 42 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thin Film Solar Cells written by Jef Poortmans and published by John Wiley & Sons. This book was released on 2006-10-16 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thin-film solar cells are either emerging or about to emerge from the research laboratory to become commercially available devices finding practical various applications. Currently no textbook outlining the basic theoretical background, methods of fabrication and applications currently exist. Thus, this book aims to present for the first time an in-depth overview of this topic covering a broad range of thin-film solar cell technologies including both organic and inorganic materials, presented in a systematic fashion, by the scientific leaders in the respective domains. It covers a broad range of related topics, from physical principles to design, fabrication, characterization, and applications of novel photovoltaic devices.
Download or read book Synthesis and Characterization of Silver Copper Indium Gallium Diselenide Solar Cells on Flexible Substrates written by and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Copper Indium Gallium Selenide Thin Film Solar Cells written by Yang Tang and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The solar energy as one of the new energy sources and a regenerated energy is abundant and pollution-free. Most photovoltaic devices (solar cells) sold in the market today are based on silicon wafers, the so-called first generation" technology. The market at present is on the verge of switching to a "second generation" of thin film solar cell technology which offers prospects for a large reduction in material costs by eliminating the costs of the silicon wafers. Cadmium telluride (CdTe).
Download or read book 2016 IEEE 43rd Photovoltaic Specialists Conference PVSC written by IEEE Staff and published by . This book was released on 2016-06-05 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: scientific and engineering technical conference covering all aspects of photovoltaics materials, devices, systems and reliability
Download or read book Solution Processing for Copper Indium Sulfide Solar Cells written by Stephen Thacker Connor and published by Stanford University. This book was released on 2011 with total page 99 pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years, the field of photovoltaics has become increasingly important due to rising energy demand and climate change. While most solar cells are currently composed of crystalline silicon, devices with thinner films of inorganic absorber materials might allow production at a greater scale due to their lower materials cost. In particular, thin films of CuInS2 are promising solar absorber materials due to their high efficiencies and low required thicknesses. However, the fabrication of thin film solar cells currently requires expensive vacuum techniques. As an alternative, solution-based deposition techniques have been proposed as a route to low-cost and high-throughput electronic device fabrication. I have studied how film growth depends on solutuion deposited precursor film quality, with the goal of producing large grained films of CuInS2 through solution processing. In the first approach, we used solvothermal decomposition of organometallic precursors at moderate temperatures to produce nanoparticles of CuInS2. Thin films of these nanoparticles were cast onto molybdenum coated glass and further processed to create CuInS2 solar cells. We found that performance was dependent on film porosity, grain size, and stoichiometry of the nanoparticles. Films with grain sizes of ~200nm were attained, from which 1.3% efficient solar cells were made. In addition, we showed that this synthesis could be extended to produce CuInS2 nanoparticles with partial substitution of Fe, Zn, and Ga. In the second approach, we synthesized an air-stable hybrid organometallic/nanoparticle ink at room temperature in ambient conditions through a vulcanization reaction. This ink could be coated onto substrates in smooth layers, and further reactive annealing formed large grained CuInS2 films. This process was characterized, and a correlation between residual carbon and grain growth was found. Additionally, the chemical transformation between precursor layers and final sulfide thin film was analyzed, with an emphasis on the difference between sulfurization and selenization. We demonstrated that the sulfurization process was producing morphological defects due to its nucleation limited growth mechanism. However, it was modified to more closely resemble the diffusion limited selenization mechanism, thus producing flat films of CuInS2 with grain sizes of ~500nm.
Download or read book Preparation of Copper indium gallium diselenide Precursor Films by Electrodeposition for Fabricating High Efficiency Solar Cells written by and published by . This book was released on 1999 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A photovoltaic cell exhibiting an overall conversion efficiency of 13.6% is prepared from a copper-indium-gallium-diselenide precursor thin film. The film is fabricated by first simultaneously electrodepositing copper, indium, gallium, and selenium onto a glass/molybdenum substrate (12/14). The electrodeposition voltage is a high frequency AC voltage superimposed upon a DC voltage to improve the morphology and growth rate of the film. The electrodeposition is followed by physical vapor deposition to adjust the final stoichiometry of the thin film to approximately Cu(In.sub. 1-n Ga.sub.x)Se.sub. 2, with the ratio of Ga/(In+Ga) being approximately 0.39.
Download or read book Solar Cells and Modules written by Arvind Shah and published by Springer Nature. This book was released on 2020-07-16 with total page 357 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives a comprehensive introduction to the field of photovoltaic (PV) solar cells and modules. In thirteen chapters, it addresses a wide range of topics including the spectrum of light received by PV devices, the basic functioning of a solar cell, and the physical factors limiting the efficiency of solar cells. It places particular emphasis on crystalline silicon solar cells and modules, which constitute today more than 90 % of all modules sold worldwide. Describing in great detail both the manufacturing process and resulting module performance, the book also touches on the newest developments in this sector, such as Tunnel Oxide Passivated Contact (TOPCON) and heterojunction modules, while dedicating a major chapter to general questions of module design and fabrication. Overall, it presents the essential theoretical and practical concepts of PV solar cells and modules in an easy-to-understand manner and discusses current challenges facing the global research and development community.
Download or read book Preparation Of Copper Indium Gallium Diselenide Films For Solar Cells written by and published by . This book was released on 1998 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: High quality thin films of copper-indium-gallium-diselenide useful in the production of solar cells are prepared by electrodepositing at least one of the constituent metals onto a glass/Mo substrate, followed by physical vapor deposition of copper and selenium or indium and selenium to adjust the final stoichiometry of the thin film to approximately Cu(In, Ga)Se.sub. 2. Using an AC voltage of 1-100 KHz in combination with a DC voltage for electrodeposition improves the morphology and growth rate of the deposited thin film. An electrodeposition solution comprising at least in part an organic solvent may be used in conjunction with an increased cathodic potential to increase the gallium content of the electrodeposited thin film.
Download or read book Spectroscopic Characterization of Surfaces and Interfaces of Gallium rich Chalcopyrite Solar Cell Absorbers with Wet chemical Buffer Layers written by Victor van Maris and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
