Download or read book Characterization of the Growth of Aluminum Nitride and Gallium Nitride Thin Films on Hydrogen Etched And or Cleaned 6H SiC 0001 Surfaces written by Jeffrey David Hartman and published by . This book was released on 2000 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: Keywords: 6H-SiC, Hydrogen etching, Aluminum nitride, Gallium nitride, Photo-electron emission microscopy, Chemical vapor deposition, Molecular beam epitaxy.

Download or read book Charaterization of the Growth of Aluminum Nitride and Gallium Nitride Thin Films on Hydrogen Etched And or Cleaned 6H SiC 0001 Surfaces written by and published by . This book was released on 2000 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The surface morphology and atomic structure of nitrogen doped, n-type 6H-SiC(0001)Si wafers before and after various surface preparation techniques were investigated. As-received wafers were exposed to in-situ cleaning with or without excess silicon to obtain either a (rt3 x rt3)R30 & deg; or a (3 x 3) reconstructed surface. The resulting surfaces were characterized using reflection high-energy electron diffraction, photo-electron emission microscopy, and atomic force microscopy. An atomically clean, reconstructed surface was obtained via thermal annealing at 950 & deg;C. Cleaning with excess silicon resulted in the formation of silicon islands on the surface. The surface morphology of hydrogen etched wafers depended upon their doping concentrations. Wafers with doping concentrations of greater than or equal 2.5 x 10E18 and less than 7 x 10E17 (ND-NA)/cm3 were investigated with the former exhibiting more surface features. The microstructure of all the samples showed regions with full and half unit cell high steps. An atomically clean, ordered, stepped surface was achieved via annealing at 1030 degrees Celcius. Chemical vapor cleaning resulted in the formation of silicon islands. The initial growth of AlN and GaN thin films on the cleaned, hydrogen etched 6H-SiC(0001) substrates were investigated using PEEM and AFM. The AlN films nucleated immediately and coalesced, except in the areas of the substrate surface which contained half unit cell height steps where pits were observed. The GaN films grown at 800 & deg;C for 2.5 minutes exhibited nucleation and three-dimensional growth along the steps. The GaN films deposited at 700 & deg; C for 2 minutes grew three-dimensionally with coalescence of the film dependent upon the step structure. Almost complete coalescence occurred in regions with unit cell high steps and incomplete coalesce occurred in regions with half unit cell height steps. Films of AlN grown for 30 minutes via GSMBE on hydrogen etched surfaces exhibited two-dimens.

Download or read book American Doctoral Dissertations written by and published by . This book was released on 2001 with total page 776 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2002 with total page 854 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2626 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Structural and Microstructural Characterization of III Nitrides on 6H SiC 0001 Substrates written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Characterization of nitride films on 6H-SiC (0001) wafers via x-ray, TEM, and AFM was accomplished on standard GaN thin films with AlN or AlGaN buffer layers. TEM sample thinning capability was improved through the use of Nomarski in an optical microscope to gauge the thickness of the sample during preparation. TEM analysis was then completed of Au and Pt films deposited on chemical vapor cleaned GaN with annealed up to 800 & $176;C. Chemical reactions were detected in x-ray measurements of the 800 & deg;C Pt samples and GaN/metal interface roughening were confirmed by TEM images in both metals. Interface roughening is attributed to the chemical reactions and interfacial stresses greater than the yield stress of the metal created during heat treatments by the difference in the thermal expansion coefficients of the GaN and the metals. The GaN rocking curves were found to track very closely to the values of the underlying substrate and changes in buffer layer growth temperatures were found to change the screw and edge dislocation populations of subsequent GaN layers. GaN grown on 1030 & deg;C AlN buffer layers showed the lowest edge dislocation populations when compared against buffers grown in the range of 1010-1220 & deg;C, even though the 1220 & deg;C AlN was much smoother. AlGaN buffer layers provided more edge dislocation reduction, with a 1090 & deg;C Al0.2Ga0.8N layer yielding the best GaN rocking curve values found in this work. GaN films with AlN buffer layers grown on hydrogen etched SiC substrates did not show rocking curve improvement when compared against samples with unetched substrates. The AlN layers showed extremely narrow, substrate limited, on-axis rocking curve values, but it is not clear as to whether additional defects are present that may broaden the off-axis rocking curves, causing the poorer results seen in the GaN films. Reciprocal space maps of uncoalesced, maskless pendeo epitaxy samples revealed that the wing regions are shielded from poor substrate m.

Download or read book Growth and Characterization of Nitride Thin Films on Semiconductor Surfaces and Characterization of Nitrogen Containing Insulating Layers written by Elizabeth Ann Apen and published by . This book was released on 1994 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Ceramic Abstracts written by American Ceramic Society and published by . This book was released on 1996 with total page 1000 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book International Aerospace Abstracts written by and published by . This book was released on 1998 with total page 920 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Growth and Characterization of III V Nitride Thin Films written by Zlatko Sitar and published by . This book was released on 1990 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis of High Purity Gallium Nitride Powders and Growth and Characterization of Aluminum Nitride and Gallium Nitride Bulk Single Crystals written by Cengiz Mustafa Balkas and published by . This book was released on 1997 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Mechanistic Surface Chemistry and Growth Studies of Novel Precursors for Aluminum Nitride Thin Films written by David Walter Robinson and published by . This book was released on 1999 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Analysis of Aluminum Nitride AlN and Graded Aluminum Gallium Nitride AlgaN Thin Film Structures written by Phaneendra Bandaru and published by . This book was released on 2005 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Characterization of Visible Emission from Rare earth Doped Aluminum Nitride Gallium Nitride and Gallium Aluminum Nitride Powders and Thin Films written by Jonathan Huai-Tse Tao and published by . This book was released on 2010 with total page 165 pages. Available in PDF, EPUB and Kindle. Book excerpt: A three-step solution-based process had been used synthesize powders of GaN, AlN and their alloys. The complete solid solubility and tunable nature of these nitride band gaps in the visible spectrum were the motivation of these studies due to their application in solid state lighting. Energy dispersive X-ray spectroscopy confirmed the reduction in oxygen content for the GaN powders to as low as 4 atom % with an 8 % oxygen to nitrogen ratio. Relative to commercial GaN powders, the bandedge of the powders synthesized by such approach also shifted to higher energy, which indicated fewer defects, as observed from reflectance measurements. Inspired by the use of rare-earth elements as color emitters in fluorescent lamp phosphors, these elements were also used as activators in our nitride material. Visible emission was demonstrated through photoluminescence measurements in AlN powders activated with rare-earth elements Eu3, Tb3, Tm3+. These ions showed emission in the red, green and blue regions of the visible spectrum, respectively. Eu3+ and Tb3+ co-activation was also observed in an AlN sample that indicated successful energy transfer from the host to sensitizer, and subsequently to another activator. Tb3+ emission was observed under cathodoluminescence in GaN powders synthesized by the same method, and a concentration study showed no effect of concentration quenching up to 8 atom %. Using the same source powder, a pulsed-laser deposited thin film was fabricated that showed both band gap emission and activator-related emission, suggesting a reduction of defects when the powders were deposited as thin films. Additionally, GaN:Tb3+ films were also fabricated using metallorganic vapor phase epitaxy using precursors with and without oxygen ligands. Tb3+ emission was only observed in the sample fabricated from the precursor with oxygen ligand, suggestion that oxygen may be required for effective rare earth luminescence. Finally, Ga1-xAl/xN alloy powders (x = 0.5) and Ga1-x-yAl/xDy/yN (x = 0.10, 0.30, y = 0.01) powders were synthesized using the solution method while incorporating a stainless steel pressure vessel, which increased the synthesis pressure and aided the formation of a single phase hydroxide precursor. This in turn produced a single phase alloy nitride in the final step. Dy3+ emission that was not observed in GaN powders was also observed in the Ga1-x-yAl/xDy/yN powder. This suggested that the incorporation of aluminum enabled rare-earth emission in the nitrides synthesized for these experiments. However, attempts to sputter nitride alloy thin films via radio frequency sputtering were unsuccessful; only very minor peak shifts in the X-ray diffraction patterns were observed. Nevertheless, energy dispersive X-ray spectroscopy indicates the presence of Al in the Ga0.5Al0.5N film deposited on a Si substrate. This suggested that Al atoms may have segregated from the alloy lattice during the deposition process, with only a small amount of Al atoms incorporated into the GaN lattice.

Download or read book GaN and Related Materials written by Stephen J. Pearton and published by CRC Press. This book was released on 2021-10-08 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents views on current developments in heat and mass transfer research related to the modern development of heat exchangers. Devotes special attention to the different modes of heat and mass transfer mechanisms in relation to the new development of heat exchangers design. Dedicates particular attention to the future needs and demands for further development in heat and mass transfer. GaN and related materials are attracting tremendous interest for their applications to high-density optical data storage, blue/green diode lasers and LEDs, high-temperature electronics for high-power microwave applications, electronics for aerospace and automobiles, and stable passivation films for semiconductors. In addition, there is great scientific interest in the nitrides, because they appear to form the first semiconductor system in which extended defects do not severely affect the optical properties of devices. This series provides a forum for the latest research in this rapidly-changing field, offering readers a basic understanding of new developments in recent research. Series volumes feature a balance between original theoretical and experimental research in basic physics, device physics, novel materials and quantum structures, processing, and systems.

Download or read book Epitaxial Growth of Aluminum Nitride and Gallium Nitride Via Supersonic Beams Seeded with NH3 written by Victor Mario Torres and published by . This book was released on 1998 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book CRC Handbook of Metal Etchants written by Perrin Walker and published by CRC Press. This book was released on 1990-12-11 with total page 1434 pages. Available in PDF, EPUB and Kindle. Book excerpt: This publication presents cleaning and etching solutions, their applications, and results on inorganic materials. It is a comprehensive collection of etching and cleaning solutions in a single source. Chemical formulas are presented in one of three standard formats - general, electrolytic or ionized gas formats - to insure inclusion of all necessary operational data as shown in references that accompany each numbered formula. The book describes other applications of specific solutions, including their use on other metals or metallic compounds. Physical properties, association of natural and man-made minerals, and materials are shown in relationship to crystal structure, special processing techniques and solid state devices and assemblies fabricated. This publication also presents a number of organic materials which are widely used in handling and general processing...waxes, plastics, and lacquers for example. It is useful to individuals involved in study, development, and processing of metals and metallic compounds. It is invaluable for readers from the college level to industrial R & D and full-scale device fabrication, testing and sales. Scientific disciplines, work areas and individuals with great interest include: chemistry, physics, metallurgy, geology, solid state, ceramic and glass, research libraries, individuals dealing with chemical processing of inorganic materials, societies and schools.