Download or read book Catalyseurs base de m taux nobles pour l oxydation totale du m thane written by Delphine Roth and published by . This book was released on 2000 with total page 205 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Oxydation de divers compos s organiques par le dioxyg ne en milieu aqueux sur catalyseurs base de m taux nobles written by Florence Delanoe͏̈ and published by . This book was released on 1996 with total page 187 pages. Available in PDF, EPUB and Kindle. Book excerpt: L'OBJECTIF DE CE TRAVAIL EST DE METTRE AU POINT UN SYSTEME CATALYTIQUE HETEROGENE SUSCEPTIBLE, PAR OXYDATION VOIE HUMIDE SOUS OXYGENE, D'ELIMINER DES COMPOSES ORGANIQUES OXYGENES ET AZOTES, REPRESENTATIFS DES POLLUANTS DES EFFLUENTS URBAINS ET INDUSTRIELS. DES TESTS D'OXYDATION DU PHENOL, REALISES SUR LE CATALYSEUR, 1%PT/CEO#2, MONTRENT LE CARACTERE REFRACTAIRE DE L'ACIDE ACETIQUE, SEUL SOUS PRODUIT DE FIN DE REACTION AVEC LE DIOXYDE DE CARBONE. L'OXYDATION DE L'ANILINE SE CARACTERISE PAR LA FORMATION D'INTERMEDIAIRES PRESENTS EN QUANTITE RELATIVEMENT IMPORTANTE. LES PRODUITS DE CONDENSATION DE L'ANILINE GENERALEMENT OBSERVES (AZO, AZOXYBENZENE,...) NE SONT PAS FORMES EN OXYDATION CATALYTIQUE. LE MECANISME RADICALAIRE FAVORISE PAR LE CATALYSEUR RU/CEO#2 CONDUIT DIRECTEMENT A LA FORMATION DE COMPOSES PLUS LEGERS. CONCERNANT L'OXYDATION DE L'ACIDE ACETIQUE, LE METAL JOUE UN ROLE PRIMORDIAL DANS L'ACTIVATION DE LA REACTION. LE RUTHENIUM EST, PARMI LES METAUX DES GROUPES VII ET VIII, CELUI OFFRANT LA MEILLEURE CONVERSION DE L'ACIDE ACETIQUE. IL A ETE DEMONTRE LA NECESSITE D'AVOIR UN SUPPORT CATALYTIQUE DE TYPE SEMI-CONDUCTEUR N, TEL QUE LA CERINE, AFIN DE MAINTENIR LE METAL A L'ETAT REDUIT. DANS LES CONDITIONS GENERALES DE REACTION, L'OXYDATION PAR LE SYSTEME CATALYTIQUE 5%RU/CEO#2 EST TOTALE EN 90 MINUTES DE REACTION. LE ROLE DE L'OXYGENE, LA CONCENTRATION DU REACTIF ET LA TEMPERATURE SUR LA REACTION D'OXYDATION ONT PU ETRE PRECISES PAR UNE ETUDE CINETIQUE COMPLETE. LE DIOXYDE DE CARBONE SOLUBLE PRESENTE UN EFFET INHIBITEUR SUR L'ACTIVITE EN DIMINUANT LA SOLUBILITE DE L'OXYGENE. DEUX PHENOMENES MAJEURS ENTRAINENT LA DESACTIVATION DES CATALYSEURS. ILS SONT MIS EN EVIDENCE PAR DES ANALYSES SPECIFIQUES DES CATALYSEURS VIEILLIS PAR DES CYCLES SUCCESSIFS D'OVH, LA REOXYDATION DU METAL EN RUO#2 ET L'EMPOISONNEMENT DE LA SURFACE DU CATALYSEUR PAR L'ACIDE ACETIQUE. NEANMOINS, UN RETRAITEMENT REDUCTEUR DES CATALYSEURS PERMET DE RECUPERER 90% DE SON ACTIVITE INITIALE

Download or read book laboration de mat riaux catalytiques pour l limination de polluants organiques en phase gaz written by Henri-Joël Sedjame and published by . This book was released on 2013 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Les travaux dont les résultats sont présentés dans ce manuscrit ont été menés dans le but de préparer des matériaux catalytiques à base de métaux nobles pour l'élimination de certains composés organiques volatils (COV). Différents catalyseurs à base de platine ont ainsi été préparés et leurs performances catalytiques évaluées pour l'oxydation de deux polluants : le n-butanol et l'acide acétique. Une première étude sur l'élimination oxydative et non-oxydative du n-butanol sur des catalyseurs à base de platine supportés sur alumine a été menée. Ce travail a porté essentiellement sur l'étude de l'effet des différents paramètres intervenant dans la réaction (oxygène, eau, métal). Le phénomène d'adsorption-désorption du polluant à la surface du catalyseur a également été étudié. S'inspirant des données de la littérature sur les propriétés redox particulières de la cérine, les travaux ont ensuite porté sur l'effet de l'ajout de CeO2 à des catalyseurs de type Pt/Al2O3 pour l'oxydation du n-butanol et de l'acide acétique. La modification des propriétés redox et acido-basiques ainsi que celle des performances catalytiques du matériau observées avec l'ajout de CeO2 a permis d'établir une corrélation entre activité catalytique en oxydation, capacité de stockage de l'oxygène et basicité. Cette corrélation a été confirmée dans la dernière étude menée sur des catalyseurs mis en forme de type monolithes enduits avec différents matériaux (Pt/Al2O3, Pt/CeO2, Pt/ZrO2, Pt/Al2O3-CeO2, Pt/Al2O3-ZrO2 et Pt/CeO2-ZrO2).

Download or read book A German English Dictionary for Chemists written by Austin M 1876-1956 Patterson and published by Scholar Select. This book was released on 2015-08-08 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work was reproduced from the original artifact, and remains as true to the original work as possible. Therefore, you will see the original copyright references, library stamps (as most of these works have been housed in our most important libraries around the world), and other notations in the work. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work.As a reproduction of a historical artifact, this work may contain missing or blurred pages, poor pictures, errant marks, etc. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.

Download or read book Dynamics and Control of Underactuated Multibody Spacecraft written by Sangbum Cho and published by . This book was released on 2002 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Filtering for Some Stochastic Processes with Discrete Observations written by Oleg V. Makhnin and published by . This book was released on 2002 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Guidance Strategies for Microburst Escape written by Atilla Dogan and published by . This book was released on 2000 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Performance Prediction of a Ducted Rocket Combustor microform written by Robert Alan Stowe and published by National Library of Canada = Bibliothèque nationale du Canada. This book was released on 2001 with total page 420 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Fixed structure Adaptive improvement Control written by Daniel P. Scharf and published by . This book was released on 2001 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book A Numerical Investigation of Sound Generation in Supersonic Jet Screech written by Ted A. Manning and published by . This book was released on 1999 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Adaptive Harmonic Balance Method for Unsteady Nonlinear One Dimensional Periodic Flows written by Raymond C. Maple and published by . This book was released on 2002-09-01 with total page 167 pages. Available in PDF, EPUB and Kindle. Book excerpt: A new adaptive split-domain harmonic balance computational fluid dynamics (CFD) method is developed to solve highly nonlinear time-periodic flows such as those found in turbomachinery. The basic harmonic balance CFD method transforms an unsteady time-periodic problem into a steady-state problem by assuming a solution in the form of a Fourier series in time. The new method employs a unique multi-domain split-operator solution technique to remove a large-series stability restriction present in previous harmonic balance CFD approaches. In addition, the new method adapts the frequency content to the flow, starting with a small number of Fourier frequencies and augmenting the frequency content in each cell as necessary to capture local flow physics. The method reduces compute times by allowing larger integration time steps, eliminating Fourier transforms, and reducing overall problem size. The stability and accuracy of the method are verified with solutions to the 1-D inviscid Burger's equation and 1-D Euler's equation. Accurate adapted quasi-1-D Euler solutions for a supersonic/subsonic diverging nozzle with periodic unsteady outflow conditions are generated in 86% less time than an equivalent non-adapted split-domain solution, demonstrating the performance benefit of matching frequency content to the local flow conditions.

Download or read book Engine Airframe Integration written by and published by . This book was released on 1992 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Velocity and Vorticity Fields of a Single Stream Shear Layer written by Scott Christopher Morris and published by . This book was released on 2002 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Properties of Spray Formation by Turbulent Primary Breakup written by Khaled A. Sallam and published by . This book was released on 2002 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Numerical Investigation of the Physical Vapor Deposition of Titanium written by Jitendra Balakrishnan and published by . This book was released on 2001 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: