Download or read book Carbon Dioxide and Vegetable Oil for the Synthesis of Bio based Polymer Precursors written by Margot Alves and published by . This book was released on 2016 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Although it is a thermodynamically and kinetically stable molecule, carbon dioxide can beconverted into five- and six-membered cyclic carbonates by coupling with epoxides or oxetanes, respectively, using appropriate catalysts. Cyclic carbonates are used as green solvents, electrolytes for Liion batteries or intermediates for the synthesis of polymers. However, the catalytic performance must be further enhanced in particular for the coupling of CO2 with epoxidized vegetable oils or oxetanes. In this context, we developed a new highly efficient bicomponent homogeneous organocatalyst composed of anammonium salt as the catalyst and fluorinated single or double hydrogen bond donors as co-catalysts. First,a screening of onium-based catalysts and hydrogen-bond donors was performed. Performances of thecatalysts and optimization of the reaction was realized through detailed kinetics studies using in-situ FTIR/Raman spectroscopy under pressure. We demonstrated that fluorinated alcohols showed unexpected co-catalytic activity due to synergisms between the onium salt and fluorinated co-catalysts enabling the fast and selective addition of CO2 on to model epoxides and epoxidized vegetable oils under solvent-free and mild experimental conditions. The use of this powerful dual catalyst was then extended to the first organocatalytic coupling of CO2 with less reactive oxetanes to produce hydroxyl telechelic oligocarbonates that were used asprecursor of CO2-based polyurethanes by chain-extension with a diisocyanate. In addition, a fine comprehension of the mechanisms was investigated by DFT calculations highlighting that the co-catalytic performance of the onium salt/fluorinated alcohol binary catalyst arose from the strong stabilization of the intermediates and transitions states by hydrogen-bonding. To date, through comparative studies, we evidenced that this new catalyst is one.

Download or read book Synthesis and Applications of Copolymers written by Anbanandam Parthiban and published by John Wiley & Sons. This book was released on 2014-06-23 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: Understanding the reactivity of monomers is crucial in creating copolymers and determining the outcome of copolymerization. Covering the fundamental aspects of polymerization, Synthesis and Applications of Copolymers explores the reactivity of monomers and reaction conditions that ensure that the newly formed polymeric materials exhibit desired properties. Referencing a wide-range of disciplines, the book provides researchers, students, and scientists with the preparation of a diverse variety of copolymers and their recent developments, with a particular focus on copolymerization, crystallization, and techniques like nanoimprinting and micropatterning.

Download or read book Vegetable Oil Based Polymers written by Niranjan Karak and published by Elsevier. This book was released on 2012-07-10 with total page 345 pages. Available in PDF, EPUB and Kindle. Book excerpt: The growing need to find a sustainable, environmentally-friendly replacement for petroleum-based materials is fuelling the development of bio-based polymers from renewable resources. Amongst the most promising of these are vegetable oil-based polymeric materials. Vegetable oil-based polymers provides a comprehensive review of the research in this important field.After an introduction to classification and polymerization, Vegetable oil-based polymers goes on to review the factors involved in polymer biodegradation. The extraction, purification and application of vegetable oils are then explored, along with vegetable oil-based polyesters and poly(ester amide)s, polyurethanes and epoxies. The book then reviews polyamides, polyolefins and vegetable oil-based hyperbranched polymers. It concludes with an analysis of vegetable oil-based polymer composites and polymer nanocomposites.Vegetable oil-based polymers is an indispensable guide for all those involved in the research and development of biopolymers as well as the wide range of industries looking for more sustainable polymer materials. Provides a comprehensive review of recent research in the area of vegetable oil-based polymeric materials Discusses vegetable oils and their derivatives, biodegradable polymers and the fundamentals of polymers Explores the extraction, purification and application of vegetable oils, along with vegetable oil-based polyesters and poly(ester amide)s, polyurethanes and epoxies

Download or read book Bio Based Plant Oil Polymers and Composites written by Samy Madbouly and published by William Andrew. This book was released on 2015-08-27 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bio-based Plant Oil Polymers and Composites provides engineers and materials scientists a useful framework to help take advantage of the latest research conducted in this rapidly advancing field—enabling them to develop and commercialize their own products quickly and more successfully. Plant oil is one of the most attractive options as a substitute for non-renewable resources in polymers and composites, and is producing materials with very promising thermomechanical properties relative to traditional, petroleum-based polymers. In addition to critical processing and characterization information, the book assists engineers in deciding whether or not they should use a plant oil-based polymer over a petroleum-based polymer, discussing sustainability concerns, biodegradability, associated costs, and recommended applications. The book details the advancements in the development of polymeric materials and composites from plant oils, and provides a critical review of current applications in various fields, including packaging, biomedical, and automotive applications. Also includes the latest progress in developing multifunctional biobased polymers—by increasing thermal conductivity or adding antibacterial properties, for example. Essential coverage of processing, characterization, and the latest research into polymeric materials and composites derived from plant oils (thermoplastics, thermosets, nanocomposites, and fiber reinforced composites) Critically reviews the potential applications of plant oil-based polymers, including sensors, structural parts, medical devices, and automotive interiors Includes the latest developments in multifunctional bio-based polymer composites

Download or read book Biobased Aerogels written by Sabu Thomas and published by Royal Society of Chemistry. This book was released on 2018-08-23 with total page 346 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biobased Aerogels is the first book to cover aerogel research from a green perspective, using commentary and analysis from leading researchers working in the field.

Download or read book Green Composites written by Subramanian Senthilkannan Muthu and published by Springer. This book was released on 2018-08-25 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights the processing, characterization and applications of various green composites. Composites are known for their unique properties, which are derived by combining two or more components. This yields properties such as greater strength and rigidity than that of the individual components, as well as reduced weight. To help achieve such outcomes, the book discusses the potential applications of hybrid bio-composites and sisal-fiber-reinforced epoxidized non-edible oil-based epoxy green composites.

Download or read book Green Chemistry and Green Materials from Plant Oils and Natural Acids written by Zengshe Liu and published by Royal Society of Chemistry. This book was released on 2023-12-22 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is an increasing awareness that materials and chemicals produced from fossil fuels are not sustainable, both in terms of the pollution caused by the extraction and production processes, and the fact that there is only a finite supply of these fossil fuels. Therefore, there is a strong incentive to find sources for chemicals and materials from source materials that we know we can continue to generate. Plants are a source of a wide variety of chemicals, many with interesting properties, and these chemical feedstocks are considered renewable rather than finite. Green Chemistry and Green Materials from Plant Oils and Natural Acids covers the application of these natural materials in producing polymers, lubricants and plasticisers.

Download or read book Handbook of Thermoset Plastics written by Hanna Dodiuk and published by William Andrew. This book was released on 2021-10-25 with total page 1118 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Thermoset Plastics, Fourth Edition provides complete coverage of the chemical processes, manufacturing techniques and design properties of each polymer, along with its applications. This new edition has been expanded to include the latest developments in the field, with new chapters on radiation curing, biological adhesives, vitrimers, and 3D printing. This detailed handbook considers the practical implications of using thermoset plastics and the relationships between processing, properties and applications, as well as analyzing the strengths and weakness of different methods and applications. The aim of the book is to help the reader to make the right decision and take the correct action on the basis of informed analysis – avoiding the pitfalls the authors’ experience has uncovered. In industry, the book supports engineers, scientists, manufacturers and R&D professionals working with plastics. The information included will also be of interest to researchers and advanced students in plastics engineering, polymer chemistry, adhesives and coatings. Offers a systematic approach, guiding the reader through chemistry, processing methods, properties and applications of thermosetting polymers Includes thorough updates that discuss current practice and the new developments on biopolymers, nanotechnology, 3D printing, radiation curing and biological adhesives Uses case studies to demonstrate how particular properties make different polymers suitable for different applications Covers end-use and safety considerations

Download or read book Biopolymers Applications and Trends written by Michael Niaounakis and published by William Andrew. This book was released on 2015-08-13 with total page 603 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biopolymers: Applications and Trends provides an up-to-date summary of the varying market applications of biopolymers characterized by biodegradability and sustainability. It includes tables with the commercial names and properties of each biopolymer family, along with biopolymers for each marketing segment, not only presenting all the major market players, but also highlighting trends and new developments in products. The book includes a thorough breakdown of the vast range of application areas, including medical and pharmaceutical, packaging, construction, automotive, and many more, giving engineers critical materials information in an area which has traditionally been more limited than conventional polymers. In addition, the book uses recent patent information to convey the latest applications and techniques in the area, thus further illustrating the rapid pace of development and need for intellectual property for companies working on new and innovative products. Provides an up-to-date summary of the varying market applications of biopolymers characterized by biodegradability and sustainability Includes tables with the commercial names and properties of each biopolymer family, along with biopolymers for each marketing segment Presents a thorough breakdown of the vast range of application areas, including medical and pharmaceutical, packaging, construction, automotive, and many more Uses recent patent information to convey the latest applications and techniques in the area, thus further illustrating the rapid pace of development and need for intellectual property

Download or read book Handbook of Sustainable Materials Modelling Characterization and Optimization written by Ajay and published by CRC Press. This book was released on 2023-03-31 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Sustainable Materials presents recent developments in sustainable materials and how these materials interact with the environment. It highlights the recent advancements involved in proper utilization of sustainable materials, including chemical and biological approaches. With chapters written by global experts, the book offers a guide and insights into sustainable materials from a variety of engineering disciplines. Each chapter provides in-depth technical information on the sustainable materials theory and explores synthesis strategies, green materials, and artificial intelligence. The book considers applications in sectors such as aerospace, automobile, and biomedical for rapid prototyping and customized production without negative environmental impacts. It features research outcomes and case studies of optimization and modeling techniques in practice. Features: Presents recent developments in sustainable materials from various engineering fields and industry applications. Emphasizes analytical strategies, computational, and simulation approaches develop innovative sustainable materials. Discusses an artificial intelligence approach, rapid prototyping, and customized production. This book is designed for researchers and professionals working with sustainable materials, clean manufacturing, and environmental impacts.

Download or read book Bio based Flame Retardant Technology for Polymeric Materials written by Yuan Hu and published by Elsevier. This book was released on 2022-08-19 with total page 494 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bio-Based Flame Retardants for Polymeric Materials provides a comprehensive overview of flame retardants derived directly and indirectly from plant sources, drawing on cutting-edge research and covering preparation methods, testing and evaluation techniques, enhanced properties, and end applications. Chapters introduce bio-based materials in the context of additives for flame retardancy, explaining fundamentals and testing methods and analyzing synthetic approaches and the potential advantages of pursuing a bio-based approach. This is followed by detailed coverage of bio-based retardants, with each chapter covering a specific source and guiding the reader systematically through preparation techniques, evaluation methods, properties and applications. Throughout the book, the latest progress in the field is critically reviewed, and there is a continual emphasis on novel approaches to achieve enhanced properties and performant materials. This is an essential guide for all those with an interest in innovative, sustainable flame retardant additives for polymeric materials, including researchers, scientists, advanced students, and more. Explains innovative techniques for the preparation of bio-based flame retardant mechanisms, analyzing properties, performance and applications Offers in-depth coverage of a range of sources, including cellulose, lignin, cardanol, chitosan, eugenol, vanillin, furan, alginate and vegetable oils Presents the latest advances in the field, serving as a novel resource to advanced students, researchers and R&D professionals in academia and industry

Download or read book Environmentally Friendly and Biobased Lubricants written by Brajendra K. Sharma and published by CRC Press. This book was released on 2016-09-19 with total page 644 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Comprehensive Review of Developing Environmentally Friendly Lubricants A push from environmentally savvy consumers along with recent changes in governmental regulations have paved the way for a marketplace of products with high levels of environmental performance. Fueled by the growing demand for biobased lubricants, Environmentally Friendly and Biobased Lubricants highlights the development of environmentally friendly additives that are compatible with environmental regulations and describes the approaches being used in this emerging area. Derived from research topics shared over the years at various technical sessions of the Society of Tribologists and Lubrication Engineers (STLE) Annual Meetings, the book includes a critical assessment of gaps and weaknesses in the field of environmentally friendly fluids and biobased lubricants. Each chapter is written by authors selected from the environmentally friendly fluids and biobased lubricants sessions of STLE and also incorporates input from prominent researchers invited to take part in the book. Expert contributors discuss the control, production, usage, and disposal of lubricants; factor in related policies, laws, and regulations around the world; and include case studies demonstrating the uses and values of commercially viable biobased lubricants. The book is divided into five sections that cover advanced environmentally friendly base oils and feedstocks, biobased hydraulic lubricants and biodegradability, chemically/enzymatically modified environmentally friendly base oils, vegetable oil–based environmentally friendly fluids, and additives for environmentally friendly fluids.

Download or read book Bio Based Epoxy Polymers Blends and Composites written by Jyotishkumar Parameswaranpillai and published by John Wiley & Sons. This book was released on 2021-04-26 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt: State-of-the-art overview on bioepoxy polymers as well as their blends and composites -- covering all aspects from fundamentals to applications! Bioepoxy polymers is an emerging area and have attracted more and more attention due to their biodegradability and good thermo-mechanical performance. In recent years, research progress has been made in synthesis, processing, characterization, and applications of bioepoxy blends and composites. Bioepoxy polymers are very promising candidates to replace the traditional thermosetting nonbiodegradable polymers. Bio-Based Epoxy Polymers, Blends and Composites summaries recent research progress on bioepoxy polymers as well as their blends and composites. It covers aspects from synthesis, processing, various characterization techniques to broad spectrum of applications. It provides a correlation of physical properties with macro, micro and nanostructures of the materials. Moreover, research trends, future directions, and opportunities are also discussed. Attracts attention: Bioepoxy polymers are environmentally friendly and considered as a promising candidate to replace the traditional thermosetting nonbiodegradable polymers Highly application-oriented: Bioepoxy polymers can be used in a broad range of applications such as polymer foams, construction, aerospace, automobiles, self-healing systems One-stop reference: Covers all aspects of bioepoxy polymer, their blends and composites, such as synthesis, properties, processing, characterization and applications Broad audience: Attracts attention from both academia and industry

Download or read book Trends in Packaging of Food Beverages and Other Fast Moving Consumer Goods FMCG written by Neil Farmer and published by Elsevier. This book was released on 2013-02-26 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt: Packaging plays an essential role in protecting and extending the shelf life of a wide range of foods, beverages and other fast-moving consumer goods. There have been many key developments in packaging materials and technologies in recent years, and Trends in packaging of food, beverages and other fast-moving consumer goods (FMCG) provides a concise review of these developments and international market trends. Beginning with a concise introduction to the present status and trends in innovations in packaging for food, beverages and other fast-moving consumer goods, the book goes on to consider modified atmosphere packaging and other active packaging systems, including smart and intelligent packaging, and the role these play in augmenting and securing the consumer brand experience. Developments in plastic and bioplastic materials and recycling systems are then discussed, followed by innovations and trends in metal, paper and paperboard packaging. Further chapters review international environmental and sustainability regulatory and legislative frameworks, before the use of nanotechnology, smart and interactive packaging developments for enhanced communication at the packaging/user interface are explored. Finally, the book concludes by considering potential future trends in materials and technologies across the international packaging market. With its distinguished editor and international team of expert contributors, Trends in packaging of food, beverages and other fast-moving consumer goods (FMCG) is an important reference tool, providing a practical overview of emerging packaging technologies and market trends for research and design professionals in the food and packaging industry, and academics working in this area. Introduces the present status, current trends and new innovations in the field whilst considering future trends in materials and technologies Considers modified atmosphere packaging and other active packaging systems including smart and intelligent packaging Discusses developments in plastic and bioplastic materials and recycling systems

Download or read book Polymer Science A Comprehensive Reference written by and published by Newnes. This book was released on 2012-12-05 with total page 7752 pages. Available in PDF, EPUB and Kindle. Book excerpt: The progress in polymer science is revealed in the chapters of Polymer Science: A Comprehensive Reference, Ten Volume Set. In Volume 1, this is reflected in the improved understanding of the properties of polymers in solution, in bulk and in confined situations such as in thin films. Volume 2 addresses new characterization techniques, such as high resolution optical microscopy, scanning probe microscopy and other procedures for surface and interface characterization. Volume 3 presents the great progress achieved in precise synthetic polymerization techniques for vinyl monomers to control macromolecular architecture: the development of metallocene and post-metallocene catalysis for olefin polymerization, new ionic polymerization procedures, and atom transfer radical polymerization, nitroxide mediated polymerization, and reversible addition-fragmentation chain transfer systems as the most often used controlled/living radical polymerization methods. Volume 4 is devoted to kinetics, mechanisms and applications of ring opening polymerization of heterocyclic monomers and cycloolefins (ROMP), as well as to various less common polymerization techniques. Polycondensation and non-chain polymerizations, including dendrimer synthesis and various "click" procedures, are covered in Volume 5. Volume 6 focuses on several aspects of controlled macromolecular architectures and soft nano-objects including hybrids and bioconjugates. Many of the achievements would have not been possible without new characterization techniques like AFM that allowed direct imaging of single molecules and nano-objects with a precision available only recently. An entirely new aspect in polymer science is based on the combination of bottom-up methods such as polymer synthesis and molecularly programmed self-assembly with top-down structuring such as lithography and surface templating, as presented in Volume 7. It encompasses polymer and nanoparticle assembly in bulk and under confined conditions or influenced by an external field, including thin films, inorganic-organic hybrids, or nanofibers. Volume 8 expands these concepts focusing on applications in advanced technologies, e.g. in electronic industry and centers on combination with top down approach and functional properties like conductivity. Another type of functionality that is of rapidly increasing importance in polymer science is introduced in volume 9. It deals with various aspects of polymers in biology and medicine, including the response of living cells and tissue to the contact with biofunctional particles and surfaces. The last volume is devoted to the scope and potential provided by environmentally benign and green polymers, as well as energy-related polymers. They discuss new technologies needed for a sustainable economy in our world of limited resources. Provides broad and in-depth coverage of all aspects of polymer science from synthesis/polymerization, properties, and characterization methods and techniques to nanostructures, sustainability and energy, and biomedical uses of polymers Provides a definitive source for those entering or researching in this area by integrating the multidisciplinary aspects of the science into one unique, up-to-date reference work Electronic version has complete cross-referencing and multi-media components Volume editors are world experts in their field (including a Nobel Prize winner)

Download or read book The Water Food Energy Nexus written by I. M. Mujtaba and published by CRC Press. This book was released on 2017-09-11 with total page 846 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exponential growth of the worldwide population requires increasing amounts of water, food, and energy. However, as the quantity of available fresh water and energy sources directly affecting cost of food production and transportation diminishes, technological solutions are necessary to secure sustainable supplies. In direct response to this reality, this book focuses on the water-energy-food nexus and describes in depth the challenges and processes involved in efficient water and energy production and management, wastewater treatment, and impact upon food and essential commodities. The book is organized into 4 sections on water, food, energy, and the future of sustainability, highlighting the interplay among these topics. The first section emphasizes water desalination, water management, and wastewater treatment. The second section discusses cereal processing, sustainable food security, bioenergy in food production, water and energy consumption in food processing, and mathematical modeling for food undergoing phase changes. The third section discusses fossil fuels, biofuels, synthetic fuels, renewable energy, and carbon capture. Finally, the book concludes with a discussion of the future of sustainability, including coverage of the role of molecular thermodynamics in developing processes and products, green engineering in process systems, petrochemical water splitting, petrochemical approaches to solar hydrogen generation, design and operation strategy of energy-efficient processes, and the sustainability of process, supply chain, and enterprise.

Download or read book Biopolymers and Composites written by Samy A. Madbouly and published by Walter de Gruyter GmbH & Co KG. This book was released on 2021-10-04 with total page 394 pages. Available in PDF, EPUB and Kindle. Book excerpt: The growing interest in replacing petroleum-based products by inexpensive, renewable, natural materials will have a significant impact on sustainability, environment, and the polymer industry. This book provides scientists a useful framework to help take advantage of the latest research conducted in this rapidly advancing field enabling them to develop and commercialize their own products quickly and more successfully.