Download or read book Biogenic Fluxes of Oxygenated Volatile Organic Compounds to the Atmosphere written by Bradly M. Baker and published by . This book was released on 2000 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Volatile Organic Compounds in the Atmosphere written by Ralf Koppmann and published by Wiley-Blackwell. This book was released on 2008-04-15 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: Every day, large quantities of volatile organic compounds (VOCs) are emitted into the atmosphere from both anthropogenic and natural sources. The formation of gaseous and particulate secondary products caused by oxidation of VOCs is one of the largest unknowns in the quantitative prediction of the earth's climate on a regional and global scale, and on the understanding of local air quality. To be able to model and control their impact, it is essential to understand the sources of VOCs, their distribution in the atmosphere and the chemical transformations which remove these compounds from the atmosphere. In recent years techniques for the analysis of organic compounds in the atmosphere have been developed to increase the spectrum of detectable compounds and their detection limits. New methods have been introduced to increase the time resolution of those measurements and to resolve more complex mixtures of organic compounds. Volatile Organic Compounds in the Atmosphere describes the current state of knowledge of the chemistry of VOCs as well as the methods and techniques to analyse gaseous and particulate organic compounds in the atmosphere. The aim is to provide an authoritative review to address the needs of both graduate students and active researchers in the field of atmospheric chemistry research.
Download or read book Biogenic Volatile Organic Compounds in the Atmosphere written by Günter Helas and published by Balogh Scientific Books. This book was released on 1997 with total page 196 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Concentrations and Fluxes of Atmospheric Biogenic Volatile Organic Compounds by Proton Transfer Reaction Mass Spectrometry written by Pawel Konrad Misztal and published by . This book was released on 2010 with total page 499 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are few published direct measurements of the atmosphere-surface exchange of volatile organic compounds (VOCs), particularly for biogenic VOCs (BVOCs). Global modelling of atmospheric chemistry and transport of BVOCs has large uncertainties due to the very small number of measurements in tropical regions, which are responsible for half the global BVOC emissions. This thesis presents direct measurements of concentrations and ecosystem fluxes of BVOCs in different regions (Tropics, Mediterranean) using the approach of virtual disjunct eddy covariance (vDEC) combined with proton transfer reaction mass spectrometry (PTR-MS) - a real-time BVOC sensor. The field measurements also included methodological developments of the vDEC/PTR-MS approach, which will be of value to the wider flux measurement community. A novel approach to determining the lag time between the vertical wind measurement and the air concentration measurement has been developed that will greatly reduce the uncertainty in the derived flux measurements. In the laboratory, the selectivity of PTR-MS was investigated by designing an alternating drift-voltage mode (AD-PTR-MS) to discriminate between structural isomers detected at the same m/z channel, with monoterpenes used as model compounds. The results of the measurements, particularly from the rainforest and oil palm plantations in Borneo, are novel and therefore provide important experimental constraints on models of atmospheric emissions, chemistry and transport. For example, although parameters which work reasonably well can be derived for model algorithms for the emission of isoprene from the rainforest, their performance over oil palms was less good, because of circadian controls of emissions from oil palms. However, the larger problem is the measured basal emission rates (BERs) which are significantly smaller than those used by default in the global MEGAN model. Another novel finding was the high deposition velocities of MVK and MACR (isoprene first order oxidation products) which at the oil palm plantation commonly exceeded 1 cm s-1; this result has implications for atmospheric modelling. The successful field results relied on significant developments in software for data acquisition and processing, and operational optimisation of the PTR-MS instruments in the extreme humidity encountered during the fieldwork in Borneo.
Download or read book Whole Ecosystem Measurements of Biogenic Hydrocarbon Emissions written by Allen H. Goldstein and published by . This book was released on 2001 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Reactive Hydrocarbons in the Atmosphere written by C. Nicholas Hewitt and published by Elsevier. This book was released on 1998-10-20 with total page 335 pages. Available in PDF, EPUB and Kindle. Book excerpt: The vast family of volatile organic compounds plays a central role in the chemistry of the Earth's atmosphere. Reactive Hydrocarbons in the Atmosphere provides comprehensive and up-to-date reviews covering all aspects of the behavior, sources, occurrence, and chemistry of these compounds. The book considers both biogenic and anthropogenic sources, plus their effects in the atmosphere at local, regional, and global scales. Covers a major component of atmospheric chemistry and air pollution Considers both natural background chemistry and pollution processes Provides authoritative reviews for a wide range of audiences
Download or read book Climate Change Air Pollution and Global Challenges written by Francesco Loreto and published by Elsevier Inc. Chapters. This book was released on 2013-11-19 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biogenic volatile organic compounds (BVOC) play a critical role in biosphere–atmosphere interactions and are key constraints of the physical and chemical properties of the atmosphere, potentially influencing the climate and the quality of air, especially in the areas exposed to in situ release or long-range transport of anthropogenically polluted air masses. Under these conditions, reactive BVOC may contribute to ozone and particle production. The very large amount of BVOC emitted by vegetation, estimated today to more than 1000Tg C annually, is dominated by methanol and isoprenoids, released predominantly by forest species. Such a high rate of emission implies a large metabolic cost and hence likely indicates very important plant functional roles for these compounds. BVOC can be emitted by plants constitutively, or the emission may be induced in response to biotic and abiotic factors. Both constitutive and induced isoprenoids often act as defensive compounds and are crucial for plant protection in stressful environments. The importance of volatile isoprenoids as protecting molecules has been widely discussed. However, based on the use of genetically modified plants and novel technologies that allow detection of BVOC oxidation products, the idea is emerging that especially volatile isoprenoids act as antioxidants in planta, whereas they contribute to the oxidation potential of the atmosphere.
Download or read book Biogenic Volatile Organic Compounds and Climate Change written by Federico Brilli and published by Elsevier. This book was released on 2024-06-28 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biogenic Volatile Organic Compounds and Climate Change highlights the relationship between climate change and biogenic VOC and the impact they have on each other. Topics include the synthesis and emission of VOC in plants, how they respond to environmental stresses, how sustainable agricultural practices plants can be used to directly impact climate change beyond carbon sequestration, a review of biogenic VOCs as air pollutants, and the impact of biogenic VOC on clouds. This groundbreaking work is essential for anyone in climate change, global warming and cooling, atmospheric chemistry, clouds, fate and transport of chemicals in the atmosphere, air pollution, sustainability or agriculture. Explains how volatile organic compound (VOC) production and emission in plants can ameliorate the consequences of climate change induced abiotic and biotic stresses Comprehensively addresses the complex interactions between global warming, atmospheric composition and plant ecology beyond carbon sequestration Reviews the use of biogenic VOC in sustainability
Download or read book Flux Measurements of Biogenic Precursors to Ozone and Particulate Matter in the Central Valley written by Allen H. Goldstein and published by . This book was released on 2011 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Volatile Organic Compounds in the Atmosphere written by Ralf Koppmann and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: Every day, large quantities of volatile organic compounds (VOCs) are emitted into the atmosphere from both anthropogenic and natural sources. The formation of gaseous and particulate secondary products caused by oxidation of VOCs is one of the largest unknowns in the quantitative prediction of the earth’s climate on a regional and global scale, and on the understanding of local air quality. To be able to model and control their impact, it is essential to understand the sources of VOCs, their distribution in the atmosphere and the chemical transformations which remove these compounds from the atmosphere. In recent years techniques for the analysis of organic compounds in the atmosphere have been developed to increase the spectrum of detectable compounds and their detection limits. New methods have been introduced to increase the time resolution of those measurements and to resolve more complex mixtures of organic compounds. Volatile Organic Compounds in the Atmosphere describes the current state of knowledge of the chemistry of VOCs as well as the methods and techniques to analyse gaseous and particulate organic compounds in the atmosphere. The aim is to provide an authoritative review to address the needs of both graduate students and active researchers in the field of atmospheric chemistry research.
Download or read book Trace Gas Emissions by Plants written by and published by Academic Press. This book was released on 2012-12-02 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many trace gases are exchanged between the atmosphere and the biosphere. Although much research has been published on the photosynthetic exchanges of carbon dioxide, oxygen, and water vapor, this book focuses on the importance of biogenic trace gases on atmosphere chemistry and ecosystem stability. Included are methane and its effect on the radiative properties of the atmosphere, hydrocarbons (isoprene and monoterpenes), and their role in the production of ozone and carbon monoxide. Also covered are sulfur and nitrogen gases, both of which can lead to ecosystem acidification. The biochemistry and physiology of production of these and other gases are investigated. Plant physiologists, ecologists, and atmospheric chemists and modelers will benefit from this book.
Download or read book Ocean Atmosphere Interactions of Gases and Particles written by Peter S. Liss and published by Springer. This book was released on 2013-12-18 with total page 315 pages. Available in PDF, EPUB and Kindle. Book excerpt: The oceans and atmosphere interact through various processes, including the transfer of momentum, heat, gases and particles. In this book leading international experts come together to provide a state-of-the-art account of these exchanges and their role in the Earth-system, with particular focus on gases and particles. Chapters in the book cover: i) the ocean-atmosphere exchange of short-lived trace gases; ii) mechanisms and models of interfacial exchange (including transfer velocity parameterisations); iii) ocean-atmosphere exchange of the greenhouse gases carbon dioxide, methane and nitrous oxide; iv) ocean atmosphere exchange of particles and v) current and future data collection and synthesis efforts. The scope of the book extends to the biogeochemical responses to emitted / deposited material and interactions and feedbacks in the wider Earth-system context. This work constitutes a highly detailed synthesis and reference; of interest to higher-level university students (Masters, PhD) and researchers in ocean-atmosphere interactions and related fields (Earth-system science, marine / atmospheric biogeochemistry / climate). Production of this book was supported and funded by the EU COST Action 735 and coordinated by the International SOLAS (Surface Ocean- Lower Atmosphere Study) project office.
Download or read book Biology Controls and Models of Tree Volatile Organic Compound Emissions written by Ülo Niinemets and published by Springer Science & Business Media. This book was released on 2013-07-08 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: Plant-driven volatile organic compound (BVOC) emissions play a major role in atmospheric chemistry, including ozone and photochemical smog formation in the troposphere, and they extend the atmospheric lifetime of the key greenhouse gas, methane. Furthermore, condensation of photo-oxidation products of BVOCs leads to formation of secondary organic aerosols with profound implications for the earth's solar radiation budget and climate. Trees represent the plant life form that most contributes to BVOC emissions, which gives global forests a unique role in regulating atmospheric chemistry. Written by leading experts in the field, the focus is on recent advancements in understanding the controls on plant-driven BVOC emissions, including efforts to quantitatively predict emissions using computer models, particularly on elicitation of emissions under biotic and abiotic stresses, molecular mechanisms of volatile synthesis and emission and the role of emissions in plant stress tolerance.
Download or read book Development of a System for Atmospheric Measurements of Oxygenated Volatile Organic Compounds written by Andrew H. Hart and published by . This book was released on 2009 with total page 114 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Permafrost Ecosystems written by Akira Osawa and published by Springer Science & Business Media. This book was released on 2010-01-04 with total page 507 pages. Available in PDF, EPUB and Kindle. Book excerpt: Drawing from a decade-long collaboration between Japan and Russia, this important volume presents the first major synthesis of current knowledge on the ecophysiology of the coniferous forests growing on permafrost at high latitudes. It presents ecological data for a region long inaccessible to most scientists, and raises important questions about the global carbon balance as these systems are affected by the changing climate. Making up around 20% of the entire boreal forests of the northern hemisphere, these ‘permafrost forest ecosystems’ are subject to particular constraints in terms of temperature, nutrient availability, and root space, creating exceptional ecosystem characteristics not known elsewhere. This authoritative text explores their diversity, structure, dynamics and physiology. It provides a comparison of these forests in relation to boreal forests elsewhere, and concludes with an assessment of the potential responses of this unique biome to climate change. The book will be invaluable to advanced students and researchers interested in boreal vegetation, forest ecology, silviculture and forest soils, as well as to researchers into climate change and the global carbon balance.
Download or read book Eddy Covariance written by Marc Aubinet and published by Springer Science & Business Media. This book was released on 2012-01-18 with total page 451 pages. Available in PDF, EPUB and Kindle. Book excerpt: This highly practical handbook is an exhaustive treatment of eddy covariance measurement that will be of keen interest to scientists who are not necessarily specialists in micrometeorology. The chapters cover measuring fluxes using eddy covariance technique, from the tower installation and system dimensioning to data collection, correction and analysis. With a state-of-the-art perspective, the authors examine the latest techniques and address the most up-to-date methods for data processing and quality control. The chapters provide answers to data treatment problems including data filtering, footprint analysis, data gap filling, uncertainty evaluation, and flux separation, among others. The authors cover the application of measurement techniques in different ecosystems such as forest, crops, grassland, wetland, lakes and rivers, and urban areas, highlighting peculiarities, specific practices and methods to be considered. The book also covers what to do when you have all your data, summarizing the objectives of a database as well as using case studies of the CarboEurope and FLUXNET databases to demonstrate the way they should be maintained and managed. Policies for data use, exchange and publication are also discussed and proposed. This one compendium is a valuable source of information on eddy covariance measurement that allows readers to make rational and relevant choices in positioning, dimensioning, installing and maintaining an eddy covariance site; collecting, treating, correcting and analyzing eddy covariance data; and scaling up eddy flux measurements to annual scale and evaluating their uncertainty.
Download or read book Quantifying the Ecosystem scale Emission and Deposition Fluxes of Biogenic Volatile Organic Compounds BVOC and Their Oxidation Products Above Plant Canopies written by Jeong-Hoo Park and published by . This book was released on 2012 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biogenic volatile organic compounds (BVOC) are one of the most important chemical classes in tropospheric chemistry associated with ozone and secondary organic aerosol formation. Nevertheless, their emission and deposition rates remain unknown for many potentially important plant species due to lack of measurements. Moreover, the number of BVOC species reported for flux measurement by current techniques has been limited to a small fraction of the number of compounds actually emitted or deposited. Thus, large uncertainties still exist in estimating the ecosystem-scale fluxes of BVOCs and their oxidation products (OVOC). Two intensive field observation campaigns in different vegetation ecosystems took place in summer 2009 and 2010. The Biosphere Effects on AeRosols and Photochemistry EXperiment field campaign during summer 2009 (BEARPEX 2009, June 15 - July 31) was made in a Ponderosa pine plantation on the western slope of the Sierra Nevada Mountain range in California. During summer 2010 (June 25 - July 26), another intensive BVOC concentration and flux measurement campaign was conducted as part of a one-year continuous field campaign (CITRUS 2010, October 2009 - November 2010) in an orange orchard in the Central Valley of California near Visalia. Through these two field campaigns, this dissertation presents the ecosystem-atmosphere exchange of a wide range of BVOC and OVOC by coupling state of the art VOC measurement techniques (proton transfer reaction mass spectrometry; PTR-MS, and proton transfer reaction - time of flight - mass spectrometry; PTR-TOF-MS) with a well-established micrometeorological approach (eddy-covariance method; EC). Ambient concentrations of BVOC and OVOC were simultaneously measured for investigating fluxes and vertical gradients in both field sites along with the meteorological parameters. From BEARPEX 2009, I developed an approach of using the flux and gradient relationship from species which could be measured quickly enough to use the EC flux method (e.g. 5 Hz) to determine the eddy diffusivity (K), the apply that K to estimate the flux of species for which sufficiently fast measurements were not available to use the EC method. In the past, K had been inferred from heat, H2O and CO2 which don't have similar exchange characteristics as BVOC, thus I suggest using a universal K derived from multiple BVOC can more accurately be applied where PTR-MS measurements are conducted. In the CITRUS field campaign we simultaneously used PTR-MS for flux measurements of 3 species and vertical concentration gradient measurements of 27 species, and PTR-TOF-MS for flux and concentration measurements of a much fuller suite of VOCs above the plant canopy. Using the PTR-TOF-MS we demonstrate for the first time that there were significant emission for 27 VOC species for which concentration is commonly measured by PTR-MS, demonstrating not only the strong potential in use of PTR-TOF-MS in EC flux application but also possible underestimation in current knowledge about BVOC emission from land vegetation. For example, acetic acid was missed in flux measurements by the PTR-MS technique; however, acetic acid was here observed to be the third largest emission of any VOC species in the Orange orchard. I demonstrate for the first time how the application of PTR-TOF-MS can expand our observational capabilities and changes the scope of understanding of VOC exchanges at atmosphere-biosphere interface. Previous work has mostly focused on quantifying emission strength from vegetation for a limited number of BVOC species. However, the results from flux measurements performed during CITRUS 2010 show the existence of significant deposition flux of BVOC and their oxidation products in addition to their emissions. Additionally, active ecosystem-atmosphere exchanges of the vast majority of the VOCs observed (at least 494 species) were discovered by applying a new approach (time shifted absolute value covariance). Through this measurement and analysis, I proved the existence of ecosystem-scale exchanges of species showing vast majority of VOC have bi-directional flux - both upward and downward. This observation is unprecedented, and revealed that most VOC species have at least some active exchange between the biosphere and atmosphere. The observational evidence of active VOC exchanges in two independent ecosystems in this dissertation provides significant insights of interaction between the biosphere and atmosphere, coupling the VOC exchange and photochemistry within and above the plant canopy.
