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Book BIFUNCTIONAL CATALYSTS FOR THE SELECTIVE CATALYTIC REDUCTION OF NO BY HYDROCARBONS

Download or read book BIFUNCTIONAL CATALYSTS FOR THE SELECTIVE CATALYTIC REDUCTION OF NO BY HYDROCARBONS written by and published by . This book was released on 2003 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Novel bifunctional catalysts combining two active phases, typically Cu-ZSM-5 and a modifier, were prepared and tested for the selective catalytic reduction of nitrogen oxides using propylene in order to overcome the hindering effects of water typically seen for single-phase catalysts such as Cu-ZSM-5. The catalysts were made by typical preparation techniques, but parameters could be varied to influence the catalyst. The physical characterization of the materials showed that the modification phase was added strictly to the external surface of the zeolite without hindering any internal surface area. Chemical characterization by temperature programmed reactions, DRIFTS and x-ray absorption spectroscopy indicated strong interaction between the two phases, primarily producing materials that exhibited lower reduction temperatures. Two improvements in NOx reduction activity (1000 ppm NO, 1000 ppm C3H6, 2% O2, 30,000 hr-1 GHSV) were seen for these catalysts compared with Cu- ZSM-5: a lower temperature of maximum NOx conversion activity (as low at 250 C), and an enhancement of activity when water was present in the system. The use of a second phase provides a way to further tune the properties of the catalyst in order to achieve mechanistic conditions necessary to maximize NOx remediation.

Book Selective Catalytic Reduction of NOx

Download or read book Selective Catalytic Reduction of NOx written by Oliver Kröcher and published by MDPI. This book was released on 2018-12-14 with total page 281 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a printed edition of the Special Issue "Selective Catalytic Reduction of NOx" that was published in Catalysts

Book New Heterogeneous Catalysts for the Selective Reduction of NOx Under Lean Conditions Final Report

Download or read book New Heterogeneous Catalysts for the Selective Reduction of NOx Under Lean Conditions Final Report written by and published by . This book was released on 2004 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: The original goal of this program was the identification and design of new noble-metal-based catalysts for the selective catalytic reduction of nitric oxide by hydrocarbons under excess oxygen (i.e., ''lean'') conditions (HC-SCR). Work conducted in the first funding cycle of this award (i.e., 1997-2000) was successful in allowing us to develop an understanding of the fundamental surface chemistry taking place during the adsorption and reaction of nitrogen oxides and propylene on the surface of supported noble metal catalysts. Both experimental results collected in our own group as well as molecular simulation results published by Professor Neurock suggested that in order to improve the performance of the Pt catalysts--in terms of the nitrogen selectivity and the temperature window of operation-- it was necessary to introduce a second metal. However, synthesizing such catalysts with the metals of interest (i.e., Pt-Au, Pt-Ru, Pt-Rh, etc.) with some degree of control of the structure and composition of the resulting supported metal particles is in itself a research challenge. Consequently, the bulk of our efforts during the second funding cycle of this award (covered by this report) was shifted to the use of organometallic cluster precursors for the synthesis on novel bimetallic catalysts. During this time we have also continued to maintain an interest in NOx abatement, but have redirected our efforts from the HC-SCR process to the more promising from a commercial standpoint NOx Storage Reduction (NSR) approach.

Book Superior Catalysts for Selective Catalytic Reduction of Nitric Oxide

Download or read book Superior Catalysts for Selective Catalytic Reduction of Nitric Oxide written by and published by . This book was released on 1994 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book NOx Trap Catalysts and Technologies

Download or read book NOx Trap Catalysts and Technologies written by Luca Lietti and published by Royal Society of Chemistry. This book was released on 2018-06-13 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book will be the first to comprehensively present the current research on catalysts used for NOx abatement in lean exhausts.

Book Plasma assisted Catalytic Reduction of NO sub x sub

Download or read book Plasma assisted Catalytic Reduction of NO sub x sub written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Many studies suggest that lean-NOx SCR proceeds via oxidation of NO to NO[not] by oxygen, followed by the reaction of the NO[not]with hydrocarbons. On catalysts that are not very effective in catalyzing the equilibration of NO+O[not] and NO[not], the rate of N[not] formation issubstantially higher when the input NOx is NO[not] instead of NO. The apparent bifunctional mechanism in the SCR ofNOx has prompted the use of mechanically mixed catalyst components, in which one component is used to accelerate theoxidation of NO to NO[not], and another component catalyzes the reaction between NO[not] and the hydrocarbon. Catalysts that previously wereregarded as inactive for NOx reduction could therefore become efficient when mixed with an oxidation catalyst. PreconvertingNO to NO[not] opens the opportunity for a wider range of SCR catalysts and perhaps improves the durability of these catalysts. This paperdescribes the use of a non-thermal plasma as an efficient means for selective partial oxidation of NO to NO[not]. When combined with sometypes of SCR catalyst, the plasma can greatly enhance the NOx reduction and eliminate some of the deficiencies encountered inan entirely catalyst-based approach. efficiency for reduction of NOsubx

Book Zeolites and Mesoporous Materials at the Dawn of the 21st Century

Download or read book Zeolites and Mesoporous Materials at the Dawn of the 21st Century written by A. Galarneau and published by Elsevier. This book was released on 2001-08-13 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Zeolites and Mesporous Materials at the Dawn of the 21st Century Proceedings are the expression of the oral and poster communications which where presented during the 13th International Zeolite Conference (IZC). They are subdivided into 32 thematic sessions starting from the genesis of materials to their applications through their characterisation. The paper volume contains the full texts of the 5 plenary and 6 keynote lectures and informative summaries of 150 oral and 540 poster presentations. These contributions have been selected among the 903 submissions received from a total of 57 countries! In order to gather all the communications in a handy document, the full texts of oral and poster presentations are available in CD-ROM. Besides the fields of zeolite science always represented at IZC (synthesis, characterisation, catalysis, etc¿), some subjects strengthened their position (mesoporous materials, theory and modelling), new areas emerge (advanced materials, environmental and life sciences) and older ones regain interest (natural zeolites). The understanding and development of the unique properties of porous materials relies on a unique blend of multidisciplinary knowledge: material science, with the implication of organic and colloid chemistry, to prepare micro- and mesoporous materials, surface and adsorption science sustained by theory and modelling to understand the peculiar behaviour of molecules in confined systems, special branches of catalysis, physics, chemical engineering and life science to design novel applications. The gathering of these elements is at the basis of a fruitful and evolutionary zeolite science, as it is hopefully reflected by these proceedings.

Book Engineering bifunctional catalysts for hydrocarbon valorization

Download or read book Engineering bifunctional catalysts for hydrocarbon valorization written by José Ignacio Villegas Perdomo and published by . This book was released on 2006 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Heterogeneous Catalysts

Download or read book Heterogeneous Catalysts written by Wey Yang Teoh and published by John Wiley & Sons. This book was released on 2021-02-23 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents state-of-the-art knowledge of heterogeneous catalysts including new applications in energy and environmental fields This book focuses on emerging techniques in heterogeneous catalysis, from new methodology for catalysts design and synthesis, surface studies and operando spectroscopies, ab initio techniques, to critical catalytic systems as relevant to energy and the environment. It provides the vision of addressing the foreseeable knowledge gap unfilled by classical knowledge in the field. Heterogeneous Catalysts: Advanced Design, Characterization and Applications begins with an overview on the evolution in catalysts synthesis and introduces readers to facets engineering on catalysts; electrochemical synthesis of nanostructured catalytic thin films; and bandgap engineering of semiconductor photocatalysts. Next, it examines how we are gaining a more precise understanding of catalytic events and materials under working conditions. It covers bridging pressure gap in surface catalytic studies; tomography in catalysts design; and resolving catalyst performance at nanoscale via fluorescence microscopy. Quantum approaches to predicting molecular reactions on catalytic surfaces follows that, along with chapters on Density Functional Theory in heterogeneous catalysis; first principles simulation of electrified interfaces in electrochemistry; and high-throughput computational design of novel catalytic materials. The book also discusses embracing the energy and environmental challenges of the 21st century through heterogeneous catalysis and much more. Presents recent developments in heterogeneous catalysis with emphasis on new fundamentals and emerging techniques Offers a comprehensive look at the important aspects of heterogeneous catalysis Provides an applications-oriented, bottoms-up approach to a high-interest subject that plays a vital role in industry and is widely applied in areas related to energy and environment Heterogeneous Catalysts: Advanced Design, Characterization and Applications is an important book for catalytic chemists, materials scientists, surface chemists, physical chemists, inorganic chemists, chemical engineers, and other professionals working in the chemical industry.

Book Plasma assisted Catalytic Reduction of NOx

Download or read book Plasma assisted Catalytic Reduction of NOx written by and published by . This book was released on 1998 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Many studies suggest that lean-NOx SCR proceeds via oxidation of NO to NO¬ by oxygen, followed by the reaction of the NO¬ with hydrocarbons. On catalysts that are not very effective in catalyzing the equilibration of NO+O¬ and NO¬, the rate of N¬ formation is substantially higher when the input NOx is NO¬ instead of NO. The apparent bifunctional mechanism in the SCR of NOx has prompted the use of mechanically mixed catalyst components, in which one component is used to accelerate the oxidation of NO to NO¬, and another component catalyzes the reaction between NO¬ and the hydrocarbon. Catalysts that previously were regarded as inactive for NOx reduction could therefore become efficient when mixed with an oxidation catalyst. Preconverting NO to NO¬ opens the opportunity for a wider range of SCR catalysts and perhaps improves the durability of these catalysts. This paper describes the use of a non-thermal plasma as an efficient means for selective partial oxidation of NO to NO¬. When combined with some types of SCR catalyst, the plasma can greatly enhance the NOx reduction and eliminate some of the deficiencies encountered in an entirely catalyst-based approach. efficiency for reduction of NOx

Book Porous Materials in Environmentally Friendly Processes

Download or read book Porous Materials in Environmentally Friendly Processes written by I. Kiricsi and published by Elsevier. This book was released on 1999-07-30 with total page 841 pages. Available in PDF, EPUB and Kindle. Book excerpt: To leave our planet liveable in the next millennium mankind is forced to find environmentally friendly ways in solving the problems of everyday life. Among others, technologies of producing chemicals, absolutely necessary for maintaining a comfortable life, have to be modified, in some instances fundamentally changed now, or in the very near future. Developing new technologies requires strong and innovative fundamental research. In order to provide opportunity for crossfertilization the Federation of European Zeolite Associations (FEZA) decided to organise a conference, where researchers from academia as well as industry can meet, exchange ideas, show and discuss research efforts and results concerning the development of environmentally friendly processes and technologies. The conference, and thus the proceedings are divided into two main parts. The first part contains works concerning the synthesis, modification and characterisation of zeolitic materials as catalyst candidates in environmentally friendly technologies. Works in the second part describe various applications starting from developing highly selective reactions for the fine chemical industry, through waste-water treatment to applying zeolite for formulating bacteria for pest control.