Download or read book Azides and Nitrenes written by Eric Scriven and published by Elsevier. This book was released on 2012-12-02 with total page 557 pages. Available in PDF, EPUB and Kindle. Book excerpt: Azides and Nitrenes: Reactivity and Utility provides information pertinent to the fundamentals aspects of the chemistry of azides and nitrenes. This book discusses the mechanism and synthetic applications of alkyl azides. Organized into 10 chapters, this book begins with an overview of the properties and chemistry of alkyl azides and alkylnitrenes. This text then examines the various pathways to the preparation of vinyl azides. Other chapters consider the magnetic resonance spectrum of phenyl azide, which may be taken as a representative to which more complex examples can be related. This book discusses as well the acyl azides and acylnitrenes that have their nitrogen function attached to electron-withdrawing groups not possessing a heteroatom bearing an unshared electron pair next to the nitrogen function. The final chapter deals with the main uses for organic azides involved in photochemical cross-linking of polymeric systems. This book is a valuable resource for chemists, spectroscopists, and theoreticians.
Download or read book Azides and Nitrenes written by Eric F. V. Scriven and published by . This book was released on 1984-01-01 with total page 542 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organic Azides written by Stefan Bräse and published by John Wiley & Sons. This book was released on 2010-02-01 with total page 537 pages. Available in PDF, EPUB and Kindle. Book excerpt: Most current state-of-the-art overview of this important class of compounds, encompassing many new and emerging applications The number of articles on organic azides continues to increase tremendously; on average, there are more than 1000 new publications a year Covers basic chemistry as well as state-of-the-art applications in life science and materials science World-ranked authors describe their own research in the wider context of azide chemistry Includes a chapter on safe synthesis and handling (azides can decompose explosively)
Download or read book Nitrenes and Nitrenium Ions written by Daniel E. Falvey and published by John Wiley & Sons. This book was released on 2013-04-10 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt: Featuring contributions respected leaders in the field, Nitrene and Nitrenium Ions is the first comprehensive book to explore the role of reactive intermediate nitrene and nitrenium ions in chemistry and biochemistry. Covering a broad range of topics, including ultrafast studies, computational studies, behavior in aqueous solution, electronic structures, and reactions with aromatic compounds, this valuable resource will empower graduate students and researchers to better understand and expand their synthetic utility.
Download or read book The Aryl Nitrene Intermediate written by James Wagy Hill and published by . This book was released on 1968 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organic Azides written by Stefan Bräse and published by John Wiley & Sons. This book was released on 2011-09-23 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: Most current state-of-the-art overview of this important class of compounds, encompassing many new and emerging applications The number of articles on organic azides continues to increase tremendously; on average, there are more than 1000 new publications a year Covers basic chemistry as well as state-of-the-art applications in life science and materials science World-ranked authors describe their own research in the wider context of azide chemistry Includes a chapter on safe synthesis and handling (azides can decompose explosively)
Download or read book Toward the Synthesis of Azido crown Ethers with Unusual Nitrene Reactivity written by Megan E. Williams and published by . This book was released on 2011 with total page 65 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Advanced Organic Chemistry written by Francis A. Carey and published by Springer Science & Business Media. This book was released on 2007-09-06 with total page 1344 pages. Available in PDF, EPUB and Kindle. Book excerpt: The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part B describes the most general and useful synthetic reactions, organized on the basis of reaction type. It can stand-alone; together, with Part A: Structure and Mechanisms, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for students and exercise solutions for instructors.
Download or read book Heterocycles from Carbenes and Nitrenes written by Michael P. Doyle and published by Springer Nature. This book was released on 2023-08-09 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of recent developments in the applications of reactions involving carbene and nitrene intermediates directed to the synthesis of heterocyclic compounds. Multiple pathways through which diverse heterocyclic compounds are accessed occur from a variety of carbene and nitrene precursors through C-H/X-H insertions, cycloadditions, ylide transformations, rearrangements, and cascade reactions. Catalytic processes that form metallo-carbenes and nitrenes offer unparalleled chemo-, regio-, and stereo-selectivities. Insights are provided into the scope of these methodologies and the inherent control of catalyst ligands on reaction selectivities.
Download or read book Aziridines and Epoxides in Organic Synthesis written by Andrei K. Yudin and published by John Wiley & Sons. This book was released on 2006-02-20 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aziridines and epoxides are among the most widely used intermediates in organic synthesis, acting as precursors to complex molecules due to the strains incorporated in their skeletons. Besides their importance as reactive intermediates, many biologically active compounds also contain these three-membered rings. Filling a gap in the literature, this clearly structured book presents the much needed information in a compact and concise way. The renowned editor has succeeded in gathering together excellent authors to cover synthesis, applications, and the biological aspects in equal depth. Divided roughly equally between aziridines and epoxides, the twelve chapters discuss: * Synthesis of aziridines * Nucleophilic ring-opening of aziridines and epoxides * Organic synthesis with aziridine building blocks * Vinyl aziridines in organic synthesis * Diastereoselective aziridination reagents * Synthetic aspects of aziridinomitocene chemistry * Biosynthesis of biologically important aziridines * Organic catalysis of epoxide and aziridine ring formation * Metal-mediated synthesis of epoxides * Asymmetric epoxide ring opening chemistry * Epoxides in complex molecule synthesis * Biological activity of epoxide-containing molecules A high-quality reference manual for academic and industrial chemists alike.
Download or read book Carbenes Nitrenes and Arynes written by Thomas Lonsdale Gilchrist and published by . This book was released on 1969 with total page 144 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Carbonyl Nitrenes written by Paul Francis Alewood and published by . This book was released on 1973 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book CRC Handbook of Organic Photochemistry and Photobiology Volumes 1 2 written by William M. Horspool and published by CRC Press. This book was released on 2003-09-29 with total page 2898 pages. Available in PDF, EPUB and Kindle. Book excerpt: The second edition of this best-selling handbook is bigger, more comprehensive, and now completely current. In addition to thorough updates to the discussions featured in the first edition, this edition includes 66 new chapters that reflect recent developments, new applications, and emerging areas of interest. Within the handbook's 145 critically r
Download or read book Organic Photochemistry written by Albert Padwa and published by Routledge. This book was released on 2017-10-02 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic photochemistry is the science arising from the application of photochemicalmethods to organic chemistry and organic chemical methods to photochemistry. It is aninterdisciplinary frontier.Intense activity in organic photochemistry in the last decade has produced so vast anaccumulation of factual knowledge that chemists in general have viewed it with awe.Even those chemists engaged in the study of organic photochemistry will find the rate ofdevelopment in the field perplexing to a high degree. This series originated to fill theneed for a critical summary of this vigorously expanding field with the purpose ofdrawing together seemingly unrelated facts, summarizing progress, and clarifyingproblems.Volume 11 continues to fulfill the original, essential role of this unique series byproviding a convenient review of the structural aspects of organic photochemistry. Aswith earlier volumes, this new book offers the research findings of distinguishedauthorities. It stresses timely aspects of organic photochemistry-previously scatteredthroughout the large body of literature-for which necessary critical review has beenlacking.This volume of the series emphasizes the mechanistic details of the di-n:-methanerearrangement . .. the synthetic aspects of the oxadi-n:-methane reaction ... thephotochemistry of carbenium ions and related species .. . photoinduced hydrogen atomabstraction by carbonyl compounds ... and matrix photochemistry of nitrenes, carbenes,and excited triplet states. Complete with numerous illustrations and bibliographiccitations of the literature, this book explores these important processes to the advantageof organic chemists, as an aid to research and as a source for supplementary knowledgeon particular topics .
Download or read book Oxidation written by Barry M. Trost and published by Elsevier. This book was released on 1991 with total page 1048 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 7.
Download or read book Triplet Alkyl Nitrene Intermediates written by and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In this research intermolecular and intramolecular triplet sensitization has been employed to photochemically generate triplet alkyl nitrene intermediates in solution. Photolyzing with light greater than 300 nm assures that only the ketone chromophore is exclusively excited to its triplet excited state. Once generated, the ketone can transfer its triplet energy to the azide moiety which loses molecular nitrogen to give a triplet alkyl nitrene intermediate. Intermolecular triplet sensitization in solution allowed trapping of triplet alkyl nitrene intermediates via bimolecular reactions. Photolysis of 1-azidoadamantane in solution with acetophenone, benzophenone and acetone led to an azo-dimer as the major product. This product comes from dimerization of two triplet alkyl nitrenes. Intermolecular sensitized photolysis of benzyl azide led to N-methyleneaniline as the major photoproduct with acetophenone as the triplet sensitizer. With benzophenone as the triplet sensitizer the major product was benzylideneamine, which comes from H-atom abstraction by benzophenone from azide 1.
Download or read book Spectral Properties of Substituted Triplet Phenyl Nitrenes written by James Martin Fargher and published by . This book was released on 1970 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt:
