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Book Atomic scale Modeling of Transition metal Doping of Semiconductor Nanocrystals

Download or read book Atomic scale Modeling of Transition metal Doping of Semiconductor Nanocrystals written by Tejinder Singh and published by . This book was released on 2011 with total page 225 pages. Available in PDF, EPUB and Kindle. Book excerpt: Doping in bulk semiconductors (e.g., n- or p- type doping in silicon) allows for precise control of their properties and forms the basis for the development of electronic and photovoltaic devices. Recently, there have been reports on the successful synthesis of doped semiconductor nanocrystals (or quantum dots) for potential applications in solar cells and spintronics. For example, nanocrystals of ZnSe (with zinc-blende lattice structure) and CdSe and ZnO (with wurtzite lattice structure) have been doped successfully with transition-metal (TM) elements (Mn, Co, or Ni). Despite the recent progress, however, the underlying mechanisms of doping in colloidal nanocrystals are not well understood. This thesis reports a comprehensive theoretical analysis toward a fundamental kinetic and thermodynamic understanding of doping in ZnO, CdSe, and ZnSe quantum dots based on first-principles density-functional theory (DFT) calculations. The theoretical predictions of this thesis are consistent with experimental measurements and provide fundamental interpretations for the experimental observations. The mechanisms of doping of colloidal ZnO nanocrystals with the TM elements Mn, Co, and Ni is investigated. The dopant atoms are found to have high binding energies for adsorption onto the Zn-vacancy site of the (0001) basal surface and the O-vacancy site of the (0001) basal surface of ZnO nanocrystals; therefore, these surface vacancies provide viable sites for substitutional doping, which is consistent with experimental measurements. However, the doping efficiencies are affected by the strong tendencies of the TM dopants to segregate at the nanocrystal surface facets, as indicated by the corresponding computed dopant surface segregation energy profiles. Furthermore, using the Mn doping of CdSe as a case study, the effect of nanocrystal size on doping efficiency is explored. It is shown that Mn adsorption onto small clusters of CdSe is characterized by high binding energies, which, in conjunction with the Mn surface segregation characteristics on CdSe nanocrystals, explains experimental reports of high doping efficiency for small-size CdSe clusters. In addition, this thesis presents a systematic analysis of TM doping in ZnSe nanocrystals. The analysis focuses on the adsorption and surface segregation of Mn dopants on ZnSe nanocrystal surface facets, as well as dopant-induced nanocrystal morphological transitions, and leads to a fundamental understanding of the underlying mechanisms of dopant incorporation into growing nanocrystals. Both surface kinetics (dopant adsorption onto the nanocrystal surface facets) and thermodynamics (dopant surface segregation) are found to have a significant effect on the doping efficiencies in ZnSe nanocrystals. The analysis also elucidates the important role in determining the doping efficiency of ZnSe nanocrystals played by the chemical potentials of the growth precursor species, which determine the surface structure and morphology of the nanocrystals.

Book Rare Earth and Transition Metal Doping of Semiconductor Materials

Download or read book Rare Earth and Transition Metal Doping of Semiconductor Materials written by Volkmar Dierolf and published by Woodhead Publishing. This book was released on 2016-01-23 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rare Earth and Transition Metal Doping of Semiconductor Material explores traditional semiconductor devices that are based on control of the electron's electric charge. This book looks at the semiconductor materials used for spintronics applications, in particular focusing on wide band-gap semiconductors doped with transition metals and rare earths. These materials are of particular commercial interest because their spin can be controlled at room temperature, a clear opposition to the most previous research on Gallium Arsenide, which allowed for control of spins at supercold temperatures. Part One of the book explains the theory of magnetism in semiconductors, while Part Two covers the growth of semiconductors for spintronics. Finally, Part Three looks at the characterization and properties of semiconductors for spintronics, with Part Four exploring the devices and the future direction of spintronics. - Examines materials which are of commercial interest for producing smaller, faster, and more power-efficient computers and other devices - Analyzes the theory behind magnetism in semiconductors and the growth of semiconductors for spintronics - Details the properties of semiconductors for spintronics

Book Transition Metal Compounds

Download or read book Transition Metal Compounds written by Sajjad Haider and published by BoD – Books on Demand. This book was released on 2021-06-09 with total page 121 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explores synthesis, structural changes, properties, and potential applications of transition metal (TM) compounds. Over three sections, chapters cover such topics as the synthesis of pentoxide vanadium (V2O5), the effect of TM compounds on structural, dielectric properties and high-temperature superconductors, and TM-doped nanocrystals (NCs).

Book Transition Metal Doped Colloidal Semiconductor Nanocrystals

Download or read book Transition Metal Doped Colloidal Semiconductor Nanocrystals written by Franziska Muckel and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Doping And Photophysical Properties Of II VI Semiconductor Nanocrystals

Download or read book Doping And Photophysical Properties Of II VI Semiconductor Nanocrystals written by and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Semiconductor nanocrystals with sizes comparable to the corresponding bulk excitonic diameter exhibit unique size-dependent electronic and optical properties resulting from quantum confinement effect. Such nanocrystals not only allow the study of evolution of bulk properties from the molecular limit providing important fundamental understandings, but also have great technological implications, leading to intense research over the past several years. Besides tuning the crystal size in the nm regime to obtain novel properties, an additional route to derive new functionalities has been to dope transition metal ions into a semiconductor host. Thus, transition metal doped nanocrystals are of great interest since it allows two independent ways to functionalize semiconductor materials, one via the tunability of properties by size variation and other due to properties of such dopants. Chapter 1 of the thesis provide a general introduction to the subject matters dealt in with this thesis, while the necessary methodologies have been discussed in chapter 2. Chapters 3 and 4 of this thesis deal with nanocrystal doping. Following suggestions in previous literatures that the doping of nanocrystal depends strongly upon the crystal structure of the synthesized host nanocrystal, we have studied the phase-transformation between the somewhat zinc-blende and the usual wurtzite structures for CdS and CdSe nanocrystals in chapter 5. In chapter 6 we have pointed out that a gradient structure is essential to achieve nearly ideal photoluminescence efficiency using heterostructured nanocrystals and also achieved strong two-photon absorptions, adding optical bifunctionality to these nanocrystals. Finally, in chapter 7, we establish different approaches to generate white-light using nanocrystals and their unique advantages, as a first step to realizing white light emitting devices. Chapter 1 provides a brief introduction to various interesting properties and concepts relevant for the studies c.

Book Atomic scale Modeling of Nanostructured Metals and Alloys

Download or read book Atomic scale Modeling of Nanostructured Metals and Alloys written by Alexander Stukowski and published by . This book was released on 2010 with total page 155 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Editors    Showcase  Nanotechnology

Download or read book Editors Showcase Nanotechnology written by Jan M. Macak and published by Frontiers Media SA. This book was released on 2024-06-18 with total page 154 pages. Available in PDF, EPUB and Kindle. Book excerpt: We are pleased to present the latest Editors’ Showcase: Nanotechnology Research Topic. This exclusive article collection is led by Specialty Chief Editors, Professors Jan Macák, Giancarlo Franzese, Nicolae Coriolan Panoiu, John Fourkas, and Wee-Jun Ong, and submissions are open to Editorial Board members only. The work presented here celebrates the quality and diversity of research performed by our Associate and Review Editors across the entire breadth of the Nanotechnology field, and may include the latest discoveries, current challenges, and future-forward reviews and perspectives.

Book Semiconductor Nanocrystals

Download or read book Semiconductor Nanocrystals written by Alexander L. Efros and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 277 pages. Available in PDF, EPUB and Kindle. Book excerpt: A physics book that covers the optical properties of quantum-confined semiconductor nanostructures from both the theoretical and experimental points of view together with technological applications. Topics to be reviewed include quantum confinement effects in semiconductors, optical adsorption and emission properties of group IV, III-V, II-VI semiconductors, deep-etched and self assembled quantum dots, nanoclusters, and laser applications in optoelectronics.

Book Microwave Heating

    Book Details:
  • Author : Gennadiy I. Churyumov
  • Publisher : BoD – Books on Demand
  • Release : 2021-08-18
  • ISBN : 1839682264
  • Pages : 204 pages

Download or read book Microwave Heating written by Gennadiy I. Churyumov and published by BoD – Books on Demand. This book was released on 2021-08-18 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt: More than 80 years of experience in the practical application of electromagnetic energy in various fields of human activity (industry, agriculture, science, medicine, etc.) suggests that microwave heating is an effective application of electromagnetic energy. This book presents the latest investigations on the applications of microwave energy and the effects of microwave radiation on various materials and mediums. Divided into two sections on thermal and nonthermal effects, this volume contains eight chapters that examine the use of microwave energy to extract bioactive compounds from plant materials, for rock-breaking operations, to synthesize functional dyes and nanomaterials, and more.

Book Scientific and Technical Aerospace Reports

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1994 with total page 836 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Dissertation Abstracts International

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2008 with total page 868 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Catalysis and Electrocatalysis at Nanoparticle Surfaces

Download or read book Catalysis and Electrocatalysis at Nanoparticle Surfaces written by Andrzej Wieckowski and published by CRC Press. This book was released on 2003-02-19 with total page 970 pages. Available in PDF, EPUB and Kindle. Book excerpt: Illustrating developments in electrochemical nanotechnology, heterogeneous catalysis, surface science and theoretical modelling, this reference describes the manipulation, characterization, control, and application of nanoparticles for enhanced catalytic activity and selectivity. It also offers experimental and synthetic strategies in nanoscale surface science. This standard-setting work clariefies several practical methods used to control the size, shape, crystal structure, and composition of nanoparticles; simulate metal-support interactions; predict nanoparticle behavior; enhance catalytic rates in gas phases; and examine catalytic functions on wet and dry surfaces.

Book Nanocrystals

    Book Details:
  • Author : Sudheer Neralla
  • Publisher : BoD – Books on Demand
  • Release : 2012-08-29
  • ISBN : 9535107143
  • Pages : 214 pages

Download or read book Nanocrystals written by Sudheer Neralla and published by BoD – Books on Demand. This book was released on 2012-08-29 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanocrystals research has been an area of significant interest lately, due to the wide variety of potential applications in semiconductor, optical and biomedical fields. This book consists of a collection of research work on nanocrystals processing and characterization of their structural, optical, electronic, magnetic and mechanical properties. Various methods for nanocrystals synthesis are discussed in the book. Size-dependent properties such as quantum confinement, superparamagnetism have been observed in semiconductor and magnetic nanoparticles. Nanocrystals incorporated into different material systems have proven to possess improved properties. A review of the exciting outcomes nanoparticles study has provided indicates further accomplishments in the near future.

Book Atomic Layer Deposition for Semiconductors

Download or read book Atomic Layer Deposition for Semiconductors written by Cheol Seong Hwang and published by Springer Science & Business Media. This book was released on 2013-10-18 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offering thorough coverage of atomic layer deposition (ALD), this book moves from basic chemistry of ALD and modeling of processes to examine ALD in memory, logic devices and machines. Reviews history, operating principles and ALD processes for each device.

Book Quantum Dot Molecules

Download or read book Quantum Dot Molecules written by Jiang Wu and published by Springer Science & Business Media. This book was released on 2013-10-28 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: A quantum dot molecule (QDM) is composed of two or more closely spaced quantum dots or “artificial atoms.” In recent years, QDMs have received much attention as an emerging new artificial quantum system. The interesting and unique coupling and energy transfer processes between the “artificial atoms” could substantially extend the range of possible applications of quantum nanostructures. This book reviews recent advances in the exciting and rapidly growing field of QDMs via contributions from some of the most prominent researchers in this scientific community. The book explores many interesting topics such as the epitaxial growth of QDMs, spectroscopic characterization, and QDM transistors, and bridges between the fundamental physics of novel materials and device applications for future information technology. Both theoretical and experimental approaches are considered. Quantum Dot Molecules can be recommended for electrical engineering and materials science department courses on the science and design of advanced and future electronic and optoelectronic devices.