Download or read book Asymptotic Analysis of Frontal Polymerization in a Medium with Periodic Monomer Distribution written by James T. Joyner and published by . This book was released on 2006 with total page 97 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Frontal polymerization (FP) is a process in which a monomer-initiator mixture is converted into polymer through a self-sustaining reaction front. We study FP in a two-dimensional rectangular domain where the front propagates parallel to the axis of periodic, small reagent variations. The problems setup is motivated by the experimental use of polymerization to produce gradient materials. Further, it allows us to investigate the fundamental question of validity of Snell's law for reaction waves in a non-uniform medium. First we present a derivation of the one-step kinetics model. Then, we seek an asymptotic, steady-state traveling-wave solution using the assumption of high activation energy. As a part of our analysis, we show that the Snell's law does not hold for the ranges of parameters for which our asymptotic analysis is valid. We propose a modification to our asymptotic procedure that may reveal applicability of Snell's law in FP."--abstract.
Download or read book Mathematical Analysis of Two Monomer Systems of Frontal Polymerization written by Michael F. Perry and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Frontal polymerization is a technique for converting monomer into polymer via a self-propagating reaction wave. Polymers can be manufactured by using one or more monomers; however, polymers formed with two or more monomers are advantageous because the polymer can assume specific important qualities. In this thesis, mathematical models for free-radical binary frontal polymerization and free-radical frontal copolymerization, methods in which polymers are formed using two different monomers, are developed. Through simplifying assumptions, the equations are solved both analytically and numerically, and important characteristics of the process, such as the propagation speed of the wave, the final temperature in the reaction front, and the final monomer concentrations, are studied. The analytic solution is compared to the numerical solution and to experimental results, whenever possible, to demonstrate agreement between the results. Parameters of the reaction are examined to determine which ones most influence the aforementioned characteristics. Stability of the polymerization front is also investigated.
Download or read book Rheological Fundamentals of Polymer Processing written by J.A. Covas and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: Experts in rheology and polymer processing present up-to-date, fundamental and applied information on the rheological properties of polymers, in particular those relevant to processing, contributing to the physical understanding and the mathematical modelling of polymer processing sequences. Basic concepts of non-Newtonian fluid mechanics, micro-rheological modelling and constitutive modelling are reviewed, and rheological measurements are described. Topics with practical relevance are debated, such as linear viscoelasticity, converging and diverging flows, and the rheology of multiphase systems. Approximation methods are discussed for the computer modelling of polymer melt flow. Subsequently, polymer processing technologies are studied from both simulation and engineering perspectives. Mixing, crystallization and reactive processing aspects are also included. Audience: An integrated and complete view of polymer processing and rheology, important to institutions and individuals engaged in the characterisation, testing, compounding, modification and processing of polymeric materials. Can also support academic polymer processing engineering programs.
Download or read book Polymer Colloids written by Rodney Priestley and published by Royal Society of Chemistry. This book was released on 2019-12-02 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: Academic and industrial research around polymer-based colloids is huge, driven both by the development of mature technologies, e.g. latexes for coatings, as well as the advancement of new materials and applications, such as building blocks for 2D/3D structures and medicine. Edited by two world-renowned leaders in polymer science and engineering, this is a fundamental text for the field. Based on a specialised course by the editors, this book provides the reader with an invaluable single source of reference. The first section describes formation, explaining basic properties of emulsions and dispersion polymerization, microfluidic approaches to produce polymer-based colloids and formation via directed self-assembly. The next section details characterisation methodologies from microscopy and small angle scattering, to surface science and simulations. The final chapters close with applications, including Pickering emulsions and molecular engineering for materials development. A comprehensive guide to polymer colloids, with contributions by leaders in their respective areas, this book is a must-have for researchers and practitioners working across polymers, soft matter and chemical and molecular engineering.
Download or read book Electrospun Nanofibers written by Mehdi Afshari and published by Woodhead Publishing. This book was released on 2016-09-13 with total page 650 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrospun Nanofibers covers advances in the electrospinning process including characterization, testing and modeling of electrospun nanofibers, and electrospinning for particular fiber types and applications. Electrospun Nanofibers offers systematic and comprehensive coverage for academic researchers, industry professionals, and postgraduate students working in the field of fiber science. Electrospinning is the most commercially successful process for the production of nanofibers and rising demand is driving research and development in this field. Rapid progress is being made both in terms of the electrospinning process and in the production of nanofibers with superior chemical and physical properties. Electrospinning is becoming more efficient and more specialized in order to produce particular fiber types such as bicomponent and composite fibers, patterned and 3D nanofibers, carbon nanofibers and nanotubes, and nanofibers derived from chitosan. Provides systematic and comprehensive coverage of the manufacture, properties, and applications of nanofibers Covers recent developments in nanofibers materials including electrospinning of bicomponent, chitosan, carbon, and conductive fibers Brings together expertise from academia and industry to provide comprehensive, up-to-date information on nanofiber research and development Offers systematic and comprehensive coverage for academic researchers, industry professionals, and postgraduate students working in the field of fiber science
Download or read book Frontiers in the Science and Technology of Polymer Recycling written by Güneri Akovali and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 477 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymers, main components of plastics and rubbers, are being discarded in increasing quantities. But this waste can also be considered as `plastic gold'. Public concern, coupled with the inherent value of the material, means that recycling is imperative. The present book presents a survey of current knowledge in the form of case studies, including current legal and educational issues. Topics covered also include regulation and practice in NATO countries, the economics of recycling, the reprocessing of single polymers and mixtures, and future prospects and strategies. Audience: Vital reading for all polymer scientists, technicians and engineers.
Download or read book Percolation written by Geoffrey R. Grimmett and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 459 pages. Available in PDF, EPUB and Kindle. Book excerpt: Percolation theory is the study of an idealized random medium in two or more dimensions. The emphasis of this book is upon core mathematical material and the presentation of the shortest and most accessible proofs. Much new material appears in this second edition including dynamic and static renormalization, strict inequalities between critical points, a sketch of the lace expansion, and several essays on related fields and applications.
Download or read book Centrifugal Materials Processing written by Liya L. Regel and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is not good to have zeal without knowledge • . . . Book of Proverbs This volume constitutes the proceedings of the Third International Workshop on Materials Processing at High Gravity. It offers the latest results in a new field with immense potential for commercialization, making this book a vital resource for research and development professionals in industry, academia and government. We have titled the proceedings Centrifugal Materials Processing to emphasize that centrifugation causes more than an increase in acceleration. It also introduces the Coriolis force and a gradient of acceleration, both of which have been discovered to play important roles in materials processing. The workshop was held June 2-8, 1996 on the campus of Clarkson University in Potsdam, New York, under the sponsorship of Corning Corporation and the International Center for Gravity Materials Science and Applications. The meeting was very productive and exciting, with energetic discussions of the latest discoveries in centrifugal materials processing, continuing the atmosphere of the first workshop held in 1991 at Dubna (Russia) and the second workshop held in 1993 in Potsdam, New York. Results and research plans were presented for a wide variety of centrifugal materials processing, including directional solidification of semiconductors, crystallization of high Tc superconductors, growth of diamond thin films, welding, alloy casting, solution behavior and growth, protein crystal growth, polymerization, and flow behavior. Also described were several centrifuge facilities that have been constructed for research, with costs beginning at below $1000.
Download or read book Polymer Gels written by D. DeRossi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains a series of papers originally presented at the Symposium on Polymer Gels organized and sponsored by the Research Group on Polymer Gels,The Society of Polymer Science of Japan and co-sponsored by the Science and Technology Agency (ST A) and MIT!, Japan. The Symposium took place at Tsukuba Science City on 18th and 19th September, 1989. Recognized experts in their fields were invited to speak and there was a strong attendance from government, academic and industrial research centers. The purpose of the Symposium was to review the state of the art and to present and discuss recent progress in the understanding of the behavioral properties of polymer gels and their application to biomedical, environmental and robotic fields. Most of the papers and related discussions concentrated on the swelling behavior of hydrogels and chemomechanical systems, both artificial and naturally occurring, in which external stimuli of a physical or chemical nature control energy transformation or signal transduction. The recent great interest in chemomechanical systems based on polymer gels has stimulated considerable effort towards the development of new sensors and actuators, controllable membrane separation processes, and delivery systems in which the functions of sensing, processing and actuation are all built into the polymeric network device. Artificial chemomechanical systems, through the use of environmentally sensitive polymer gels, are emerging as interesting materials for mimicking basic processes previously only confined to the biological world, and commercially viable applications are also foreseen in the not-too-distant future.
Download or read book An Introduction to Nonlinear Chemical Dynamics written by Irving R. Epstein and published by Oxford University Press. This book was released on 1998-10-22 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: Just a few decades ago, chemical oscillations were thought to be exotic reactions of only theoretical interest. Now known to govern an array of physical and biological processes, including the regulation of the heart, these oscillations are being studied by a diverse group across the sciences. This book is the first introduction to nonlinear chemical dynamics written specifically for chemists. It covers oscillating reactions, chaos, and chemical pattern formation, and includes numerous practical suggestions on reactor design, data analysis, and computer simulations. Assuming only an undergraduate knowledge of chemistry, the book is an ideal starting point for research in the field. The book begins with a brief history of nonlinear chemical dynamics and a review of the basic mathematics and chemistry. The authors then provide an extensive overview of nonlinear dynamics, starting with the flow reactor and moving on to a detailed discussion of chemical oscillators. Throughout the authors emphasize the chemical mechanistic basis for self-organization. The overview is followed by a series of chapters on more advanced topics, including complex oscillations, biological systems, polymers, interactions between fields and waves, and Turing patterns. Underscoring the hands-on nature of the material, the book concludes with a series of classroom-tested demonstrations and experiments appropriate for an undergraduate laboratory.
Download or read book Understanding Aerospace Chemical Propulsion written by H. S. Mukunda and published by . This book was released on 2017-02-28 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explores aeronautical and space chemical propulsion. The book provides an understanding of propulsion systems through illustrative description of the systems; analysis of modeled systems; examination of the performance of real systems in this light; and a comparative assessment of aeronautical and space propulsion system elements.
Download or read book The Origins of Life written by D. W. Deamer and published by Cold Spring Harbor Perspective. This book was released on 2010 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Life arose on Earth more than three billion years ago. How the first self-replicating systems emerged from prebiotic chemistry and evolved into primitive cell-like entities is an area of intense research, spanning molecular and cellular biology, organic chemistry, cosmology, geology, and atmospheric science. Written and edited by experts in the field, this collection from Cold Spring Harbor Perspectives in Biology provides a comprehensive account of the environment of the early Earth and the mechanisms by which the organic molecules present may have self-assembled to form replicating material such as RNA and other polymers. The contributors examine the energetic requirements for this process and focus in particular on the essential role of semi-permeable compartments in containment of primitive genetic systems. Also covered in the book are new synthetic approaches for fabricating cellular systems, the potentially extraterrestrial origin of life's building blocks, and the possibility that life once existed on Mars. Comprising five sections Setting the Stage, Components of First Life, Primitive Systems, First Polymers, and Transition to a Microbial World it is a vital reference for all scientists interested in the origin of life on Earth and the likelihood that it has arisen on other planets
Download or read book Recent Trends in Fuel Cell Science and Technology written by S. Basu and published by Springer Science & Business Media. This book was released on 2007-10-20 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers all the proposed fuel cell systems including PEMFC, SOFC, PAFC, MCFC, regenerative fuel cells, direct alcohol fuel cells, and small fuel cells to replace batteries.
Download or read book Membrane Processes in Separation and Purification written by J.G. Crespo and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chapters of this book are based upon lectures presented at the NATO Advanced Study Institute on Membrane Processes in Separation and Purification (March 21 - April 2, 1993, Curia, Portugal), organized as a successor and update to a similar Institute that took place 10 years ago (p.M.Bungay, H.K. Lonsdale, M.N. de Pinho (Eds.): Synthetic Membranes: Science, Engineering and Applications, NATO ASI Series, Reidel, Dordrecht, 1986). The decade between the two NATO Institutes witnesses the transition from individually researched membrane processes to an applied and established membrane separation technology, as is reflected by the contents of the corresponding proceeding volumes. By and large, the first volume presents itself as a textbook on membrane processes, still valid, while the present volume focuses on areas of separation need as amenable to membrane processing: Biotechnology and Environmental Technology. Accordingly, the contributions to this volume are grouped into "Membranes in Biotechnology" (11 papers), "Membranes in Environmental Technology" (6 papers), and "New Concepts" (4 papers). This is followed by one contribution each on "Energy Requirements" and "Education", i.e., membrane processes within an academic curriculum. The book thus amounts to a state of the art of applied membrane processing and may well augment the more fundamental approach of its predecessor.
Download or read book Models of Biological Pattern Formation written by Hans Meinhardt and published by . This book was released on 1982 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Minimal Selfhood and the Origins of Consciousness written by Rupert Glasgow and published by BoD – Books on Demand. This book was released on 2018-07-10 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: In Minimal Selfhood and the Origins of Consciousness, R.D.V. Glasgow seeks to ground the logical roots of consciousness in what he has previously called the 'minimal self'. The idea is that elementary forms of consciousness are logically dependent not, as is commonly assumed, on ownership of an anatomical brain or nervous system, but on the intrinsic reflexivity that defines minimal selfhood. The aim of the book is to trace the logical pathway by which minimal selfhood gives rise to the possible appearance of consciousness. It is argued that in specific circumstances it thus makes sense to ascribe elementary consciousness to certain predatory single-celled organisms such as amoebae and dinoflagellates as well as to some of the simpler animals. Such an argument involves establishing exactly what those specific circumstances are and determining how elementary consciousness differs in nature and scope from its more complex manifestations.
Download or read book Application of Super Absorbent Polymers SAP in Concrete Construction written by Viktor Mechtcherine and published by Springer Science & Business Media. This book was released on 2012-01-03 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the state-of-the-art report prepared by the RILEM TC “Application of Super Absorbent Polymers (SAP) in concrete construction”. It gives a comprehensive overview of the properties of SAP, specific water absorption and desorption behaviour of SAP in fresh and hardening concrete, effects of the SAP addition on rheological properties of fresh concrete, changes of cement paste microstructure and mechanical properties of concrete. Furthermore, the key advantages of using SAP are described in detail: the ability of this material to act as an internal curing agent to mitigate autogenous shrinkage of high-performance concrete, the possibility to use SAP as an alternative to air-entrainment agents in order to increase the frost resistance of concrete, and finally, the benefit of steering the rheology of fresh cement-based materials. The final chapter describes the first existing and numerous prospective applications for this new concrete additive.
