Download or read book Assessment of Water Treatment Technologies for Per and Polyfluoroalkyl Substances PFAS in Multiple Matrices written by Vanessa Maldonado and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The ubiquitous presence of per-and polyfluoroalkyl substances (PFAS) in the environment resulted in extensive water contamination that poses a significant risk to human health and biota. Continuous research efforts aim to develop efficient treatment technologies to treat PFAS in water, break the PFAS accumulation cycle in the environment, and improve the efficiency of emerging technologies. In this thesis work, selected treatment technologies including electrochemical oxidation and dielectrophoresis-enhanced adsorption were used to assess and advance the state-of-the-art for PFAS remediation in multiple matrices, not previously addressed.A boron-doped diamond (BDD) flow-through cell was used to evaluate the electrochemical oxidation of perfluoroalkyl acids (PFAAs) in landfill leachates. Multiple leachates with a concentration of individual PFAAs in the range of 102 -104 ng/L were treated. The effect of current density and variability of the composition of leachates was investigated. Non-detect levels and >90% removal of perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) were reached for all leachates tested after electrochemical treatment. Although high removal efficiencies for long-chain PFAAs were obtained, high concentrations of short-chain PFAAs were generated and associated with the transformation of perfluoroalkyl acid (PFAA) precursor compounds.In the second part of this thesis research, the oxidative transformation of PFAA-precursors typically present in leachates was addressed for the first time. Target and suspect PFAS were identified in a landfill leachate and their concentrations during electrochemical treatment were quantified over time. Liquid chromatography quadrupole time-of-flight mass spectrometry (LC-QToF) measurements of the leachate identified 53 PFAS compounds and 19 PFAS classes. Multiple PFAS were reported for the first time in landfill leachates. The evaluation of the intermediate and final products generated during the electrochemical treatment showed evidence of known electrochemical degradation pathways.Coupling destructive technologies (e.g., electrochemical oxidation) with concentration technologies (e.g., ion exchange (IX), adsorption) in a treatment train approach could reduce the treatment cost of destructive technologies and increase their feasibility. Therefore, in the next part of this work, electrochemical oxidation of PFAAs from the concentrated waste of IX still bottoms was assessed at laboratory and semi-pilot scales. The concentrated waste resulted from the treatment of PFAAs-impacted groundwater with IX resins. Multiple current densities were evaluated at laboratory scale and the optimum current density was used at the semi-pilot scale. The results at the laboratory and semi-pilot scales allowed for >99% and >94% removal of total PFAAs with 50 mA/cm2, respectively. Defluorination values, energy consumption, and implications were discussed.The third matrix addressed for PFAS remediation was drinking water. Dielectrophoresis-enhanced adsorption was used for the removal of low concentrations of PFOA. This study introduced a coaxial-electrode cell (CEC) that allowed for the generation of a non-uniform electric field to enhance the adsorption of PFOA. Experiments were performed in batch and continuous-flow modes. The dielectrophoretic-enhanced adsorption in batch mode resulted in a 4, 7, and 8-fold increase in the removal of PFOA with 5, 25, and 50 V when compared to adsorption only. The performance of the CEC in continuous-flow mode allowed for an increase of up to 2.4-fold in the PFOA removal with 25 V. The results highlighted the benefits of using a dielectrophoresis-enhanced adsorption process for the removal of PFOA from water. Overall, results from this thesis contribute to the understanding of the electrochemical degradation of PFAS in multiple matrices and introduce an alternative process to enhance the widely used adsorption technology for PFAS removal. Treatment implications of each matrix are discussed and provide a clear baseline for future research, development, and scale-up of treatment technologies for PFAS remediation.

Download or read book Current Developments in Biotechnology and Bioengineering written by Sridhar Pilli and published by Elsevier. This book was released on 2022-08-27 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sustainable Treatment Technologies for Pre- and Poly-flourakyl Substances provides comprehensive details about per- and poly-fluroalkyls substances (PFASs), which are highly toxic and bio-accumulative substances that do not biodegrade easily or cannot be neutralized under normal environmental conditions. It discusses their occurrence in water, wastewater, and aquatic environment, their bioaccumulation in plants, environmental impacts and various remedial technologies for their treatment and management. All the chapters provide state-of-art information about PFASs, describing their identification methods, characterization and present critical analysis of the treatment methods such as physical, chemical, biological, hybrid and advanced systems. This book is a ready reference for the environmental engineers, municipal engineers, environmental practitioners, policy makers, and planners; it is also a practical guide for industrial engineers, government bodies and ecologists as well as for researchers. Describes occurrence of PFASs in aquatic environment and on plant Provides details on identification methods and characterization of PFAS Describes physical, chemical, biological, hybrid and advanced system treatments for PFASs Covers regulatory aspects on PFASs First dedicated book on PFASs

Download or read book Forever Chemicals written by David M. Kempisty and published by CRC Press. This book was released on 2021-07-28 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: Forever Chemicals: Environmental, Economic, and Social Equity Concerns with PFAS in the Environment provides the reader with an understanding of the complex and interwoven issues associated with per- and polyfluorinated substances (PFAS) in our environment. The chapters provide in-depth perspective into various issues, including health, regulation, detection, clean-up strategies and technologies, and more. Taken together or as the reader’s interests lead them, the variety of topics covered in the book present a balanced perspective on this complex topic. It will address the current state of PFAS and where indicators are pointing for future developments. The book is also a deeper investigation of the regulatory challenges, analytical hurdles, and toxicological progress to date for the suite of PFAS chemicals. Features Explains the trends that will affect future policy and regulatory decisions Looks holistically at 4000+ PFAS chemicals Includes PFAS risk assessments at contaminated sites and biomonitoring insights Provides in-depth discussions on remediation technologies Illustrates quality and diversified content Provides a balanced perspective on this complex topic

Download or read book Perfluorinated Chemicals PFCs written by Nicholas P. Cheremisinoff and published by John Wiley & Sons. This book was released on 2016-11-29 with total page 271 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new volume provides a timely study on the environmental challenges from a specific class of perfluorinated chemical compounds (PFCs) that are now being recognized as a worldwide health threat. Recent studies report that levels of classes of PFCs known as polyfluoroalkyl and perfluoroalkyl (PFASs) exceed federally recommended safety levels in public drinking-water supplies for 6 million people in the United States and that as many as 100 million people could be at risk from exposure to these chemicals. These chemicals occur globally in wildlife and humans. Both PFCAs and PFSAs have been produced for more than 50 years, but have only become of interest to regulators and environmentalists since the late 1990s. Recent advances in analytical methodology has enabled widespread detection in the environment and humans at trace levels. These toxic chemicals have been found in outdoor and indoor air, surface and drinking water, house dust, animal tissue, human blood serum, and human breast milk. Of great concern to communities is the presence of these compounds in a number of drinking water supplies in the U.S. and other countries. This new volume provides a timely explanation of the chemicals, provides a detailed review of the regulations both in the US and European Community, explains the health risk literature, and then explores in great detail available treatment technologies. The volume is a must for public water supply facilities, industrial operations that have historically used these chemicals and face legacy pollution issues, policy makers and the general public.

Download or read book The cost of inaction written by Gretta Goldenman and published by Nordic Council of Ministers. This book was released on 2019-03-17 with total page 194 pages. Available in PDF, EPUB and Kindle. Book excerpt: PFAS (per and polyfluoroalkylsubstances) are known to be extremely difficult to degrade in the environment and to be bioaccumulative and toxic. Exposure to PFAS is suspected to increase the risk of adverse health effects, such as impacts on the thyroid gland, the liver, fat metabolism and the immune system. This study estimates the socioeconomic costs that may result from impacts on human health and the environment from the use of PFAS. Better awareness of the costs and problems associated with PFAS exposure will assist decision-makers and the general public to make more efficient and timely risk management decisions. Findings indicate that the costs are substantial, with annual health-related costs estimated to 2.8 – 4.6 billion EUR for the Nordic countries and 52 – 84 billion EUR for all EEA countries. Overall non-health costs are estimated at 46 million – 11 billion EUR for the Nordic countries.Upon request the excel spreadsheets used for the monetarisation and valuation in this report can also be provided along with a guidance on how to use the estimation of costs for value transfer. Please contact any of the consultants or members of the steering group from the Swedish Chemicals Agency or the Danish Environmental Protection Agency if you are interested in receiving these excel spreadsheets.

Download or read book Reverse Osmosis and Nanofiltration written by American Water Works Association and published by Amer Water Works Assn. This book was released on 1998 with total page 173 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explains the processes of membrane technologies applications, used in the treatment of water sources and by medical professionals for kidney dialysis, and is a helpful research tool for engineers, scientists, administrators, and educators seeking an introduction to these processes. Covers history and theory, design and equipment, regulations, and more.

Download or read book Polyfluorinated Chemicals and Transformation Products written by Thomas P. Knepper and published by Springer Science & Business Media. This book was released on 2011-09-21 with total page 183 pages. Available in PDF, EPUB and Kindle. Book excerpt: Due to their unparalleled effectiveness and efficiency, polyfluorinated chemicals (PFC) have become essential in numerous technical applications. However, many PFCs brought to market show limited biodegradability, and their environmental persistence combined with toxic and bioaccumulative potential have become a matter of concern in some instances. This volume highlights the synthesis of PFCs, focusing on substances with improved application and environmental properties, which are a challenge for synthetic chemists. Further, modern mass spectrometric techniques for the detection and identification of biotransformation products of PFCs are described. The sorption and leaching behavior of PFC in soil is also addressed in order to predict their fate in the environment. Several contributions discuss the monitoring of PFCs in European surface, ground and drinking waters, treatment options for PFC removal from drinking water, occurrence in food, and the human biomonitoring of PFCs.

Download or read book Oxidative Transformation of Perfluoroalkyl and Polyfluoroalkyl Substances PFAS written by Eniola Oye-Bamgbose and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: "Perfluoroalkyl and Polyfluoroalkyl substances (PFAS) are anthropogenic chemicals with unique properties and wide applications in industrial and consumer products. However, studies have shown that the once highly valued PFAS are persistent pollutants, ubiquitous in the environment, and are developmental and reproductive toxins. To meet the stringent drinking water guidelines for PFAS, technologies that can destroy PFAS are urgently sought for. As multiple carbon-fluorine bonds render many conventional destruction processes ineffective, advanced oxidation-based treatment methods are some of the very promising methods for the destruction of PFAS in contaminated environmental matrices. Nevertheless, if effective oxidation-based treatment methods are to be developed, it is essential to know all the transformations PFAS can undergo during oxidation. This thesis focused on PFAS oxidation with and without the addition of external oxidants divided into two studies. The first study focused on the non-additive oxidation and degradation of perfluorooctanoic acid (PFOA) using nonthermal plasma, and the second on the additive oxidation of unknown PFAS using persulfate-based total oxidizable precursor assay.The first study was centered on plasma-based water treatment of perfluorooctanoic acid, which relies on only an electrical discharge to convert water and gas molecules to a mixture of highly reactive oxidative species. The objective was to achieve a complete mass balance of PFOA after treatment by performing a total fluorine mass balance analysis. A 16 [mu]M PFOA solution was treated with a nonthermal plasma generated in nanosecond long pulses. After 30 min of treatment, a 42% reduction in PFOA concentration was achieved. The degradation of PFOA also led to the generation of shorter chain perfluorocarboxylic acids. Specifically, 0.08 [mu]M of perfluorobutanoic acid, 0.2 [mu]M of perfluoropentanoic acid, 0.5 [mu]M of perfluorohexanoic acid, 1.5 [mu]M of perfluoroheptanoic acid and 9.1 [mu]M of free fluoride ions were produced. Total fluorine mass balance analysis using combustion ion chromatography suggested that in addition to the measured degradation products, other unmeasured compounds possibly such as gaseous fluorinated products, trifluoroacetic acid, and perfluoropropionic acid were also produced. In the second study, conventional uses of persulfate oxidation process, which degrades selected PFAS under very restrictive conditions, was repurposed for the measurement of many unidentifiable PFAS, through the total oxidizable precursor assay. The study was aimed at investigating how the presence of co-contaminants affects PFAA precursor oxidation and finding solutions to improve precursor oxidation during the assay. Seventy aqueous film-forming foam impacted groundwater samples received from Environment and Climate Change Canada were subjected to the assay. Initial analysis of the groundwater samples showed a diverse range of PFAS levels with the maximum sum of concentrations measured to be 2.33 mg/L, and several PFAA precursors were detected. The results after oxidation showed a direct correlation between matrix complexities (i.e. the presence of co-contaminants) and the extent of PFAA precursor oxidation. There was incomplete oxidation of PFAA precursors in samples with a high concentration of co-contaminants. The implementation of a previously developed clean-up procedure improved precursor oxidation during TOP assay by an average of +52%.To further investigate how the presence of co-contaminants affect PFAA precursor oxidation during the TOP assay, mixtures of 6:2 FTSA or 6:2 FTAB and natural organic matter were prepared respectively. Only at low and intermediate COD levels of no more than 230 mgO2/L, 100% loss of the precursors can be largely accounted for by the generation of C3-C7 PFCAs. The results showed that the presence of co-contaminants in TOP assay not only affects the oxidation loss of precursors but also the type of products generated"--

Download or read book Stantec s Water Treatment written by John C. Crittenden and published by John Wiley & Sons. This book was released on 2022-11-08 with total page 1956 pages. Available in PDF, EPUB and Kindle. Book excerpt: The updated third edition of the definitive guide to water treatment engineering, now with all-new online content Stantec's Water Treatment: Principles and Design provides comprehensive coverage of the principles, theory, and practice of water treatment engineering. Written by world-renowned experts in the field of public water supply, this authoritative volume covers all key aspects of water treatment engineering, including plant design, water chemistry and microbiology, water filtration and disinfection, residuals management, internal corrosion of water conduits, regulatory requirements, and more. The updated third edition of this industry-standard reference includes an entirely new chapter on potable reuse, the recycling of treated wastewater into the water supply using engineered advanced treatment technologies. QR codes embedded throughout the book connect the reader to online resources, including case studies and high-quality photographs and videos of real-world water treatment facilities. This edition provides instructors with access to additional resources via a companion website. Contains in-depth chapters on processes such as coagulation and flocculation, sedimentation, ion exchange, adsorption, and gas transfer Details membrane filtration technologies, advanced oxidation, and potable reuse Addresses ongoing environmental concerns, pharmacological agents in the water supply, and treatment strategies Describes reverse osmosis applications for brackish groundwater, wastewater, and other water sources Includes high-quality images and illustrations, useful appendices, tables of chemical properties and design data, and more than 450 exercises with worked solutions Stantec's Water Treatment: Principles and Design, Updated Third Edition remains an indispensable resource for engineers designing or operating water treatment plants, and is an essential textbook for students of civil, environmental, and water resources engineering.

Download or read book Perfluoroalkyl Substances in the Environment written by David M. Kempisty and published by CRC Press. This book was released on 2018-08-06 with total page 495 pages. Available in PDF, EPUB and Kindle. Book excerpt: Per- and polyfluorinated alkyl substances (PFAS), often referred to as per- (and poly) fluorinated compounds (PFCs), have been used for years in many everyday3⁄4 and some lifesaving3⁄4 products. However, their use has been linked to adverse health effects in humans, a problem compounded by their persistence in the environment. This book discusses the various challenges of PFAS in our environment today, including their historical use as well as their chemical and toxicological properties. It also presents robust discussion of analytical challenges and special considerations in sampling. The work goes on to give practical recommendations for dealing with these compounds in today's dynamic regulatory landscape and includes several chapters on various remediation techniques. Key Features: Comprehensive overview of per- and polyfluorinated alkyl substances (PFAS) historical use and chemical/physical properties which help us understand their persistence, transport, and transformation pathways in the environment In-depth analysis of PFAS toxicology Detailed descriptions of conventional and state-of-the-art remediation technologies Practical recommendations for dealing with PFAS in a dynamic regulatory landscape Robust discussion of important sampling and analytical considerations Perfluoroalkyl Substances in the Environment: Theory, Practice, and Innovation explores the challenges across the topical areas of regulation and management, toxicology, environmental remediation, and analytical sampling and analysis.Readers will find this text helpful in understanding complexities associated with PFAS and informing management strategies to effectively protect this and future generations.

Download or read book Bioaccumulation Fate and Treatment of Per and Polyfluoroalkyl Substances PFAS written by Asa James Lewis and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Per- and polyfluoroalkyl substances (PFAS) are a large and diverse class of man-made chemicals that are persistent and difficult to degrade in the environment. PFAS are characterized by the presence of carbon-fluorine bonds, the strongest bond in organic chemistry, which leads to great thermal and chemical stability. Often these properties provide industrial and consumer products with chemical and temperature resistance, surfactant behavior, and stain or water resistance. Currently, the problem of PFAS in the environment starts with their synthetic generation, use in products, and subsequent release to the environment where they can bioaccumulate and persist. PFAS have globally impacted aquatic ecosystems through major pathways such as direct release into the environment (e.g., fire-fighting trainings with aqueous film forming foams (AFFF)), inadequately treated industrial effluents, land-applied biosolids, and atmospheric deposition. Once released to the environment, specifically in water, many PFAS compounds tend to accumulate in ecosystems through bioaccumulation. In water, some PFAS are mobile, pose risks to all levels of an ecosystem, and are particularly difficult to remove or degrade. To address the release and accumulation in the environment, major strides must be made in terms of regulations, development of analytical techniques, mechanistic pathways understanding related to fate and transport, and advancement of treatment technologies to address the pollution whether it is large scale or site-specific remediation efforts. The goal of this dissertation is to provide further insight into bioaccumulation of PFAS in aquatic matrices, fate and transport in land-applied biosolids, and to develop a plasma treatment technology to destroy PFAS. Regarding bioaccumulation in aquatic matrices, geochemical factors have been demonstrated to impact PFAS partitioning in aquatic ecosystems and to impact bioaccumulation, but little is known related to the mechanistic understanding of the effects of elevated divalent cation concentrations of magnesium (Mg2+) and calcium (Ca2+) on macroinvertebrates. Therefore, as part of this dissertation, the impacts of Mg2+ and Ca2+ on PFAS bioaccumulation in three different macroinvertebrates species, Lumbriculus variegatus (L. variegatus), Elliptio complanata (E. complanata), and Physella acuta (P. acuta) were investigated, where it was demonstrated that the increased divalent cations concentrations impact the bioavailability of PFAS and the mechanisms responsible were discussed. L. variegatus had significantly higher PFAS bioaccumulation than P. acuta and E. complanata, likely due to higher levels of activity and interactions/ingestion of the contaminated sediment. "High Mg2+" (7.5 mM Mg2+) and "High Ca2+" (7.5 mM Ca2+) conditions generally had observable higher bioaccumulation factors (BAFs) than the "Reference Condition" (0.2 mM Ca2+ and 0.2 mM Mg2+) for PFAS with perfluorinated chain lengths greater than six carbons. Long-chain PFAS dominated the PFAS profiles of the macroinvertebrates for all classes of compounds studied, PFCA, PFSA, and FTS. These results indicate that the specific organism studied is most impactful regarding bioaccumulation, but divalent cation concentration has observable impacts between species depending on the environmental conditions. With respect to the release of PFAS from land-applied biosolids, the influence of microbial weathering on the partitioning of PFAS over a period of three months was investigated to see the impacts on fate and transport in biosolids. We found that the PFAS biosolids-water partitioning coefficients (Kd) were demonstrated to decrease, on average, 0.4 log over the course of the study. Additionally, the solid characteristics were characterized (lipids, proteins, and organic matter) and were observed to have sharp decreases over the first ten days, aligning with the most rapid changes in Kd. As a result, a multiple linear regression model was built to predict PFAS partitioning behavior in biosolids based on the biosolids characteristics and PFAS characteristics. Among the evaluated independent variables, statistical analyses demonstrated that the most significant solids characteristics that impacted PFAS partitioning were organic matter, proteins, lipids, and molecular weight of organics. A multiple linear regression model was built to predict PFAS partitioning behavior in biosolids based on solid characteristics of the biosolids and PFAS characteristics with a R2 value of 0.7391 when plotting predicted and measured log Kd. The findings from this work reveal that microbial weathering can play a significant role in the eventual fate and transport of PFAS and their precursors from biosolids. Since PFAS have been demonstrated herein to accumulate in aquatic matrices and rapidly partition from biosolids during biotic weathering processes, there is a need to effectively remove PFAS from water to decrease the environmental accumulation and transport. We report as part of this dissertation the development of a non-thermal plasma treatment system to degrade PFAS in liquid solutions. It was observed that this technology was able to rapidly degrade PFAS compounds but the degree of degradation and defluorination was highly depending on perfluorinated alkyl chain lengths, with those compounds with greater than 8 perfluorinated carbons achieving greater than 90% removal in one hour of treatment. The combination of the energy efficiency of this treatment being on the order of magnitude of other emerging destructive technologies and its effectiveness shows promise for the application of non-thermal plasmas for PFAS removal in water. The lowest EEo for PFOS was 23.2 kWh/m3/order and 213.4 kWh/m3/order for PFOA, similar with existing technologies (which range from 10 to 10,000 kWh/m3/order). These results indicate that non-thermal air plasma discharges are promising technologies for treatment of PFAS that should be further researched and developed.

Download or read book Fundamentals of Electrochemistry written by Vladimir S. Bagotsky and published by John Wiley & Sons. This book was released on 2005-12-02 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fundamentals of Electrochemistry provides the basic outline of most topics of theoretical and applied electrochemistry for students not yet familiar with this field, as well as an outline of recent and advanced developments in electrochemistry for people who are already dealing with electrochemical problems. The content of this edition is arranged so that all basic information is contained in the first part of the book, which is now rewritten and simplified in order to make it more accessible and used as a textbook for undergraduate students. More advanced topics, of interest for postgraduate levels, come in the subsequent parts. This updated second edition focuses on experimental techniques, including a comprehensive chapter on physical methods for the investigation of electrode surfaces. New chapters deal with recent trends in electrochemistry, including nano- and micro-electrochemistry, solid-state electrochemistry, and electrocatalysis. In addition, the authors take into account the worldwide renewal of interest for the problem of fuel cells and include chapters on batteries, fuel cells, and double layer capacitors.

Download or read book Drinking Water Contaminant Candidate List written by and published by . This book was released on 1998 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Membrane Separations Technology written by R.D. Noble and published by Elsevier. This book was released on 1995-01-17 with total page 737 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of membrane separation technology is presently in a state of rapid growth and innovation. Many different membrane separation processes have been developed during the past half century and new processes are constantly emerging from academic, industrial, and governmental laboratories. While new membrane separation processes are being conceived with remarkable frequency, existing processes are also being constantly improved in order to enhance their economic competitiveness. Significant improvements are currently being made in many aspects of membrane separation technology: in the development of new membrane materials with higher selectivity and/or permeability, in the fabrication methods for high-flux asymmetric or composite membranes, in membrane module construction and in process design. Membrane separation technology is presently being used in an impressive variety of applications and has generated businesses totalling over one billion U.S. dollars annually.The main objective of this book is to present the principles and applications of a variety of membrane separation processes from the unique perspectives of investigators who have made important contributions to their fields. Another objective is to provide the reader with an authoritative resource on various aspects of this rapidly growing technology. The text can be used by someone who wishes to learn about a general area of application as well as by the knowledgeable person seeking more detailed information.

Download or read book Toxicological Effects of Perfluoroalkyl and Polyfluoroalkyl Substances written by Jamie C. DeWitt and published by Humana Press. This book was released on 2015-04-14 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book serves as a timely and comprehensive overview of the latest science for perfluoroalkyl and polyfluoroalkyl substances (PFASs), covering the development of methods for assessing PFASs in biological fluids and tissues as well as the current knowledge regarding their toxicity to vertebrate organisms. This book includes chapters on human and wildlife exposure/body burdens, reviews of metabolism and toxicological effects by organ system/developmental stage and aspects of PFAS toxicity that are driving PFAS research and regulatory oversight. Toxicological Effects of Perfluoroalkyl and Polyfluoroalkyl Substances provide critical assessments of the most controversial topics surrounding toxicological evaluation of PFASs to give readers an expert perspective on the issues. Emphasis is placed on the integration of modes and mechanisms of action with functional endpoints that are relevant to human and wildlife health. This book will be a useful resource for toxicologists, environmental chemists, risk assessors and researchers with an interest in the class of compounds known as perfluoroalkyl and polyfluoroalkyl substances.

Download or read book PFASs in the Nordic environment written by Anna Kärrman and published by Nordic Council of Ministers. This book was released on 2019-03-15 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report describes a screening study of in all ninety-nine conventional and emerging per- and polyfluoroalkyl substances (PFASs) in the Nordic environment. In addition, extractable organic fluorine (EOF) was analysed. The latter can provide the amount, but not identity, of organofluorine in the samples, which in turn can be used to assess the mass balance between known and unknown PFASs. The study was initiated by the Nordic Screening Group and funded by these and the Nordic Council of Ministers through the Chemicals Group.A total of 102 samples were analyzed in this study, including bird eggs, fish, marine mammals, terrestrial mammals, surface water, WWTP effluents and sludge, and air. Samples were collected by institutes from the participating countries and self-governing areas; Denmark, Faroe Islands, Finland, Greenland, Iceland, Norway, and Sweden.

Download or read book Guide to Fluorine NMR for Organic Chemists written by William R. Dolbier, Jr. and published by John Wiley & Sons. This book was released on 2016-08-24 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt: Following its well-received predecessor, this book offers an essential guide to chemists for understanding fluorine in spectroscopy. With over 1000 compounds and 100 spectra, the second edition adds new data – featuring fluorine effects on nitrogen NMR, chemical shifts, and coupling constants. • Explains how to successfully incorporate fluorine into target molecules and utilize fluorine substituents to structurally characterize organic compounds • Includes new data on nitrogen NMR, focusing on N-15, to portray the influence of fluorine upon nitrogen NMR chemical shifts and coupling constants • Expands on each chapter from the first edition with additional data and updated discussion from recent findings • "The flawless ordering of material covered in this stand-alone volume is such that information can be found very easily." – Angewandte Chemie review of the first edition, 2010