Download or read book Application of In situ Spectroscopic Techniques to the Study of Electrochemical Processes written by Marnita Elizabeth Sandifer and published by . This book was released on 1995 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book In situ Spectroscopic Studies of Adsorption at the Electrode and Electrocatalysis written by Shi-Gang Sun and published by Elsevier. This book was released on 2011-08-11 with total page 559 pages. Available in PDF, EPUB and Kindle. Book excerpt: In-Situ Spectroscopic Studies of Adsorption at the Electrode and Electrocatalysis is a new reference on in-situ spectroscopic techniques/applications, fundamentals of electrocatalysis at molecule level, and progresses within electrochemical surface science. Presenting both essential background knowledge at graduate level and original research within the fields of spectroscopy, electrochemistry, and surface science. Featuring 15 chapters by prominent worldwide scholars, based on their recent progress in different aspects of in-situ spectroscopy studies, this book will appeal to a wide audience of scientists. In summary this book is highly suitable for graduates learning basic concepts and advanced applications of in-situ spectroscopy, electrocatalysis and electrode adsorptions. * Written by the most active scientists in the fields of spectroscopy, electrochemistry and surface science* Essential background knowledge for graduate students* A modern reference of cutting-edge scientific research
Download or read book Diffraction and Spectroscopic Methods in Electrochemistry written by and published by John Wiley & Sons. This book was released on 2009-04-22 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: This ninth volume in the series concentrates on in situ spectroscopic methods and combines a balanced mixture of theory and applications, making it highly readable for chemists and physicists, as well as for materials scientists and engineers. As with the previous volumes, all the chapters continue the high standards of this series, containing numerous references to further reading and the original literature, for easy access to this new field. The editors have succeeded in selecting highly topical areas of research and in presenting authors who are leaders in their fields, covering such diverse topics as diffraction studies of the electrode-solution interface, thin organic films at electrode surfaces, linear and non-linear spectroscopy as well as sum frequency generation studies of the electrified solid-solution interface, plus quantitative SNIFTIRS and PM-IRRAS. Special attention is paid to recent advances and developments, which are critically and thoroughly discussed. The result is a compelling set of reviews, serving equally well as an excellent and up-to-date source of information for experienced researchers in the field, as well as as an introduction for newcomers.
Download or read book Spectroscopic and Diffraction Techniques in Interfacial Electrochemistry written by C. Gutiérrez and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemistry is one of the oldest branches of Physical Chemistry. Having its foundations in the work of Faraday, Arrhenius and others, it evolved from the study of transport in electrolyte solutions to that of electrode kinetics. Kinetic methods are inherently unable to identify unequivocally the species involved in a reaction. Therefore, beginning in the 70s many spectroscopic and diffraction techniques were applied to the study of the electrode-electrolyte interface, in order to identify intermediary reaction species, and even the spatial arrangement of atoms or molecules at the interface. In order to disseminate these techniques, a NATO Advanced Sutdy Institute was held at Puerto de la Cruz, Tenerife (Canary Islands, Spain) from July 2 to 15, 1988. The Institute consisted of tutorial type lecutures, poster sessions, and round-table discussions. It was attended by over 65 participants from NATO-member countries, and others from Argentina and Japan. In the present volume most of the lectures presented at the Institute have been collected. At least one chapter is devoted to each technique. Emphasis has been made on case studies, rather than theory, which can be found in textbooks and other publications. Our purpose in this book is to help the electrochemists uninitiated in spectroscopic methods to decide which techniques would be suitable for application to their particular problems. We thank all the lecturers who contributed to this volume, and even those UHPs (Unrepentant Habitual Procrastinators) who did not in spite of our urgings to do so.
Download or read book Diffraction and Spectroscopic Methods in Electrochemistry written by Richard C. Alkire and published by John Wiley & Sons. This book was released on 2006-09-11 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: This ninth volume in the series concentrates on in situ spectroscopic methods and combines a balanced mixture of theory and applications, making it highly readable for chemists and physicists, as well as for materials scientists and engineers. As with the previous volumes, all the chapters continue the high standards of this series, containing numerous references to further reading and the original literature, for easy access to this new field. The editors have succeeded in selecting highly topical areas of research and in presenting authors who are leaders in their fields, covering such diverse topics as diffraction studies of the electrode-solution interface, thin organic films at electrode surfaces, linear and non-linear spectroscopy as well as sum frequency generation studies of the electrified solid-solution interface, plus quantitative SNIFTIRS and PM-IRRAS. Special attention is paid to recent advances and developments, which are critically and thoroughly discussed. The result is a compelling set of reviews, serving equally well as an excellent and up-to-date source of information for experienced researchers in the field, as well as as an introduction for newcomers.
Download or read book Electrochemical Interfaces and Electrode Processes written by E. B. Yeager and published by . This book was released on 1984 with total page 37 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report summarizes ONR research on the development and use of spectroscopic techniques for the study of electrochemical interfaces and electrode processes occurring at such interfaces. A number of in-situ techniques have been used including ultraviolet-visible reflectance spectroscopy and ellipsometry, infrared attenuated total reflectance spectroscopy, surface enhanced and resonant Raman spectroscopy, and Mossbauer spectroscopy. These in-situ techniques have provided important insight into the electronics and the properties of adsorbed molecules, ions and atoms at electrochemical interfaces. They have also been used to examine the adsorption isotherms and kinetics of adsorption-desorption. The in-situ techniques, however, are insufficient to establish the type of adsorption sites or compositional questions. For this reason substantial use has also been made of ex-situ surface physics techniques including LEED, AES, XPS and secondary ion mass spectroscopy. Special hardware and techniques have been developed as part of the ONR contract research to facilitate the transfer of electrodes between the electrochemical and ultrahigh vacuum environments and vice versa with the possibility for restructuring and contamination at a minimum. The report describes the application of these techniques to adsorption on single crystal electrodes. (Author).
Download or read book Raman Spectroscopy for In situ Monitoring of Electrode Processes written by and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The theoretical and experimental applications of Raman spectroscopic techniques to the study of battery electrode processes are described. In particular, the potential of Raman spectroscopy as an in-situ analytical tool for the characterization of the structure and composition of electrode surface layers at electrode-electrolyte interfaces during electrolysis is examined. It is anticipated that this understanding of the battery electrode processes will be helpful in designing battery active material with improved performance. The applications of Raman spectroscopy to the in-situ study of electrode processes has been demonstrated in a few selected areas, including: (1) the anodic corrosion of lead in sulfuric acid and (2) the anodization and sulfation of tetrabasicleadsulfate in sulfuric acid. Preliminary results on the anodization of iron and on the electrochemical behavior of nickel positive-electrode active material in potassium hydroxide electrolytes are presented in the Appendix.
Download or read book Laser Techniques for the Study of Electrode Processes written by Gyözö G. Láng and published by Springer Science & Business Media. This book was released on 2012-04-23 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: Laser-enabled measurements are valuable tools for the investigation of surfaces and interfaces or for the in situ investigation of interfacial processes including electrode processes. The understanding of the thermodynamics of solid/liquid surfaces is important for surface science and electrochemistry. In the first part of this book, the authors describe a range of techniques for investigating interfacial tension and surface stress, which is important for coatings, thin films, and fuel cells. The techniques covered comprise bending beam (bending plate, bending cantilever, wafer curvature) methods with different detection techniques. Special attention is given to methods using optical detection by laser beam deflection or interferometry. The second part is devoted to the techniques based on the detection of refractive index gradients in the solution. The refractive index changes could be related to concentration gradients (Probe Beam Deflection, PBD) or light-induced thermal gradients (Photothermal Deflection Spectroscopy, PDS). The application of the techniques to surface-confined and solution electrochemical systems is described. Subsequently, a comparison with others techniques able to monitor ion fluxes is performed.
Download or read book Handbook of Electrochemistry written by Cynthia G. Zoski and published by Elsevier. This book was released on 2007-02-07 with total page 935 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)
Download or read book Organic Electrochemistry written by Ole Hammerich and published by CRC Press. This book was released on 2015-09-22 with total page 1706 pages. Available in PDF, EPUB and Kindle. Book excerpt: Praise for the Fourth Edition"Outstanding praise for previous editions.the single best general reference for the organic chemist."-Journal of the Electrochemical Society"The cast of editors and authors is excellent, the text is, in general, easily readable and understandable, well documented, and well indexed those who purchase the book will be sa
Download or read book Electrochemical Imaging written by Todd H. Lewis and published by American Chemical Society. This book was released on 2024-06-03 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt: ACS In Focus Electrochemical Imaging introduces some of the most exciting and important imaging techniques in electrochemistry. This digital primer, targeted at senior undergraduate students and first-year graduate students, demonstrates how electrochemical imaging has become increasingly important in enhancing our fundamental understanding of the electrode/solution interface. Chapter 1 introduces electrochemistry, the unique aspects of electrochemical reactions, and the key importance of electrochemical imaging. Chapter 2 focuses on array-based electrochemical imaging methods. Chapter 3 describes several electrochemical imaging methods based on small scanning probes. Chapter 4 introduces electrochemical imaging methods based on optical microscopies, such as fluorescence, dark field, and Raman spectroscopy. The last chapter is devoted to briefly discussing some imaging methods for examining the electrochemical interface with molecular and atomic scale resolution. It also reveals exciting ways of using in-situ methods, such as electron microscopies, to image electrochemical processes in situ.
Download or read book Electrochemical and spectroscopic techniques combined in situ for the study of artificial and biological redox systems at a molecular level written by Daniela D. Schlereth and published by . This book was released on 1998 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Vibrational Spectroscopy at Electrified Interfaces written by Andrzej Wieckowski and published by John Wiley & Sons. This book was released on 2013-07-15 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reviews the latest theory, techniques, and applications Surface vibrational spectroscopy techniques probe the structure and composition of interfaces at the molecular level. Their versatility, coupled with their non-destructive nature, enables in-situ measurements of operating devices and the monitoring of interface-controlled processes under reactive conditions. Vibrational Spectroscopy at Electrified Interfaces explores new and emerging applications of Raman, infrared, and non-linear optical spectroscopy for the study of charged interfaces. The book draws from hundreds of findings reported in the literature over the past decade. It features an internationally respected team of authors and editors, all experts in the field of vibrational spectroscopy at surfaces and interfaces. Content is divided into three parts: Part One, Nonlinear Vibrational Spectroscopy, explores properties of interfacial water, ions, and biomolecules at charged dielectric, metal oxide, and electronically conductive metal catalyst surfaces. In addition to offering plenty of practical examples, the chapters present the latest measurement and instrumental techniques. Part Two, Raman Spectroscopy, sets forth highly sensitive approaches for the detection of biomolecules at solid-liquid interfaces as well as the use of photon depolarization strategies to elucidate molecular orientation at surfaces. Part Three, IRRAS Spectroscopy (including PM-IRRAS), reports on wide-ranging systems from small fuel molecules at well-defined surfaces to macromolecular complexes that serve as the building blocks for functional interfaces in devices designed for chemical sensing and electric power generation. The Wiley Series on Electrocatalysis and Electrochemistry is dedicated to reviewing important advances in the field, exploring how these advances affect industry. The series defines what we currently know and can do with our knowledge of electrocatalysis and electrochemistry as well as forecasts where we can expect the field to be in the future.
Download or read book In situ Combined Electrochemical Techniques for Conducting Polymers written by Csaba Visy and published by Springer. This book was released on 2017-02-28 with total page 78 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book outlines methods to improve functioning of these polymer based devices – in particular, the multi-faceted cognition of these materials. In situ electrochemical techniques are studied to elucidate redox switching between non-conducting and conducting states. The book examines the advantages of combinations of in situ electrochemical techniques in a hyphenated mode for analyzing conducting polymers.
Download or read book New Techniques for the Study of Electrodes and Their Reactions written by R.G. Compton and published by Elsevier. This book was released on 1989-04-01 with total page 521 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 29 gives an account of new techniques for the study of electrodes and their reactions. It extends and complements Volumes 26 and 27 of the series which provide an introductory treatment of modern electrochemical methodology and reactions. This volume covers the various branches of spectroelectrochemistry and also some recent purely electrochemical advances. In-situ spectroelectrochemical techniques are covered by chapters on infrared, Raman, EPR, ellipsometry, electroreflectance, and photocurrent spectroscopy. Ex-situ UHV experiments are treated in a separate chapter. New electrochemical directions are described in chapters on hydrodynamic methods, channel electrodes, and microelectrodes. A final chapter covers computing strategies for the on-line accumulation and processing of electrochemical data.
Download or read book Application of Polarization Modulation Infrared Reflection Absorption Spectroscopy in Electrochemistry written by Izabella Brand and published by . This book was released on 2020 with total page 122 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the physical basis of polarization modulation infrared reflection-absorption spectroscopy and its application in electrochemical studies. It provides a concise yet comprehensive review of the research done in this field in the last 20 years. Electrochemical methods are used to determine the rate and mechanism of charge transfer reactions between an electrode and species adsorbed or diffusing to its surface. In the past two decades PM-IRRAS has grown to be one of the most important vibrational spectroscopy techniques applied to investigate structural changes taking place at the electrochemical interface. The monograph presents foundations of this technique and reviews in situ studies of redox-inactive and redox-active films adsorbed on electrode surfaces. It also discusses experimental conditions required in electrochemical and spectroscopic studies and presents practical solutions to perform efficient experiments. As such, it offers an invaluable resource for graduate and postgraduate students, as well as for all researchers in academic and industrial laboratories.
Download or read book Spectroelectrochemistry written by Wolfgang Kaim and published by Royal Society of Chemistry. This book was released on 2008 with total page 247 pages. Available in PDF, EPUB and Kindle. Book excerpt: A practical guidebook illustrating the applications of spectroelectrochemistry to the understanding of redox reactions through identification of their intermediaries and products.
