Download or read book Analysis of Organoaluminium and Organozinc Compounds written by T. R. Crompton and published by Elsevier. This book was released on 2013-10-22 with total page 377 pages. Available in PDF, EPUB and Kindle. Book excerpt: Analysis of Organoaluminum and Organozinc Compounds, Volume 31 presents information pertinent to the organo compound of aluminum and zinc. This book discusses the growing interest in organoaluminum compounds as intermediates in the manufacture of organic chemicals. Comprised of nine chapters, this volume begins with an overview of the methods for the determination of different functional groups and elements in organoaluminum compounds, viz. alkyle, alkozide, hydride, aluminum, halogens, amino and thio alkoxide groups. This text then explains the different solution methods of analysis of organoaluminum compounds, including various titrimetric procedures. Other chapters consider an iodometric titration method for analyzing organoaluminum compounds, which is particularly useful for rapid analysis of diluted samples. This book discusses as well the extensive work on the analysis of organoaluminum compounds by thermometric titrimetry with suitable reagents. The final chapter deals with the detailed procedures for carrying out different analyses. This book is a valuable resource for students of analytical chemistry.
Download or read book Principles of Field Ionization and Field Desorption Mass Spectrometry written by G. Svehla and published by . This book was released on 1968 with total page 335 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Comprehensive Organometallic Analysis written by T.R. Crompton and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 907 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is now some sixteen years since the author's first series of books on the analysis of organometallic compounds. Many developments in the subject have occurred since that time and a new book on the subject is now overdue. The present book aims to provide a comprehensive review of the subject. It covers not only all aspects of the analysis of organometallic compounds but also contains two additional chapters, dealing with environmental analysis and the use of chelates of metals in the determination of very low concentrations of organic metals. Whilst reviewing the literature for the present book, it was observed that whereas papers published prior to 1973 dealt almost exclusively with various forms of analysis, a high proportion of those published during the past ten years were concerned with the application of proven or newly developed methods to the determination of organometallic compounds in environmental samples such as water, air, soil, river and ocean sediments, fish life and biota samples. An increasing range of elements including mercury, lead, arsenic, tin, antimony, selenium and manganese are now being found in organically bound forms in the environment, some resulting from pollution, others formed in nature by bacterial processes. As many of these substances have appreciable implications to human and animal health and the ecosystem as a whole, it was considered that it would be timely to include a separate chapter in the book devoted entirely to this subject.
Download or read book Analytical Applications of EDTA and Related Compounds written by R. Přibil and published by Elsevier. This book was released on 2013-09-17 with total page 391 pages. Available in PDF, EPUB and Kindle. Book excerpt: Analytical Applications of EDTA and Related Compounds examines the analytical applications of ethylenediaminetetra-acetic acid (EDTA) and related compounds. This book also considers the “passive role of these substances, that is, their screening (masking) properties, which greatly improve the selectivity of the reactions in common use. This text consists of six chapters organized into two sections. The first part deals with the uses of EDTA and its derivatives in some fields of chemical analysis. After providing an overview of the history behind the development of EDTA as an analytical reagent, this book discusses to the nature of equilibria of complexes and the methods used in their investigation. The next chapter is dedicated to the reactions of “classical gravimetric analysis, including the precipitation reactions by means of organic reagents. The chapter on colorimetry includes a section on “colored complexing agents, which can be used also in colorimetric determinations of some elements. This text concludes by evaluating the use of EDTA as a masking agent in colorimetry. This book will be of interest to students and practitioners working in analytical chemistry and related disciplines, including polarography, chromatography, electrophoresis, flame photometry, and qualitative analysis.
Download or read book Analytical Chemistry of Organic Halogen Compounds written by L. Mázor and published by Elsevier. This book was released on 2013-09-03 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Analytical Chemistry of Organic Halogen Compounds presents the procedures applied in the analysis of organic halogen compounds. This book is composed of eight chapters that discuss the methods involved in the production and application of organic halogen compounds and in overcoming contamination problems caused by these compounds. After briefly dealing with the preparation, characteristics, and reactions of organic halogen compounds, this book goes on discussing the fundamental concepts of methods for the detection of halogens in organic compounds, namely, chlorine, bromine, iodine, and fluorine. The following chapter describes the characteristic features, advantages, and disadvantages of ultramicro and submicro chemical methods. A chapter also examines the qualitative and quantitative studies of organic halogen compounds based on the thermal and chemical stability of these compounds. The concluding chapters discuss the interference or interfering effects of halogens and their elimination in the determination of other elements. A list of physical constants of organic halogen compounds of general pharmaceutical and industrial significance is provided. This book is an ideal source for analytical chemists and other workers who are interested in the theoretical bases of the methods.
Download or read book Aliphatic Compounds written by M. F. Ansell and published by Elsevier. This book was released on 1975-01-01 with total page 477 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aliphatic Compounds
Download or read book Isotope Dilution Analysis written by J. Tölgyessy and published by Elsevier. This book was released on 2013-10-22 with total page 197 pages. Available in PDF, EPUB and Kindle. Book excerpt: International Series of Monographs in Analytical Chemistry, Volume 49: Isotope Dilution Analysis focuses on the method of isotope dilution analysis (IDA). The book first discusses the principles, types, and theory of IDA. Classification of the methods of IDA; precision, accuracy, and sensitivity of IDA; and types of IDA are described. The text also examines experimental techniques, separation, and mass determination. The separation of components, reagents and tracers, and amount of substance separated are underscored. The text takes a look at the inorganic applications of IDA, including determination of elements and selected procedures. The text examines the applications of IDA in organic chemistry and biochemistry, particularly in the analysis of alcohols and ethers, steroids, penicillin, proteins and amino acids, and insecticides. The book discusses IDA with stable isotopes. Methods for the determination of isotopic composition, fundamentals and technique, and practical applications are underscored. The text also emphasizes the special applications of isotope dilution. Determination of the content of isotopic carriers in radioactive preparations; determination of the coefficient of self-absorption and specific activity; and determination of radioactive contaminants are discussed. The text is a vital reference for readers interested in isotope dilution analysis.
Download or read book Chemical Analysis of Additives in Plastics written by T. R. Crompton and published by Elsevier. This book was released on 2016-07-29 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: International Series in Analytical Chemistry, Volume 46: Chemical Analysis of Additives in Plastics, Second Edition brings together numerous investigations on the characterization, identification, and determination of various types of additives in plastics. This book is divided into five chapters. Chapters 1 and 2 describe first the methods for examining additives present in polymers based on either direct spectroscopy of a cast polymer film or on solvent extraction of total additives from the polymer followed by quantitative chemical or physical analysis for various components in the extract. Chapter 3 discusses the application of thin-layer and column chromatography to the separation and determination of known additives. Chapters 4 and 5 examine the application of combined chromatographic and spectroscopic techniques for the separation and determination of unknown plastics additives. This book will prove useful to plastics manufacturers, researchers, institutions, and universities.
Download or read book The Determination of Impurities in Nuclear Grade Sodium Metal written by Louis Silverman and published by Elsevier. This book was released on 2013-10-22 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt: International Series of Monographs in Analytical Chemistry, Volume 44: The Determination of Impurities in Nuclear Grade Sodium Metal (and Related Sodium Compounds) provides analytical chemical procedures for the determination of impurities in nuclear grade sodium metal. This book is composed of 25 chapters, and begins with a presentation of the methods for dissolving, bulk separation, sampling, and handling of sodium metal. The rest of the book describes the procedures for impurity determination in nuclear grade sodium metals, including aluminum, bismuth, boron, cadmium, calcium, magnesium, carbon, cesium, and chloride. Other impurities considered include chromium, cobalt, copper, hydrogen, iodine, iron, lead, lithium, manganese, nickel, oxide, oxygen, and phosphorus. The last chapters examine the procedures for determination of potassium, silicon, sulfur, and uranium impurities. This book is of value to analytical and inorganic chemists.
Download or read book Indicators written by Edmund Bishop and published by Elsevier. This book was released on 2013-10-22 with total page 759 pages. Available in PDF, EPUB and Kindle. Book excerpt: Indicators offers a comprehensive account of indicators and their applications in areas such as titrimetric analysis and the analysis of mineral waters. The theory and principles of visual indicators are discussed, along with acid-base indicators, indicators for non-aqueous acid-base titrations, and titrations with non-chelating ligands. Metallochromic indicators, adsorption indicators, oxidation-reduction indicators, and fluorescent and chemiluminescent indicators are also considered. This volume is comprised of 10 chapters and begins with a brief history of indicators, including the contribution of Robert Boyle in the field. The different kinds of indicators are also described, along with developments in indicators in the nineteenth century. The next chapter deals with the theory and principles of visual indicators, followed by a discussion on acid-base indicators such as organic dyes, inorganic substances, compounds capable of fluorescence, and chemiluminescent systems. Subsequent chapters explore other varieties of indicators, including indicators for non-aqueous acid-base titrations, metallochromic indicators, and adsorption indicators, as well as oxidation-reduction indicators and fluorescent and chemiluminescent indicators. This book will be of interest to chemists.
Download or read book Analytical Chemistry of Molybdenum and Tungsten written by W. T. Elwell and published by Elsevier. This book was released on 2013-10-22 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: International Series of Monographs in Analytical Chemistry, Volume 47: Analytical Chemistry of Molybdenum and Tungsten describes the chemical and instrumental methods of analysis of molybdenum and tungsten. This book is composed of 15 chapters that particularly consider detailed methods for determining these metals in typical samples and their alloys by both classical and modern techniques. The opening chapters discuss the history, occurrence, physico-chemical properties, and applications of molybdenum and tungsten. The succeeding chapters deal with the metals’ sampling, decomposition, separation, and qualitative detection. Considerable chapters are devoted to various chemical and instrumental methods for their analysis, including gravimetry, titrimetry, colorimetry, polarography, amperometry, coulometry, emission and atomic absorption spectroscopy, X-ray spectrophotometry, mass spectrometry, and radiochemical methods. The concluding chapter examines the determination of impurities and alloying elements. This book will prove useful to analytical and inorganic chemists, as well as analytical and inorganic chemistry students.
Download or read book Ion Exchange in Analytical Chemistry written by William Rieman and published by Elsevier. This book was released on 2013-10-22 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Analytical Chemistry, Volume 38: Ion Exchange in Analytical Chemistry provides a broad survey of the important role that ion exchange can and should play in chemical analysis. This book focuses on the plate-equilibrium theory of chromatography, which is less difficult theoretically than the mass-transfer theory. Organized into 11 chapters, this volume begins with an overview of the earliest recorded application of ion exchange. This text then examines how high temperature affects ion-exchange resins. Other chapters consider the exchange of ions between a solid ion-exchanging material and a solution, which is a typically reversible reaction. This book describes as well the relatively simple separations and other applications of ion exchange to analytical chemistry. The final chapter deals with the interesting nature of the metal complexes formed within the exchanger and describe the use of ion-exchange distribution studies to determine the stability and nature of complexes existing in the solution. This book is a valuable resource for analytical chemists.
Download or read book N Benzoylphenylhydroxylamine and Its Analogues written by A. K. Majumdar and published by Elsevier. This book was released on 2017-07-19 with total page 223 pages. Available in PDF, EPUB and Kindle. Book excerpt: International Series of Monographs in Analytical Chemistry, Volume 50: N-Benzoylphenylhydroxylamine and its Analogues covers the analytical applications of the organic hydroxylamine derivatives. This book is composed of seven chapters, and starts with a brief historical account of the uses of organic reagents in inorganic analysis. The next chapter discusses some basic physico-chemical factors associated with the constitution of a good reagent, including some fundamental ideas about the type and nature of the principal reactive and other groupings in the ligand. A chapter deals with the inclusion of the methods of preparation and properties of N-benzoylphenylhydroxylamine (BPHA) and its analogues and derivatives, and their reactions with different metal ions. These topics are followed by descriptions of the various types of analytical applications of BPHA and its analogues, such as gravimetry, spectrophotometry, and solvent extraction, as well as their applications in titrimetry and paper chromatography. This book is of value to analytical and organic chemists.
Download or read book Analytical Chemistry of Zirconium and Hafnium written by Anil K. Mukherji and published by Elsevier. This book was released on 2013-10-22 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: Analytical Chemistry of Zirconium and Hafnium compiles literature on the characterization and analysis of zirconium and hafnium. Various methods in studying the properties of the featured elements are presented in this book. This book also discusses the aqueous solutions of zirconium and hafnium. It then explains the methods such as dissolution of ores and alloys, detection and identification, and gravimetric determinations. This text further examines the titrimetric, electrometric, and absorptiometric methods, as well as methods of separations using ion-exchange and using solvent extraction, along with separation of hafnium from zirconium. The latter part of this text presents methods such as spectrographic analyses, X-ray analyses, and neutron activation analysis and separation of tracers. This book will come in handy for chemists and chemistry students, as well as for others interested in studying zirconium and hafnium.
Download or read book Principles of Field Ionization and Field Desorption Mass Spectrometry written by H. D. Beckey and published by Elsevier. This book was released on 2016-07-29 with total page 355 pages. Available in PDF, EPUB and Kindle. Book excerpt: Principles of Field Ionization and Field Desorption Mass Spectrometry delves deeper into field ionization and field desorption. The book covers the five main subareas of field ionization and field desorption mass spectrometry that has grown in importance. Coverage includes the theory of field ionization and field desorption; field ionization and field desorption techniques and sources; high field surface chemistry; kinetics and mechanisms of decompostion of field ions in the gas phase; and qualitative and mixture analysis with field ionization and field desorption mass spectrometry. The text is recommended for students, experts, and researchers in chemistry, especially those who wish to learn more or have an in-depth study about field ionization and field desorption, its principles, and its applications in chemistry.
Download or read book The Destruction of Organic Matter written by T. T. Gorsuch and published by Elsevier. This book was released on 2013-10-22 with total page 161 pages. Available in PDF, EPUB and Kindle. Book excerpt: International Series of Monographs in Analytical Chemistry, Volume 39: The Destruction of Organic Matter focuses on the identification of trace elements in organic compounds. The monograph first offers information on the processes involved in the determination of trace elements in organic matters, as well as the methods not involving complete destruction of these elements. The text surveys the sources of errors in the processes responsible in pinpointing elements in organic compounds. These processes include sampling, disruption of the samples, manipulation, and measurements. The book examines the processes of wet and dry oxidation, including their applications to sulfuric, nitric, and perchloric acids and hydrogen peroxide. The methods of dry ashing and oxidation with excited oxygen and oxidative fusion are elaborated. The text also underscores the varying methods in removing trace elements in organic compounds. The elements include zinc, copper, silver, gold, lead, germanium, titanium, arsenic, bismuth, and vanadium. The book also describes wet digestion methods and dry ashing procedures in the removal of trace elements in organic matters. The monograph is a vital source of information for readers interested in the identification of trace elements in organic compounds.
Download or read book Inorganic Syntheses written by and published by John Wiley & Sons. This book was released on 2009-09-22 with total page 223 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.
