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Book Analysis of Ignition Behavior in a Turbocharged Direct Injection Dual Fuel Engine Using Propane and Methane as Primary Fuels

Download or read book Analysis of Ignition Behavior in a Turbocharged Direct Injection Dual Fuel Engine Using Propane and Methane as Primary Fuels written by and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This paper presents experimental analyses of the ignition delay (ID) behavior for diesel-ignited propane and diesel-ignited methane dual fuel combustion. Two sets of experiments were performed at a constant speed (1800 rev/min) using a 4-cylinder direct injection diesel engine with the stock ECU and a wastegated turbocharger. First, the effects of fuel-air equivalence ratios (© pilot ¼ 0.2-0.6 and © overall ¼ 0.2-0.9) on IDs were quantified. Second, the effects of gaseous fuel percent energy substitution (PES) and brake mean effective pressure (BMEP) (from 2.5 to 10 bar) on IDs were investigated. With constant © pilot (> 0.5), increasing © overall with propane initially decreased ID but eventually led to premature propane autoignition; however, the corresponding effects with methane were relatively minor. Cyclic variations in the start of combustion (SOC) increased with increasing © overall (at constant © pilot), more significantly for propane than for methane. With increasing PES at constant BMEP, the ID showed a nonlinear (initially increasing and later decreasing) trend at low BMEPs for propane but a linearly decreasing trend at high BMEPs. For methane, increasing PES only increased IDs at all BMEPs. At low BMEPs, increasing PES led to significantly higher cyclic SOC variations and SOC advancement for both propane and methane. Finally, the engine ignition delay (EID) was also shown to be a useful metric to understand the influence of ID on dual fuel combustion.

Book Recent Technologies for Enhancing Performance and Reducing Emissions in Diesel Engines

Download or read book Recent Technologies for Enhancing Performance and Reducing Emissions in Diesel Engines written by Basha, J. Sadhik and published by IGI Global. This book was released on 2020-02-21 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt: In today’s global context, there has been extensive research conducted in reducing harmful emissions to conserve and protect our environment. In the automobile and power generation industries, diesel engines are being utilized due to their high level of performance and fuel economy. However, these engines are producing harmful pollutants that contribute to several global threats including greenhouse gases and ozone layer depletion. Professionals have begun developing techniques to improve the performance and reduce emissions of diesel engines, but significant research is lacking in this area. Recent Technologies for Enhancing Performance and Reducing Emissions in Diesel Engines is a pivotal reference source that provides vital research on technical and environmental enhancements to the emission and combustion characteristics of diesel engines. While highlighting topics such as biodiesel emulsions, nanoparticle additives, and mathematical modeling, this publication explores the potential additives that have been incorporated into the performance of diesel engines in order to positively affect the environment. This book is ideally designed for chemical and electrical engineers, developers, researchers, power generation professionals, mechanical practitioners, scholars, ecologists, scientists, graduate students, and academicians seeking current research on modern innovations in fuel processing and environmental pollution control.

Book Comparison of Propane and Methane Performance and Emissions in a Turbocharged Direct Injection Dual Fuel Engine

Download or read book Comparison of Propane and Methane Performance and Emissions in a Turbocharged Direct Injection Dual Fuel Engine written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: With increasingly restrictive NO x and particulate matter emissions standards, the recent discovery of new natural gas reserves, and the possibility of producing propane efficiently from biomass sources, dual fueling strategies have become more attractive. This paper presents experimental results from dual fuel operation of a four-cylinder turbocharged direct injection (DI) diesel engine with propane or methane (a natural gas surrogate) as the primary fuel and diesel as the ignition source. Experiments were performed with the stock engine control unit at a constant speed of 1800 rpm, and a wide range of brake mean effective pressures (BMEPs) (2.7-11.6 bars) and percent energy substitutions (PESs) of C 3 H 8 and CH 4. Brake thermal efficiencies (BTEs) and emissions (NO x, smoke, total hydrocarbons (THCs), CO, and CO 2) were measured. Maximum PES levels of about 80-95% with CH 4 and 40-92% with C 3 H 8 were achieved. Maximum PES was limited by poor combustion efficiencies and engine misfire at low loads for both C 3 H 8 and CH 4, and the onset of knock above 9 bar BMEP for C 3 H 8. While dual fuel BTEs were lower than straight diesel BTEs at low loads, they approached diesel BTE values at high loads. For dual fuel operation, NO x and smoke reductions (from diesel values) were as high as 66-68% and 97%, respectively, but CO and THC emissions were significantly higher with increasing PES at all engine loads.

Book Detailed Characterization of Conventional and Low Temperature Dual Fuel Combustion in Compression Ignition Engines

Download or read book Detailed Characterization of Conventional and Low Temperature Dual Fuel Combustion in Compression Ignition Engines written by and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The goal of this study is to assess conventional and low temperature dual fuel combustion in light- and heavy-duty multi-cylinder compression ignition engines in terms of combustion characterization, performance, and emissions. First, a light-duty compression ignition engine is converted to a dual fuel engine and instrumented for in-cylinder pressure measurements. The primary fuels, methane and propane, are each introduced into the system by means of fumigation before the turbocharger, ensuring the air-fuel composition is well-mixed. Experiments are performed at 2.5, 5, 7.5, and 10 bar BMEP at an engine speed of 1800 RPM. Heat release analyses reveal that the ignition delay and subsequent combustion processes are dependent on the primary fuel type and concentration, pilot quantity, and loading condition. At low load, diesel-ignited propane yields longer ignition delay periods than diesel-ignited methane, while at high load the reactivity of propane is more pronounced, leading to shorter ignition delays. At high load (BMEP = 10 bar), the rapid heat release associated with diesel-ignited propane appears to occur even before pilot injection, possibly indicating auto-ignition of the propane-air mixture. Next, a modern, heavy-duty compression ignition engine is commissioned with an open architecture controller and instrumented for in-cylinder pressure measurements. Initial diesel-ignited propane dual fuel experiments (fumigated before the turbocharger) at 1500 RPM reveal that the maximum percent energy substitution (PES) of propane is limited to 86, 60, 33, and 25 percent at 5, 10, 15, and 20 bar BMEP, respectively. Fueling strategy, injection strategy, exhaust gas recirculation (EGR) rate, and intake boost pressure are varied in order to maximize the PES of propane at 10 bar BMEP, which increases from 60 PES to 80 PES of propane. Finally, diesel-ignited propane dual fuel low temperature combustion (LTC) is implemented using early injection timings (50 DBTDC) at 5 bar BMEP. A sweep of injection timings from 10 DBTDC to 50 DBTDC reveals the transition from conventional to low temperature dual fuel combustion, indicated by ultra-low NOx̳ and smoke emissions. Optimization of the dual fuel LTC concept yields less than 0.02 g/kW-hr NOx̳ and 0.06 FSN smoke at 93 PES of propane.

Book Introduction to Hydrogen Technology

Download or read book Introduction to Hydrogen Technology written by K. S. V. Santhanam and published by John Wiley & Sons. This book was released on 2017-09-19 with total page 431 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduces the field of hydrogen technology and explains the basic chemistry underlying promising and innovative new technologies This new and completely updated edition of Introduction to Hydrogen Technology explains, at an introductory level, the scientific and technical aspects of hydrogen technology. It incorporates information on the latest developments and the current research in the field, including: new techniques for isolating and storing hydrogen, usage as a fuel for automobiles, residential power systems, mobile power systems, and space applications. Introduction to Hydrogen Technology, Second Edition features classroom-tested exercises and sample problems. It details new economical methods for isolating the pure hydrogen molecule. These less expensive methods help make hydrogen fuel a very viable alternative to petroleum-based energy. The book also adds a new chapter on hydrogen production and batteries. It also provides in-depth coverage of the many technical hurdles in hydrogen storage. The developments in fuel cells since the last edition has been updated. Offers new chapters on hydrogen production, storage, and batteries Features new sections on advanced hydrogen systems, new membranes, greenhouse gas sensors and updated technologies involving solar and wind energies Includes problems at the end of the Chapters, as well as solutions for adopters This book is an introduction to hydrogen technology for students who have taken at least one course in general chemistry and calculus; it will also be a resource book for scientists and researchers working in hydrogen-based technologies, as well as anyone interested in sustainable energy.

Book Alternative Fuels and Advanced Vehicle Technologies for Improved Environmental Performance

Download or read book Alternative Fuels and Advanced Vehicle Technologies for Improved Environmental Performance written by Richard Folkson and published by Woodhead Publishing. This book was released on 2022-07-27 with total page 800 pages. Available in PDF, EPUB and Kindle. Book excerpt: Alternative Fuels and Advanced Vehicle Technologies for Improved Environmental Performance: Towards Zero Carbon Transportation, Second Edition provides a comprehensive view of key developments in advanced fuels and vehicle technologies to improve the energy efficiency and environmental impact of the automotive sector. Sections consider the role of alternative fuels such as electricity, alcohol and hydrogen fuel cells, as well as advanced additives and oils in environmentally sustainable transport. Other topics explored include methods of revising engine and vehicle design to improve environmental performance and fuel economy and developments in electric and hybrid vehicle technologies. This reference will provide professionals, engineers and researchers of alternative fuels with an understanding of the latest clean technologies which will help them to advance the field. Those working in environmental and mechanical engineering will benefit from the detailed analysis of the technologies covered, as will fuel suppliers and energy producers seeking to improve the efficiency, sustainability and accessibility of their work. - Provides a fully updated reference with significant technological advances and developments in the sector - Presents analyses on the latest advances in electronic systems for emissions control, autonomous systems, artificial intelligence and legislative requirements - Includes a strong focus on updated climate change predictions and consequences, helping the reader work towards ambitious 2050 climate change goals for the automotive industry

Book Combustion Engines Development

Download or read book Combustion Engines Development written by Günter P. Merker and published by Springer Science & Business Media. This book was released on 2011-09-24 with total page 660 pages. Available in PDF, EPUB and Kindle. Book excerpt: Combustion Engines Development nowadays is based on simulation, not only of the transient reaction of vehicles or of the complete driveshaft, but also of the highly unsteady processes in the carburation process and the combustion chamber of an engine. Different physical and chemical approaches are described to show the potentials and limits of the models used for simulation.

Book Natural Gas Engines

Download or read book Natural Gas Engines written by Kalyan Kumar Srinivasan and published by Springer. This book was released on 2018-11-03 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the various advanced reciprocating combustion engine technologies that utilize natural gas and alternative fuels for transportation and power generation applications. It is divided into three major sections consisting of both fundamental and applied technologies to identify (but not limited to) clean, high-efficiency opportunities with natural gas fueling that have been developed through experimental protocols, numerical and high-performance computational simulations, and zero-dimensional, multizone combustion simulations. Particular emphasis is placed on statutes to monitor fine particulate emissions from tailpipe of engines operating on natural gas and alternative fuels.

Book Effects of Different Fuels on a Turbocharged  Direct Injection  Spark Ignition Engine

Download or read book Effects of Different Fuels on a Turbocharged Direct Injection Spark Ignition Engine written by Justin E. Negrete and published by . This book was released on 2010 with total page 65 pages. Available in PDF, EPUB and Kindle. Book excerpt: The following pages describe the experimentation and analysis of two different fuels in GM's high compression ratio, turbocharged direct injection (TDI) engine. The focus is on a burn rate analysis for the fuels - gasoline and E85 - at varying intake air temperatures. The results are aimed at aiding in a subsequent study that will look at the benefits of direct injection in turbocharged engines, ethanol's knock suppression properties, and the effects of ethanol concentration in gasoline/ethanol blends. Spark sweeps were performed for each fuel/temperature combination to find the knock limit and to assess each fuels' sensitivity to spark timing and temperature. The findings were that E85 has lower sensitivity to spark timing in terms of NIMEP loss for deviation from MBT timing. A 5% loss in NIMEP was seen at 3° of spark advance or retard for gasoline, whereas E85 took 5' to realize the same drop in NIMEP. Gasoline was also much more sensitive to intake air temperature changes than E85. Increasing the intake air temperature for gasoline decreased the peak pressure, however, knock onset began earlier for the higher temperatures, indicating that end-gas autoignition is more dependent on temperature than pressure. E85's peak pressure sensitivity to spark timing was found to be about 50% lower than that of gasoline and it displayed much higher knock resistance, not knocking until the intake air temperature was 130°C with spark timing of 30° bTDC. These results give some insight into the effectiveness of ethanol to improve gasoline's anti-knock index. Future experiments will aim to quantify charge cooling and anti-knock properties, and determine how ethanol concentration in gasoline/ethanol blends effects this knock suppression ability.

Book Experimental and Numerical Study of the Combustion and Emissions of Natural Gas diesel Dual fuel Engine Under Different Engine Load speed Conditions

Download or read book Experimental and Numerical Study of the Combustion and Emissions of Natural Gas diesel Dual fuel Engine Under Different Engine Load speed Conditions written by Amin Yousefi and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Universal concerns about degradation in air quality, stringent emissions regulations, energy scarcity, and global warming have prompted research and development of compressed ignition engines using alternative combustion concepts. Natural gas/diesel dual-fuel combustion is an advanced combustion concept for compression ignition diesel engines, which has attracted global attention in recent years. This combustion concept is accomplished by creating reactivity stratification in the cylinder via the use of two fuels characterized by distinctly different reactivities. The low reactivity and main fuel (i.e., natural gas) is firstly premixed with air and then charged into the cylinder through the intake manifold, and the high reactivity fuel (i.e., diesel) is then injected into the charged mixture through a direct injector. This combustion concept offers prominent benefits in terms of a significant reduction of particulate matter (PM) and sometimes nitrogen oxides (NOx) emissions while maintaining comparable fuel efficiency compared to diesel engine. However, low thermal efficiency and high greenhouse gas (GHG) emissions under low load conditions are major challenges which prevented the implementation of dual-fuel concept in commercial automative engines. The present study investigates different combustion approaches with the aim to enhance combustion performance and reduce emissions of unburned methane, CO, NOx, soot, and GHG of natural gas/diesel dual-fuel engines under different engine load-speed conditions. In particular, the main focus of this thesis is on low load conditions where GHG emissions of conventional natural gas/diesel dual-fuel engine is much higher than that of conventional diesel engine. Alongside the experimental study, a computational fluid dynamic (CFD) model is developed to help understand the behaviour of natural gas/diesel dual-fuel combustion process under different engine load-speed conditions. The studied approaches showed that the fuel efficiency and GHG emissions of natural gas/diesel dual-fuel engine can be significantly improved under low engine load conditions compared to diesel engine.

Book Combustion Characteristics of Turbo Charged DISI engines

Download or read book Combustion Characteristics of Turbo Charged DISI engines written by Henrik Hoffmeyer and published by Logos Verlag Berlin GmbH. This book was released on 2012 with total page 193 pages. Available in PDF, EPUB and Kindle. Book excerpt: In spite of progress in the development of alternative powertrain systems and energy sources, the internal combustion and all its derivates still are and will be the main powertrain for automobiles. In SI-engines, several approaches compete with each other like the controlled auto ignition (CAI or HCCI), throttle-free load control using variable valvetrains, stratified mixture formation with lean engine operation or highly turbo charged downsizing concepts all combined with gasoline direct injection. The presented work makes a contribution for a deeper understanding of the combustion process of a turbo charged direct injection engine operating with external EGR as well as lean stratified mixture. Using detailed test bench investigations and introducing a new optical measurement tool, the combustion process is described in detail focusing on the occurrence of non-premixed combustion phenomena. The influence of engine parameters like global and local air-/fuel ratio, external EGR and fuel rail pressure as well as the influence of fuel parameters are discussed giving a characterization of the combustion process of stratified engine operation. Furthermore, the influences of non-inert exhaust gas components on engine knock tendency are investigated using external EGR with an EGR catalyst. Opposing the results to numerical analysis, combustion characteristics of turbo charged DISI-engines are presented.

Book MODEL BASED ENGINE OUT EMISSIONS ANALYSIS FOR A GASOLINE TURBOCHARGED DIRECT INJECTION SPARK IGNITED ENGINE IN ELEVATED HEV CRANKING SPEED

Download or read book MODEL BASED ENGINE OUT EMISSIONS ANALYSIS FOR A GASOLINE TURBOCHARGED DIRECT INJECTION SPARK IGNITED ENGINE IN ELEVATED HEV CRANKING SPEED written by and published by . This book was released on 2021 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract : The in-cylinder trapped air, residual gas, and temperature are important dynamic parameters in Gasoline Direct Injection (GDI) Spark Ignition (SI) engines for fuel and combustion control. However, their real-time prediction for transient engine operations is complicated, especially when concerning variable valve timing. A dynamic cycle-by-cycle control-oriented discrete nonlinear model is proposed and developed in this thesis to estimate the in-cylinder mixture temperature and the mass of trapped air, and residual gas at the point of Intake Valve Closing (IVC). The developed model uses in-cylinder, intake, and exhaust pressures as the primary inputs. The exhaust gas backflow into the cylinder is estimated using a compressible ideal gas model that is designed for engines equipped with Variable Valve Timing (VVT). The designed model is integrated into a rapid-prototype control system for real-time operation. The model's dynamic behavior is validated using an engine dynamometer transient test cycle under real-time conditions. The cold crank-start phase significantly contributes to total engine-out emissions during the US Federal Test Procedure (FTP). The first three engine cycles of the cold crank-start for a Gasoline Direct Injection (GDI) engine in Hybrid Electric Vehicle (HEV) elevated cranking speed is investigated at 20°C. To this end, the impact of the operating strategy on the individual-cylinder engine-out emissions is analyzed quantitatively. For this purpose, a new dynamic method was developed to translate the engine-out emissions concentration measured at the exhaust manifold outlet to mass per cycle per cylinder. The HEV elevated cranking speed provides valve timing control, throttling, and increased fuel injection pressure from the first firings. This study concentrates on analyzing the cranking speed, spark timing, valve timing, and fuel injection strategy, and parameter effects on engine-out emissions. Design of Experiment (DOE) method is used to create a two-step multi-level fractional-factorial test plan with a minimum number of test points to evaluate the significant parameters affecting engine-out emissions during cold crank-start. The split injection parameters, including the Start of the first Injection (SOI), End of the second injection (EOI), and split ratio, in addition to the first cycle additive fuel factor, are investigated. Results show that using the high cranking speed with stabilized low intake Manifold Absolute Pressure (MAP), highly-retarded spark timing, high valve overlap, late intake first injection, 30 CAD bTDC firing EOI, and low first cycle fuel factor reduces the average first three cycles HC emission by 94\%.

Book Control Strategy for Hydrocarbon Emissions in Turbocharged Direct Injection Spark Ignition Engines During Cold start

Download or read book Control Strategy for Hydrocarbon Emissions in Turbocharged Direct Injection Spark Ignition Engines During Cold start written by Kevin David Cedrone and published by . This book was released on 2013 with total page 191 pages. Available in PDF, EPUB and Kindle. Book excerpt: Gasoline consumption and pollutant emissions from transportation are costly and have serious, demonstrated environmental and health impacts. Downsized, turbocharged direct-injection spark ignition (DISI) gasoline engines consume less fuel and achieve superior performance compared with conventional port fuel injected spark ignition (PFI-SI) engines. Although more efficient, turbocharged DISI engines have new emissions challenges during cold start. DISI fuel injection delivers more liquid fuel into the combustion chamber, increasing the emissions of unburned hydrocarbons. The turbocharger slows down activation (warm-up) of the catalytic exhaust after-treatment system. The objective of this research is to find a control strategy that: 1. Accelerates warm-up of the catalyst, and 2. Maintains low emissions of unburned hydrocarbons (UBHCs) during the catalyst warm-up process. This research includes a broad experimental survey of engine behaviour and emission response for a modern turbocharged DISI engine. The study focuses on the idle period during cold-start for which DISI engine emissions are worst. Engine experiments and simulations show that late and slow combustion lead to high exhaust gas temperatures and mass flow rate for fast warm-up. However, late and slow combustion increase the risk of partial-burn misfire. At the misfire limit for each parameter, the following conclusions are drawn: 1. Late ignition timing is the most effective way to increase exhaust enthalpy flow rate for fast catalyst warm-up. 2. By creating a favourable spatial fuel-air mixture stratification, split fuel injection can simultaneously retard and stabilize combustion to improve emissions and prevent partial-burn misfire. 3. Excessive trapped residuals from long valve overlap limit the potential for valve timing to reduce cold-start emissions. 4. Despite their more challenging evaporation characteristics, fuel blends with high ethanol content showed reasonable emissions behaviour and greater tolerance to late combustion than neat gasoline. 5. Higher exhaust back-pressure leads to high exhaust temperature during the exhaust stroke, leading to significantly more post-flame oxidation. 6. Post-flame oxidation in the combustion chamber and exhaust system play a critical role in decreasing the quantity of catalyst-in emissions due to hydrocarbons that escape primary (flame) combustion. A cold start strategy combining late ignition, 15% excess air, and high exhaust backpressure yielded the lowest cumulative hydrocarbon emissions during cold start.

Book Effects of Natural Gas Composition on Ignition Delay Under Diesel Conditions

Download or read book Effects of Natural Gas Composition on Ignition Delay Under Diesel Conditions written by and published by . This book was released on 1993 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt: Effects of variations in natural gas composition on autoignition of natural gas under direct-injection (DI) diesel engine conditions were studied experimentally in a constant-volume combustion vessel and computationally using a chemical kinetic model. Four fuel blends were investigated: pure methane, a capacity weighted mean natural gas, a high ethane content natural gas, and a natural gas with added propane typical of peak shaving conditions. Experimentally measured ignition delays were longest for pure methane and became progressively shorter as ethane and propane concentrations increased. At conditions characteristic of a DI compression ignition natural gas engine at Top Dead Center (CR=23:1, p = 6.8 MPa, T = 1150K), measured ignition delays for the four fuels varied from 1.8 ms for the peak shaving and high ethane gases to 2.7 ms for pure methane. Numerically predicted variations in ignition delay as a function of natural gas composition agreed with these measurements.

Book Ignition Behavior of Gasolines and Surrogate Fuels in Low Temperature Combustion Strategies

Download or read book Ignition Behavior of Gasolines and Surrogate Fuels in Low Temperature Combustion Strategies written by Vickey Kalaskar and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation discusses the results from three different studies aimed at understanding the importance of fuel chemical structure during low temperature combustion (LTC) strategies, like homogeneous charge compression ignition (HCCI) and partially premixed combustion (PPC) employed in internal combustion (IC) engines wherein the focus is on high octane fuels. Boosted intake air operation combined with exhaust gas recirculation, internal as well as external, has become a standard path for expanding the load limits of IC engines employing LTC strategies mentioned above as well as conventional diesel and spark ignition (SI) engines. However, the effects of fuel compositional variation have not been fully explored. The first study focusses on three different fuels, where each of them were evaluated using a single cylinder boosted HCCI engine using negative valve overlap. The three fuels investigated were: a regular grade gasoline (RON = 90.2), 30% ethanol-gasoline blend (E30, RON = 100.3), and 24% iso-butanol-gasoline blend (IB24, RON = 96.6). Detailed sweeps of intake manifold pressure (atmospheric to 250 kPaa), EGR (0 -- 25% EGR), and injection timing were conducted to identify fuel-specific effects. While significant fuel compositional differences existed, the results showed that all these fuels achieved comparable operation with minor changes in operational conditions. Further, it was shown that the available enthalpy from the exhaust would not be sufficient to satisfy the boost requirements at higher load operation by doing an analysis of the required turbocharger efficiency. While the first study concentrated on load expansion of HCCI, it is important to mention that controlling LTC strategies is difficult under low load or idle operating conditions. To ensure stable operation, fuel injection in the negative valve overlap (NVO) is used as one of method of achieving combustion control. However the combustion chemistry under high temperature and fuel rich conditions that exist during the NVO have not been previously explored. The second study focused on examining the products of fuel rich chemistry as a result of fuel injection in the NVO. In this study, a unique six stroke cycle was used to segregate the exhaust from the NVO and to study the chemistry of the range of fuels injected during NVO under low oxygen conditions. The fuels investigated were methanol, ethanol, iso-butanol, and iso-octane. It was observed that the products of reactions under NVO conditions were highly dependent on the injected fuel's structure with iso-octane producing less than 1.5% hydrogen and methanol producing more than 8%. However a weak dependence was observed on NVO duration and initial temperature, indicating that NVO reforming was kinetically limited. Finally, the experimental trends were compared with CHEMKIN (single zone, 0-D model) predictions using multiple kinetic mechanism that were readily available through literature. Due to the simplicity of the model and inadequate information on the fuel injection process, the experimental data was not modeled well with the mechanisms tested. Some of the shortcomings of the 0-D model were probably due to the model ignoring temperature and composition spatial inhomogeneities and evaporative cooling from fuel vaporization.Though the results from the NVO injection and boosted NVO-HCCI studies are enlightening, the fundamentals of the autoignition behavior of gasoline, alcohols, and their mixtures are not entirely understood despite the interest in high octane fuels in compression engines from a point of view of better thermal efficiency. The third study focused on higher octane blends consisting of binary and ternary mixtures of n-heptane and/or iso-octane, and a fuel of interest. These fuels of interest were toluene, ethanol, and iso-butanol. In this study, the autoignition of such blends is studied under lean conditions ([phi] = 0.25) with varying intake pressure (atmospheric to 3 bar, abs) and at a constant intake temperature of 155 °C. The blends consisted of varying percentages of fuels of interest and their research octane number (RON) approximately estimated at 100 and 80. For comparison, neat iso-octane was selected as RON 100 fuel and PRF 80 blend was selected as RON 80 fuel. It was observed that the blends with a higher percentage of n-heptane showed a stronger tendency to autoignite at lower intake pressures. However, as the intake pressure was increased, the non-reactive components, in this case, the higher octane blend components (toluene, ethanol, and iso-butanol), reduced this tendency subsequently delaying the critical compression ratio (CCR) of the blends. The heat release analysis revealed that the higher octane components in the blends reduced the low temperature reactivity of n-heptane and iso-octane. GC-MS and GC-FID analysis of the partially compressed fuel also indicated that the higher octane components did affect the conversion of the more reactive components, n-heptane and iso-octane, into their partially oxidized branched hydrocarbons in the binary/ternary blends, and reduced the overall reactivity which resulted in a delayed CCR at higher intake pressures.

Book Chemical Abstracts

Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2726 pages. Available in PDF, EPUB and Kindle. Book excerpt: