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Book Transition Metal Chemistry Under High Carbon Monoxide Pressure

Download or read book Transition Metal Chemistry Under High Carbon Monoxide Pressure written by and published by . This book was released on 1978 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Transition Metal Chemistry Under High Carbon Monoxide Pressure

Download or read book Transition Metal Chemistry Under High Carbon Monoxide Pressure written by and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This project involves the design and construction of equipment to investigate the infrared spectra of metal carbonyl derivatives in the 1600 to 2200 cm.−1 nu(CO) region at pressures up to 500 atmospheres and temperatures up to 250° followed by the use of this equipment to study the infrared spectra of a variety of transition metal derivatives at elevated pressures of carbon monoxide. The ultimate objective of this work is the discovery of new chemistry leading to the development of new systems which are catalytically active for the conversion of mixtures of carbon monoxide and hydrogen to hydrocarbons in connection with the conversion of coal to hydrocarbon fuels. During the initial period covered by this first progress report a high pressure infrared cell has been designed, constructed, and used for the preliminary investigations of reactions of about 15 transition metal derivatives under elevated pressure of carbon monoxide and hydrogen.

Book Catalyst Characterization

    Book Details:
  • Author : Boris Imelik
  • Publisher : Springer Science & Business Media
  • Release : 2013-06-29
  • ISBN : 1475795890
  • Pages : 720 pages

Download or read book Catalyst Characterization written by Boris Imelik and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 720 pages. Available in PDF, EPUB and Kindle. Book excerpt: to the Fundamental and Applied Catalysis Series Catalysis is important academically and industrially. It plays an essential role in the manufacture of a wide range of products, from gasoline and plastics to fertilizers and herbicides, which would otherwise be unobtainable or prohibitive ly expensive. There are few chemical-or oil-based material items in modern society that do not depend in some way on a catalytic stage in their manufacture. Apart from manufacturing processes, catalysis is finding other important and over-increasing uses; for example, successful applications of catalysis in the control ofpollution and its use in environmental control are certain to in crease in the future. The commercial import an ce of catalysis and the diverse intellectual challenges of catalytic phenomena have stimulated study by a broad spectrum of scientists including chemists, physicists, chemical engineers, and material scientists. Increasing research activity over the years has brought deeper levels of understanding, and these have been associated with a continually growing amount of published material. As recentlyas sixty years ago, Rideal and Taylor could still treat the subject comprehensively in a single volume, but by the 19 50s Emmett required six volumes, and no conventional multivolume text could now cover the whole of catalysis in any depth.

Book Theoretical Aspects of Transition Metal Catalysis

Download or read book Theoretical Aspects of Transition Metal Catalysis written by Gernot Frenking and published by Springer Science & Business Media. This book was released on 2005-06-23 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal catalysis belongs to the most important chemical research areas because a ubiquitous number of chemical reactions are catalyzed by transition metal compounds. Many efforts are being made by industry and academia to find new and more efficient catalysts for chemical processes. Transition metals play a prominent role in catalytic research because they have been proven to show an enormous diversity in lowering the activation barrier for chemical reactions. For many years, the search for new catalysts was carried out by trial and error, which was costly and time consuming. The understanding of the mechanism of the catalytic process is often not very advanced because it is difficult to study the elementary steps of the catalysis with experimental techniques. The development of modern quantum chemical methods for calculating possible intermediates and transition states was a breakthrough in gaining an understanding of the reaction pathways of transition metal catalyzed reactions. This volume, organized into eight chapters written by leading scientists in the field, illustrates the progress made during the last decade. The reader will obtain a deep insight into the present state of quantum chemical research in transition metal catalysis.

Book Dissertation Abstracts International

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2008 with total page 902 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Supported Metals in Catalysis

Download or read book Supported Metals in Catalysis written by James Arthur Anderson and published by World Scientific. This book was released on 2012 with total page 581 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions from experts in supported metal catalysis from both the industry and academia, this book presents the latest developments in characterization and application of supported metals in heterogeneous catalysis. In addition to thorough and updated coverage of the traditional aspects of heterogeneous catalysis such as preparation, characterization and use in well-established technologies such as vehicle emission control, the book also includes emerging areas where supported metal catalysis will make significant contributions to future developments, such as fuel cells and fine chemicals synthesis. The second edition of Supported Metals in Catalysis comes complete with new and updated chapters containing important summaries of research in a rapidly evolving field. Very few other books deal with this highly pertinent subject matter and, as such, it is a must-have for anyone working in the field of heterogeneous catalysis.

Book A Molecular View of Heterogeneous Catalysis

Download or read book A Molecular View of Heterogeneous Catalysis written by E. G. Derouane and published by De Boeck Supérieur. This book was released on 1998-01-21 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains the texts of the conferences presented at the First Francqui Colloquium, held in Brussels on 19 and 20 February 1996 and organised by Professor Eric G. Derouane, 1994 Francqui Prize, Director of the Leverhulme Centre for Innovative Catalysis at the University of Liverpool. These conferences cover broadly the field of molecular heterogeneous catalysis, including catalyst preparation, theory, modelling, new concepts, reactivity, and vistas.

Book Scientific and Technical Aerospace Reports

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1995 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.

Book Kinetics of Multistep Reactions

Download or read book Kinetics of Multistep Reactions written by Friedrich G. Helfferich and published by Elsevier. This book was released on 2004-09-15 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses primarily the engineer in industrial process development, the research chemist in academia and industry, and the graduate student intending to become a reaction engineer. In industry, competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such development should be based on "fundamental" kinetics that reflect the elementary steps of which the reaction consists. The book forges fundamental kinetics into a practical tool by presenting new, effective methods for elucidation of mechanisms and reduction of complexity without unacceptable sacrifice in accuracy: fewer equations (lesser computational load), fewer coefficients (fewer experiment to determine them). For network elucidation, new rules relating network configurations to observable kinetic behaviour allow incorrect networks to be ruled out by whole classes instead of one by one. For modelling, general equations and algorithms are given from which equations for specific networks can be recovered by simple substitutions. The procedures are illustrated with examples of industrial reactions including, among others, paraffin oxidation, ethoxylation, hydroformylation, hydrocyanation, shape-selective catalysis, ethane pyrolysis, styrene polymerization, and ethene oligomerization. Many of the rate equations have not been published before. The expanded edition of the 2001 title, Kinetics of Homogeneous Multistep Reactions includes new chapters on heterogeneous catalysis and periodic and chaotic re-actions; new sections on adsorption, statistical methods, and lumping; and other new detail. - Contains new chapters on heterogeneous catalysis, oscillations and chaos - Includes new sections on statistical methods, lumping adsorption and software and databases - Provides a better understanding of complex reaction mechanisms

Book Energy Research Abstracts

Download or read book Energy Research Abstracts written by and published by . This book was released on 1993 with total page 922 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Advanced Catalysis in Hydrogen Production from Formic Acid and Methanol

Download or read book Advanced Catalysis in Hydrogen Production from Formic Acid and Methanol written by Dmitri A. Bulushev and published by MDPI. This book was released on 2020-06-18 with total page 122 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Special Issue is related to studies of the hydrogen production from formic acid decomposition. It is based on five research papers and two reviews. The reviews discuss the liquid phase formic acid decomposition over bimetallic (PdAg), molecular (Ru, Ir, Fe, Co), and heterogenized molecular catalysts. The gas-phase reaction is studied over highly dispersed Pd, Pt, Au, Cu, and Ni supported catalysts. It is shown that the nature of the catalyst’s support plays an important role for the reaction. Thus, N-doping of the carbon support provides a significant promotional effect. One of the reasons for the high activity of the N-doped catalysts is the formation of single-atom active sites stabilized by pyridinic N species present in the support. It is demonstrated that carbon materials can be N-doped in different ways. It can be performed either directly from N-containing compounds during the carbon synthesis or by a post-synthetic deposition of N-containing compounds on the carbon support with known properties. The Issue could be useful for specialists in catalysis and nanomaterials as well as for graduate students studying chemistry and chemical engineering. The reported results can be applied for development of catalysts for the hydrogen production from different liquid organic hydrogen carriers.

Book Spectroscopy of Transition Metal Ions on Surfaces

Download or read book Spectroscopy of Transition Metal Ions on Surfaces written by Bert M. Weckhuysen and published by Leuven University Press. This book was released on 2000 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical industries are based on catalytic processes as both bulk and fine chemicals are often produced with heterogeneous catalysts. Transition metal ions dispersed on high-surface area inorganic solids are very important catalysts and a full characterization of these materials requires a profound knowledge of the oxidation state, coordination environment and dispersion of the metal ions on the catalyst surface. Such information can only be obtained by using a combination of complementary spectroscopic techniques. 'Spectroscopy of Transition metal ions on Surfaces' serves as an introduction to some of the most important spectroscopic techniques nowadays used for studying the chemistry and catalytic properties of transition metal ions on surfaces. The basic principles and the strengths and weaknesses of continuous wave electron spin resonance, pulsed electron spin resonance, solid state nuclear magnetic resonance, infrared spectroscopy, Raman spectroscopy, diffuse reflectance spectroscopy and X-ray photoelectron spectroscopy are critically reviewed by internationally recognized experts. This gives the reader a solid background for judging literature results and for planning and conducting his/her own experiments. Each chapter closes with several relevant examples mainly from the recent literature. In addition, the use of in situ techniques and chemometrical techniques has been included because of its growing importance in catalyst characterization. As a consequence, the book has been written as a text not only for graduate students, but also for anyone else who is new in the field and wants a recent update. The following scientists have contributed to this textbook: Br.

Book Transition Metal Catalysis in Aerobic Alcohol Oxidation

Download or read book Transition Metal Catalysis in Aerobic Alcohol Oxidation written by Francesca Cardona and published by Royal Society of Chemistry. This book was released on 2015 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with the search for environmentally benign procedures for the oxidation of alcohols and gives an overview of their transition-metal-catalyzed aerobic oxidation.

Book Science and Technology in Catalysis

Download or read book Science and Technology in Catalysis written by Masakazu Anpo and published by Gulf Professional Publishing. This book was released on 2003-07-09 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt: (Selected) -- Plenary Lecures: New Catalysts for Controlled/Living Atom Transfer Radical Polymerization (ATRP; Catalysis and Applications of Gold Nanoparticles -- Oral Presentations: Ionic Liquids as New Solvents and Catalysis for Petrochemical and Refining Processes; High Throughput Experiment on the Investigation of Oxidation Catalysts with Gas Sensor System -- Poster Presentations: Development of a Low-Temperature Dioxin Decomposition Catalyst; Studies on Unique Properties of Polyolefins Prepared with Metallocene Catalyst Systems -- Index.

Book Comprehensive Coordination Chemistry II

Download or read book Comprehensive Coordination Chemistry II written by J. A. McCleverty and published by Newnes. This book was released on 2003-12-03 with total page 11845 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.

Book Organometallic Chemistry

    Book Details:
  • Author : E W Abel
  • Publisher : Royal Society of Chemistry
  • Release : 2007-10-31
  • ISBN : 1847554105
  • Pages : 516 pages

Download or read book Organometallic Chemistry written by E W Abel and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.