Download or read book Ammonia Removal and Recovery from Wastewater Using Natural Zeolite An Integrated System for Regeneration by Air Stripping Followed Ion Exchange written by Qiaosi Deng and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This study revealed that ammonium ion exchange of natural zeolite could be a feasible method of nitrogen removal and recovery from permeate from anaerobic membrane bioreactors (AnMBRs). NaCl concentrations optimized for chemical regeneration in batch experiments did not match those in continuous column tests. Instead, the mass ratio of Na+ to Zeolite-NH4+-N was significant for improving regeneration efficiency in column experiments; this mass ratio was 750 g Na+/g Zeolite-NH4+-N required for regeneration efficiency over 90% in 2 hours at pH 9. ???To decrease the NaCl dose in regeneration of exhausted zeolite, a high pH regeneration method was developed using an NaCl concentration of 10 g/L at pH 12 (the mass of Na+ to Zeolite-NH4+-N of 4.2 ) which achieved a regeneration efficiency about 85%. The recovery of ammonium nitrogen from the exhausted zeolite was assessed with air stripping followed by ammonia collection in an acid scrubber. The effects of shaking and air stripping were investigated in batch tests and the results showed the superiority of air stripping over shaking. Liquid circulation and air flow rates were varied for optimization of ammonia recovery in a continuous zeolite-packed column combined with a regeneration chamber and a stripping column. The liquid circulation rate had no significant effect on either the regeneration efficiency or the ammonia transfer efficiency from ammonium nitrogen to ammonia gas, while the ammonia transfer efficiency significantly increased with the air flow rate.??? Furthermore, the effect of pH on ammonia recovery was tested. Both the regeneration efficiency and the ammonia transfer efficiency were significantly improved with increasing pH. When the pH was increased from 9.5 to 12, the regeneration efficiency increased from 9.2% to 84% and the ammonia transfer efficiency increased from 54% to 92%. The nitrogen recovery process that combines zeolite ammonium exchange and air stripping can decrease chemical costs for regeneration of exhausted zeolite and efficiently collect ammonium nitrogen to be reused as fertilizers. Hence, the integrated nitrogen process can resolve the challenge of nitrogen removal in anaerobic membrane bioreactors treating organic wastewater in sustainable manners.
Download or read book Microbial Technologies in Industrial Wastewater Treatment written by Maulin P. Shah and published by Springer Nature. This book was released on 2023-06-26 with total page 351 pages. Available in PDF, EPUB and Kindle. Book excerpt: Microbial technology using live, naturally occurring microorganisms in industrial wastewater treatment, is the most effective and innovative method to degrade environmental pollutants such as heavy metals, radionuclides, xenobiotic compounds, organic waste, and pesticides, or to prevent their contamination of the environment. The technology includes several techniques such as biostimulation, biogeneration, bioaccumulation, and biosorption. This book describes the limitations and challenges associated with some generally accepted bioremediation strategies and evaluates the possible applications of these corrective strategies to eliminate toxic pollutants from the environment. The environmental contamination by both natural and anthropogenic sources is, nowadays, an international concern. To decontaminate soils, sediments, and water polluted by anthropogenic activities, scientists and technologists have developed various technologies over the years; however, not only do we have to pay a high cost for physical and chemical environmental technologies but also they sometimes are not ecological or safe. Therefore, we have realized the necessity to develop viable technologies that use microbes and plants to avoid these issues. This book is designed for engineers, scientists, and other professionals who are seeking introductory and advanced knowledge of the principles of nanotechnology, and those who work or are interested in the environmental microbiology or bioremediation field.
Download or read book Sewage written by Ivan Zhu and published by BoD – Books on Demand. This book was released on 2018-07-25 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt: Wastewater treatment and sludge disposal are important for protecting receiving rivers, lakes, and other water bodies, and vital for human health. Since excessive discharge may cause eutrophication and deterioration of aquatic systems, the US EPA and other national agencies have set guidelines for wastewater discharge standards. Conventional technologies are well developed and widely applied worldwide for wastewater treatment; however, new ideas and new technologies are gaining additional interest for the sake of water and energy reuse. While water is essential in arid regions, wastewater reuse and recycling have been playing an important role in human life. Although there are no universal standards for industrial and agriculture reuse, balancing wastewater treatment and public health protection presents challenges and opportunities.
Download or read book Wastewater Ammonia Removal by Ion Exchange written by and published by . This book was released on 1972 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Ammonia Removal from Mining Wastewater by Ion Exchange Regenerated by Chlorine Solutions written by Tianguang Zhang and published by . This book was released on 2022 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The mining industry is a significant contributor to the Canadian economy. However, the mining activities can be detrimental to the environment due to the release of pollutants. Ammonia is one of the noxious and toxic contaminants associated with mining, ammonia contamination is created by the oxidizing agent in explosives. The explosives impacted mining wastewater (EIMWW) usually contains ammonia and other metal ions. The ammonia in EIMWW could harm the aquatic environment by the depletion of oxygen and its lethal toxicity to aquatic organisms. Before release to environment, EIMWW needs to be treated with an easy-to-operate method for ammonia removal at the remote mining sites. Ion-exchange (IE) with zeolite is an effective method for ammonia removal that is easy-to-operate, is not significantly impacted by cold temperature or toxicity effects. However, the traditional IE regeneration approach of using high concentration NaCl solutions creates a secondary polluting stream. Chlorine regeneration of ammonia-loaded zeolite appears to be a promising option, an evaluation of this option is the main topic of this thesis. This thesis includes three initiatives. The first is a set of multi-cycle batch loading-regeneration tests to assess the viability of ammonia removal with a commercial zeolite (SIR-600) for the treatment of a synthetic EIMWW (containing total ammonia nitrogen (TAN), K, and Ca) and to examine the performance of different ion-exchange regeneration solutions. The long-term TAN uptake of SIR-600 regenerated using a NaOCl (100 mg free Cl2/L) solution was 0.24 meq/g, which was approximately 20% lower than that after a NaCl regeneration. However, chlorine regeneration is promising because the selectivity of SIR-600 for TAN over Ca and K increased after the chlorine regeneration. To simulate recycling of the NaOCl regenerants, K and Ca were added to the NaOCl solution, it did not substantially affect the subsequent SIR-600's ion uptake. This initiative represents a significant contribution since the earlier studies into chlorine regeneration did not investigate the impact of competing ions. The second initiative addressed concerns regarding the long-term integrity of SIR-600 arising from its exposure to high chlorine concentrations during the regeneration. The five-week long chlorine batch exposure tests with solutions of up to 1000 mg free Cl2/L showed that chlorine exposure did not significantly affect the SIR-600's characteristics in terms of particle size distribution, surface area, FTIR spectra and ion uptake. Thus, SIR-600 has the potential for long-term use in field applications. The final initiative evaluated the feasibility of chlorine regeneration for continuous flow IE column systems used for ammonia removal from a synthetic EIMWW. Continuous flow column systems are important because these are the standard IE units used in full-scale applications. Multi-cycle column loading-regeneration tests were performed to compare the zeolite performance using a NaOCl (1000 ppm as free Cl2) solution with that using a 5% NaCl regeneration. The influence of loading duration was also assessed. The use of 6-hr loading cycles were shown to be preferable to 23-hr loading cycles because it had lower effluent concentrations and they could achieve higher overall TAN mass removals per unit time. After three operational cycles, the SIR-600 had similar TAN uptake performances (0.21 meq/g Vs. 0.21 meq/g) after NaOCl regeneration and after salt (NaCl) regeneration. This is in contrast to the lower TAN uptakes for the NaOCl regeneration in the batch tests, this indicates that batch tests are not always representative of full-scale applications. Compared to NaCl regenerated SIR-600, SIR-600 after NaOCl regeneration had a higher preference for TAN over Ca and K, which makes this type of regeneration very promising. Its only apparent limitation is that the NaOCl regeneration required a longer duration. During the NaOCl regeneration, the main mechanism appears to be the oxidation of ammonia to nitrogen gas and hydrogen ions, however the Na in the NaOCl solution also seems to have a role in the regeneration.
Download or read book Optimization of Ammonia Removal by Ion Exchange Using Clinoptilolite written by John H. Koon and published by . This book was released on 1971 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Zeolite Ammonia Removal from Catfish Pond Waters written by William R. Reynolds and published by . This book was released on 1987 with total page 72 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Selective Ion Exchange Removal of Ammonia from Mining Wastewater written by Zachary Guy Chartrand and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The Canadian mining industry is a multi-billion-dollar effort and one of Canada's largest industrial sectors, creating jobs and security across the country. Certain practices employed within the industry have led to great developments, while increasing productivity and reducing costs. One such practice is the use of nitrogen-based explosives, which have serious environmental repercussions, namely the introduction of large quantities of ammonia into the ecosystem through means of complex blends of wastewaters also containing various metals. These explosive impacted mining wastewaters (EIMWW), must be treated before being introduced into natural waterways as ammonia pose several threats to the environment including the depletion of dissolved oxygen as well as acute toxicity for fish. Newterra, a provider of modular treatment solutions for water, wastewater and groundwater, requested an assessment of the feasibility of a brine-based ion exchange (IE) system for the removal of ammonia from EIMWW, that would be simple to operate and could be deployed in remote areas. The following thesis consists of an evaluation of several IE materials, to determine the feasibility of an IE system for the treatment of real EIMWW. Potassium and calcium were determined to be the problematic ions present in the EIMWW, potentially leading to competitive adsorption issues. This was accomplished by comparing batch IE isotherms for five different IE materials; one natural zeolite (clinoptilolite), one modified clinoptilolite (Resintech SIR-600), and three synthetic resins (Purolite SSTC60, Amberlite IR120 Na and Bojie BC121 H) using both a synthetic single-solute ammonia wastewater and real EIMWW with a total ammonia nitrogen (TAN) concentration of 3.87 meq TAN/L (7̃0 mg/L). The three synthetic resins produced the largest reductions in capacities from the effects of competition and featured the following exchange capacities when treating EIMWW: 0.24±0.03, 0.25±0.01 and 0.22±0.001 meq TAN/g for the Purolite, Amberlite and Bojie resins respectively. These were respective reductions of 87±0.96, 86±0.80 and 87±0.03 % compared to their single-solute TAN solution capacities. The two zeolites featured higher multi-component exchange capacities; 0.32±0.04 meq TAN/g for the clinoptilolite and 0.42±0.01 meq TAN/g for the SIR-600. Furthermore, calcium was found to pose minimal competitive effects and potassium was responsible for the most capacity reduction. Batch regeneration experiments with the clinoptilolite and SIR-600 were undertaken to evaluate the long-term performance of both materials. These consisted of IE isotherms with the EIMWW followed by material regeneration with various regenerants including a 2.5 % KCl/2.5 % NaCl, a 5 % KCl, and a 2.5, 5 and 10 % NaCl solution. Ultimately, the 5 % and 10 % NaCl solutions were the only regenerants to result in an increase of capacity with the 10 % solution featuring higher capacities for both materials. After four exchange/regeneration cycles using a 10 % NaCl brine, the clinoptilolite produced the following capacities: 0.16±0.01 meq Ca2+/g, 0.39±0.06 meq K+/g and 0.34±0.02 meq TAN/g. For the same conditions the Resintech SIR-600 resulted in the following capacities: 0.12±0.01 meq Ca2+/g, 0.52±0.01 meq K+/g and 0.46±0.00 meq TAN/g. Based on the higher TAN exchange performance, column studies were performed with the Resintech SIR-600 to validate the material's performance using a more realistic mode of operation similar to real world applications. This was accomplished by comparing the capacities of the material using both a single solute TAN wastewater as well as the EIMWW and a breakthrough concentration criterion of 0.55 meq TAN/L (1̃0 mg/L). The EIMWW featured breakthrough after only 50 bed volumes, comparatively to the synthetic TAN solution where breakthrough occurred after 274 bed volumes, indicating that competition played a significant role in the performance of the system.
Download or read book Biogas from Waste and Renewable Resources written by Dieter Deublein and published by John Wiley & Sons. This book was released on 2008-04-18 with total page 469 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written as a practical introduction to biogas plant design and operation, this book fills a huge gap by presenting a systematic guide to this emerging technology -- information otherwise only available in poorly intelligible reports by US governmental and other official agencies. The author draws on teaching material from a university course as well as a wide variety of industrial biogas projects he has been involved with, thus combining didactical skill with real-life examples. Alongside biological and technical aspects of biogas generation, this timely work also looks at safety and legal aspects as well as environmental considerations.
Download or read book Zeolites in Industrial Separation and Catalysis written by Santi Kulprathipanja and published by John Wiley & Sons. This book was released on 2010-01-26 with total page 618 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first book to offer a practical overview of zeolites and their commercial applications provides a practical examination of zeolites in three capacities. Edited by a globally recognized and acclaimed leader in the field with contributions from major industry experts, this handbook and ready reference introduces such novel separators as zeolite membranes and mixed matrix membranes. The first part of the book discusses the history and chemistry of zeolites, while the second section focuses on separation processes. The third and final section treats zeolites in the field of catalysis. The three sections are unified by an examination of how the unique properties of zeolites allow them to function in different capacities as an adsorbent, a membrane and as a catalyst, while also discussing their impact within the industry.
Download or read book Natural Zeolites written by David L. Bish and published by ISSN. This book was released on 2001 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reviews in Mineralogy & Geochemistry (RiMG) volumes contain concise advances in theoretical and/or applied mineralogy, crystallography, petrology, and geochemistry.
Download or read book Process Design Manual for Nitrogen Control written by United States. Environmental Protection Agency. Office of Technology Transfer and published by . This book was released on 1975 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Feasibility written by Michael J. Semmens and published by . This book was released on 1976 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Optimization of Ammonia Removal by Ion Exchange Using Clinoptilolite written by John H. Koon and published by . This book was released on 1972 with total page 189 pages. Available in PDF, EPUB and Kindle. Book excerpt: The zeolite ion exchanger clinoptilolite was investigated with the objective of optimizing its application to ammonia removal from wastewaters. The study included multiple cycle pilot plant operations at three municipal sewage treatment plants. Particular attention was given to cation interference with exhaustion performance and with minimum cost regeneration. The ammonia capacity of clinoptilolite was found to be nearly constant over the pH range of 4 to 8, but diminished rapidly outside this range. In regeneration the pH was critical in determining the NaCl requirements, a higher pH favoring lesser amounts of salt. However, at a pH over 12.5 zeolite attrition became excessive and exchanger makeup contributed significantly to operating costs. An average ammonia removal of 95.7% was obtained in demonstration studies on three municipal wastes have an NH3N content of about 20 mg/l. The cost of ammonia removal using clinoptilolite for a 10-mgd plant operating under these conditions was estimated to be $0.082/1000 gal. Ammonia removal down to less than 0.5 mg/l NH3−N is technically feasible, but only with shorter exhaustion runs and greater regenerant requirements.
Download or read book Ammonia Removal from Sirofloc STP Treated Sewage Using Australian Natural Zeolite written by Emma L. Cooney and published by . This book was released on 1996 with total page 117 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Membrane Distillation written by Mohamed Khayet Souhaimi and published by Elsevier. This book was released on 2011-08-12 with total page 493 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modern membrane engineering is critical to the development of process-intensification strategies and to the stimulation of industrial growth. Membrane Distillation (MD) is a broad reference that covers specific information on membranes available and methods for MD membrane preparation and characterization. The book offers an introduction to the terminology and fundamental concepts as well as a historical review of MD development. Commercial membranes used in MD as well as laboratory-made membranes, including emerging membranes, are described in detail and illustrated by a number of clear and instructive schematic drawings and images. A comprehensive review on the development of MD membranes, MD modules, MD membrane characterization, MD configurations, applications in different areas and theoretical models Introduction to the terminology and fundamental concepts associated with MD as well as an historical review of MD development Description of commercial membranes used in MD as well as laboratory-made membranes, including emerging membranes
Download or read book Water Chemistry written by Patrick Brezonik and published by OUP USA. This book was released on 2011-03-22 with total page 809 pages. Available in PDF, EPUB and Kindle. Book excerpt: It emphasizes that both equilibrium and kinetic processes are important in aquatic systems.
