Download or read book Amine Oxides as Oxidizing Agents written by Robert John Rolih and published by . This book was released on 1956 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book MECHANISMS OF THE OXIDATION OF ORGANIC AMINES BY OXYGEN AND BY FREE RADICAL OXIDIZING AGENTS written by and published by . This book was released on 1961 with total page 65 pages. Available in PDF, EPUB and Kindle. Book excerpt: OXIDATION OF Amines by Ozone and other reagents: A study of the oxidation of tributylamine by O3 and MnO2 was made. The oxidation products depended on the reaction conditions. The N-oxide was the main product in some solvents whereas attack of O3 at the C next to N occurred in others. Oxidation of tributylamine with MnO2 gave N-formyldibutylamine; similar oxidation occurs with other trialkylamines. Oxidation of Amines by Monovalent Radicals: Examples of the formation of substituted ethylene diamines by reaction of tertiary amines with t-butoxy radicals are given. Dehydrogenative coupling did not occur when t-butoxy-radicals reacted with dimethylaniline in acetic acid solution. The amine was demethylated, the ejected C linking 2, then 3 aromatic rings together. Evidence for intermediate steps in the over-all reaction was obtained. Reactions of Amines in Aqueous Solution with Polyvalent Metal Oxidants: Argentic compounds are uniquely effective for aliphatic amine oxidations in aqueous media. With aqueous solutions of primary amines, argentic picolinate gave aldehydes or ketones in 10-40% yield, while secondary amines gave yields of 20-90%.
Download or read book Basic Principles of Organic Chemistry written by John D. Roberts and published by . This book was released on 1977 with total page 1596 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.
Download or read book Aromatic Amine Oxides written by Eiji Ochiai and published by . This book was released on 1967 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Selection of Oxidants in Synthesis written by Leland J. Chinn and published by . This book was released on 1971 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book N Oxidation of Drugs written by P. Hlavica and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 487 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Nitroarenes written by Paul C. Howard and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: Prior to 1979, consideration of the problem of the carcinogenicity of the aromatic amine class of chemicals took place primarily in poster sessions and symposia of annual meetings of the American Association for Cancer Research and analogous international associations. In November 1979 the first meeting concerned with the aromatic amines was held in Rockville, Haryland under primary sponsorship of the National Cancer Institute. The proceedings from this meeting were published as Monograph 58 of the Journal of the National Cancel' Institute in 1981. The second meeting in this series, the Second International Conference on N-Substituted Aryl Compounds, was held in March/April of 1982 in Hot Springs, Arkansas. The National Cancer Institute and The National Center for Toxicological Research were the primary sponsors of this meeting. The proceedings were published as Volume 49 of the journal En-vil'onmental Health Perspectives in 1983. The third meeting in this series was held in April of 1987 at the Dearborn Hyatt in Dearborn, Michigan. The principal sponsor of this meeting was the Heyer L. Pre ntis Comprehensive Cancer Center of Metropolitan Detroit. The proceedings, Carcinogenic and Mutagenic Responses to Aromatic Amines and Nitroal'enes, were published in 1987 by Elsevier Press. The fourth meeting was held in Cleveland, Ohio, on July 15-19, 1989.
Download or read book Some Deoxygenation Reactions of Amine Oxides written by Theodore Cohen and published by . This book was released on 1963 with total page 1 pages. Available in PDF, EPUB and Kindle. Book excerpt: This project involves a survey of the reactions of amine oxides with various electrophilic compounds such as anhydrides, esters, alpha, betaunsaturated carbonyl compounds and epoxides. A new oxidation of epoxides by amine oxides or dimethyl sulfoxide was discovered. The reactions of pyridine-N-oxide with dimethyl acetylenedicarboxylate and with naphthoquinone result in self-reactions of the latter compounds. PyridineN-oxide was found to form a 2:1 molecular complex, presumably of the charge-transfer variety with tetrahydroxydinaphthalene. The structure of the ''hydrazone'' of dehydrodinaphthoquinone was reinvestigated. An unusual redox reaction occured when N-acyloxypyridinium halides were pyrolyzed producing pyridine, the carboxylic acid and halogenated organics. Other reactions discussed include: (1) reaction of phenyl acetate with 2- and 4-picoline-N-oxide; (2) phenylacetic anhydride treated with 2- and 4-picolineN-oxide; (3) oxidative decarboxylation of some carboxylic acids by pyridine-N-oxide. (Author).
Download or read book Concerning Amines written by David Ginsburg and published by Elsevier. This book was released on 2016-06-06 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: Concerning Amines
Download or read book Catalytic Aerobic Oxidations written by Esteban Mejía and published by Royal Society of Chemistry. This book was released on 2020-07-14 with total page 349 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidation reactions are an important chemical transformation in both academia and industry. Among the major advances in the field has been the development of catalytic processes, which are not only selective and efficient, but also allow the replacement of common stoichiometric oxidants with molecular oxygen, ideally from air at atmospheric pressure. This results in processes with higher atom efficiency, where water is the only side product in line with the principles of green chemistry. Focusing on the use of molecular oxygen as the terminal oxidant, this book covers recent advances in both heterogeneous and homogeneous systems, with and without metals and on the “taming” of the highly reactive oxygen gas by use of micro-flow reactors and membranes. A useful reference for industrial and academic chemists working on oxidation processes, as well as green chemists.
Download or read book Kirk Othmer Concise Encyclopedia of Chemical Technology 2 Volume Set written by Kirk-Othmer and published by John Wiley & Sons. This book was released on 2007-07-16 with total page 2762 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is an easily-accessible two-volume encyclopedia summarizing all the articles in the main volumes Kirk-Othmer Encyclopedia of Chemical Technology, Fifth Edition organized alphabetically. Written by prominent scholars from industry, academia, and research institutions, the Encyclopedia presents a wide scope of articles on chemical substances, properties, manufacturing, and uses; on industrial processes, unit operations in chemical engineering; and on fundamentals and scientific subjects related to the field.
Download or read book The Complete Book on Emulsifiers with Uses Formulae and Processes 2nd Revised Edition written by NPCS Board of Consultants & Engineers and published by NIIR PROJECT CONSULTANCY SERVICES. This book was released on 2014-01-01 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emulsifier is an organic compound that encompasses in the same molecule two dissimilar structural groups e.g. water soluble and a water insoluble moiety. It is the ingredient which binds the water and oil in a cream or lotion together permanently. The composition, solubility properties, location and relative sizes of these dissimilar groups in relation to the overall molecular configuration determine the surface activity of a compound. Emulsifiers are classified on the basis of their hydrophilic or solubilizing groups in to four categories anionic, non ionic, cationics and amphoterics. Emulsifier is utilized in various industries; agriculture, building and construction, elastomers & plastics, food & beverages, industrial cleaning, leather, metals, paper, textiles paints & protective coatings etc. An emulsion is an ideal formulation for the administration. The emulsion form allows uniform application of a small amount of active ingredient on the surface of the skin. Some of the important emulsions in different field are pharmaceutical emulsions, rosin & rubber emulsion, textile emulsions, pesticide emulsions, food emulsions, emulsion in paint industry, emulsion in polish industry, leather & paper treatment emulsions etc. Various cosmetics creams, such as moisturizers, contain emulsifiers. Lighter, less greasy feeling creams are oil in water emulsions; heavier creams used to treat rough skin are water in oil emulsions, with oil as the main ingredient. Liquid soaps, toothpastes and other body care products also contain emulsifiers. Emulsifiers have the ability to optimize the concentration of certain nutrients in an emulsion. For example, in hair conditioners, some conditioning agents can damage hair if not properly diluted in the solution. Emulsifiers are among the most frequently used types of food additives. Emulsifiers can help to make a food appealing. Emulsifiers have a big effect on the structure and texture of many foods. Increasing demand for low fat food among health conscious consumers is gradually driving the market for emulsifiers. Besides stabilizing emulsions, emulsifiers derived from non hydrogenated fats help in maintaining sensory characteristics of food such as texture, flavor, and taste that are often lost due to fat reduction. This characteristic of making healthier products similar in taste to fat containing versions has enabled emulsifiers in gaining widespread acceptance in the market. The global food industry is also witnessing increase in demand for multipurpose emulsifiers that perform functions of both stabilization and emulsification. Some of the fundamentals of the book are characteristics and application of emulsifiers, wetting and detergent structures in emulsifier, effect of surfactant on the properties of solutions, wetting characteristics of emulsifiers, formulated emulsifiers, non surfactant functional additives, inert fillers, functional surfactant additives, uses of emulsifiers, household and personal products, industrial uses of emulsifier, anionic surfactants, non ionic surfactants, cationic, amphoteric and enzyme, alkylolamides, vinylarene polymers, alkyl sulfates, ethoxylation processes, application of emulsifiers, etc. The present book contains manufacturing processes of various types of emulsifiers which have applications in different industries. This is a resourceful book for scientists, technologists, entrepreneurs and ingredients suppliers. 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Download or read book Modern Oxidation Methods written by Jan-Erling Bäckvall and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: At the very latest, with the award of the 2001 Nobel Prize for work on asymmetric oxidation, there has been a need for a comprehensive book on such methods. Edited by J.-E. Backvall, one of the world's leaders in the field, this book fills that gap by covering the topic, from classical to green chemistry methods. He has put together a plethora of well-established authors from all over the world who cover every important aspect in high-quality contributions -- whether aerobic oxidation or transition metal-catalyzed epoxidation of alkenes. By providing an overview of this huge topic, this book represents an unparalleled aid for any chemist working in the field. Chapters include: Recent Developments in the Osmium-Catalyzed Dihydroxylation of Olefins Transition Metal-Catalyzed Epoxidation of Alkenes Organocatalytic Oxidation - Ketone-Catalyzed Asymmetric Epoxidation of Olefins Modern Oxidation of Alcohols using environmentally Benign Oxidants Aerobic Oxidations and Related Reactions Catalyzed by N-Hydroxyphthalimide Ruthenium-Catalyzed Oxidation of Alkenes, Alcohols, Amines, Amides, b-Lactams, Phenols, and Hydrocarbons Selective Oxidations of Sulfides and Amines Liquid Phase Oxidation Reactions Catalyzed by Polyoxometalates Oxidation of Carbonyl Compounds Mn-catalysed Oxidation with Hydrogen Peroxide
Download or read book Spot Tests in Inorganic Analysis written by F. Feigl and published by Elsevier. This book was released on 2012-12-02 with total page 700 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many years have passed since the last edition of the present book was published. The discovery during this period of many new reagents has resulted in a vast accumulation of data on their application and made this completely revised edition necessary. Numerous new tests and various new chapters have been added. Chapters 3,4 and 5 of the fifth edition have been combined into one chapter, which is divided into sections devoted to the elements. These sections are arranged in alphabetical order to make for easier location of information on a given element. To further improve the usefulness of the volume, a reference list has been provided for each sub-section followed by a biography of the appropriate quantitative methods.
Download or read book Catalytic Oxidations with Hydrogen Peroxide as Oxidant written by G. Strukul and published by Springer Science & Business Media. This book was released on 2013-03-14 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen peroxide is a chemical that is becoming increasingly fashionable as an oxidant, both in industry and in academia and whose production is expected to increase significantly in the next few years. This growth in interest is largely due to environmental considerations related to the clean nature of hydrogen peroxide as an oxidant, its by-product being only water. To date this chemical has largely been employed as a non-selective oxidant in operations like the bleaching of paper, cellulose and textiles, or in the formulation of detergents, and only to a minimal extent in the manufacture of organic chemicals. This book has been organized to cover the different aspects of the chemistry of hydrogen peroxide. The various chapters into which the book is divided have been written critically by the authors with the general aim of stimulating new ideas and emphasizing those aspects that are likely to lead to new developments in organic synthesis in the coming future.
Download or read book Handbook of Detergents Part A written by Guy Broze and published by CRC Press. This book was released on 1999-04-14 with total page 814 pages. Available in PDF, EPUB and Kindle. Book excerpt: Part A of this handbook describes the raw materials and potential interactions of detergent products before, during and after use, focusing on the development and mechanisms of action of cleaning components. The text presents the basic physiochemical concepts necessary to formulate new, safer and more effective detergent products.
Download or read book Heteroatom Manipulation written by E. Winterfeldt and published by Elsevier. This book was released on 1992-09-08 with total page 1217 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this volume, those functional groups containing heteroatoms that have gained importance in organic synthesis are dealt with in detail. The introduction of these various groups and their relevant transformations are described and the various aspects of chemoselectivity, regioselectivity and stereoselectivity are discussed. After a compilation of the synthetically most useful substitution processes, there is a series of chapters on the various types of acylation reactions and in this context the different methods of acyl group activation are discussed. As functional group protection is of very general importance for organic synthesis, a corresponding chapter is included. This is followed by a section on the preparation of carbonyl derivatives and the most important transformations and rearrangements of functional group derivatives. At the end of the volume one finds chapters on all types of elimination reactions and related thermal reactions together with a survey on fragmentation processes in organic synthesis.
