Download or read book Advances in Metal and Semiconductor Clusters written by and published by . This book was released on 1993 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Advances in Metal and Semiconductor Clusters written by M.A. Duncan and published by Elsevier. This book was released on 1998-07-27 with total page 401 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cluster Materials is the fourth volume of the highly successful series Advances in Metal and Semiconductor Clusters. In this volume the focus is on the properties of clusters which determine their potential applications as new materials. Metal and semiconductor clusters have been proposed as precursors for materials or as actual materials since the earliest days of cluster research. In the last few years, a variety of techniques have made it possible to produce clusters in sizes varying from a few atoms up to several thousand atoms. While some measurements are performed in the gas phase on non-isolated clusters, many cluster materials can now be isolated in macroscopic quantities and more convenient studies of their properties become possible. In this volume the authors focus on measurement of optical, electronic, magnetic, chemical and mechanical properties of clusters or of cluster assemblies. All of these properties must fall into acceptable ranges of behaviour before useful materials composed of clusters can be put into practical applications. As evidenced by the various work described here, the realisation of practical products based on cluster materials seems to be approaching rapidly.
Download or read book Advances in Metal and Semiconductor Clusters written by M.A. Duncan and published by Elsevier. This book was released on 2001-07-10 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: In previous volumes in this series, Advances in Metal and Semiconductor Clusters, the focus has been on atomic clusters of metals, semiconductors and carbon. Fundamental gas phase studies have been surveyed, and most recently scientists have explored new materials which can be produced from clusters or cluster precursors. In this latest volume, the focus shifts to clusters composed primarily of non-metal molecules or atoms which have one or more metal atoms seeded into the cluster as an impurity. These clusters provide model systems for metal ion solvation processes and metal-ligand interactions. Metal-ligand bonding underlies the vast fields of organometallic chemistry, transition metal chemistry and homogeneous catalysis. Catalytic activity, ligand displacement reactions and photochemical activity depend on the specific details of metal-ligand bonding. Likewise, metal ions are ubiquitous in chemistry and biology and weaker electrostatic interactions play a leading role in their function. In solution, metals exist in different charge states depending on the conditions, and the solvation environment strongly influences their chemistry. Many enzymes have metal ions at their active sites, and electrostatic interactions influence the selectivity for metal ion transport through cell membranes. Metal ions (e.g., Mg+, Ca+) are deposited into the earth's atmosphere by meteor ablation, resulting in a rich variety of atmospheric chemistry. Similarly, metal ions ( Mg+) have been observed in planetary atmospheres and in the impact of the comet Shoemaker-Levy 9 on Jupiter. In various circumstances, the electrostatic interactions of metal ions determine the outcome of significant chemistry. Cluster chemistry has made significant contributions to the understanding of these stronger metal ligand interactions and weaker metal ion solvation interactions. In this volume, the authors explore a variety of work in these general areas, where new cluster science techniques in the gas phase have made it possible to synthesize new kinds of complexes with metals and to measure their properties in detail.
Download or read book Advances in Metal and Semiconductor Clusters written by and published by . This book was released on 1998 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Spectroscopy and Structure written by M.A. Duncan and published by Elsevier. This book was released on 1996-01-04 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spectroscopy and Structure
Download or read book Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials written by J.F. Harrod and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the ten years since the scientific rationale for the design, synthesis and application of inorganic and organometallic polymers (IOPs) was first conceptualised, we have witnessed the first tentative exploration of IOPs as precursors to new materials, with efforts focusing on the design and synthesis of novel ceramic precursors. Developing expertise led to precursor studies combined with the characterisation of the transformation processes that occur when IOPs are converted to ceramic materials. Now at maturity, the science presented in this volume reveals the polymer precursor approach to materials synthesis together with examples of processing ceramic shapes for a range of mechanical properties, the development of sophisticated, noninvasive analytical techniques, and IOP design rationales relying on well-defined processing-property relationships. The production of multifunctional IOPs is described, providing ion conductivity, gas sensing, bioactivity, magnetic properties, etc., combined with processability. The existence of well-defined IOPs and the exquisite control that can be exerted on sol-gel systems now provide access to such a variety of mixed organic-organometallic and/or inorganic hybrid systems that their exploitation is likely to develop into an entirely new field of materials chemistry. Future exciting avenues of research are also being opened up with the advent of buckyballs, Met-Cars, dopable preceramics, rigid-rod organometallics, and molecular tinkertoys.
Download or read book Advances in Photochemistry written by Douglas C. Neckers and published by John Wiley & Sons. This book was released on 2009-09-24 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: Setting the pace for progress and innovation . . . ADVANCES IN PHOTOCHEMISTRY More than a simple survey of the current literature, Advances in Photochemistry offers critical evaluations written by internationally recognized experts. These pioneering scientists offer unique and varied points of view of the existing data. Their articles are challenging as well as provocative and are intended to stimulate discussion, promote further research, and encourage new developments in the field. In this volume Present Status of the Photoisomerization About Ethylenic Bonds TATSUO ARAI AND KATSUMI TOKUMARU Cooling of a Dye Solution by Anti-Stokes Fluorescence CHRISTOPH ZANDER AND KARL HEINZ DREXHAGE Atmospheric Photochemistry of Alternative Halocarbons JOSEPH S. FRANCISCO AND M. MATTI MARICQ Photochemistry and Photoelectrochemistry of Quantized Matter: Properties of Semiconductor Nanoparticles in Solution and Thin-Film Electrodes HORST WELLER AND ALEXANDER EYCHMULLER Artificial Photosynthetic Transformations Through Biocatalysis and Biomimetic Systems ITAMAR WILLNER AND BILHA WILLNER
Download or read book Encyclopedia of Chemical Physics and Physical Chemistry written by John H. Moore and published by CRC Press. This book was released on 2023-07-03 with total page 715 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Encyclopedia of Physical Chemistry and Chemical Physics introduces possibly unfamiliar areas, explains important experimental and computational techniques, and describes modern endeavors. The encyclopedia quickly provides the basics, defines the scope of each subdiscipline, and indicates where to go for a more complete and detailed explanation. Particular attention has been paid to symbols and abbreviations to make this a user-friendly encyclopedia. Care has been taken to ensure that the reading level is suitable for the trained chemist or physicist. The encyclopedia is divided in three major sections: FUNDAMENTALS: the mechanics of atoms and molecules and their interactions, the macroscopic and statistical description of systems at equilibrium, and the basic ways of treating reacting systems. The contributions in this section assume a somewhat less sophisticated audience than the two subsequent sections. At least a portion of each article inevitably covers material that might also be found in a modern, undergraduate physical chemistry text. METHODS: the instrumentation and fundamental theory employed in the major spectroscopic techniques, the experimental means for characterizing materials, the instrumentation and basic theory employed in the study of chemical kinetics, and the computational techniques used to predict the static and dynamic properties of materials. APPLICATIONS: specific topics of current interest and intensive research. For the practicing physicist or chemist, this encyclopedia is the place to start when confronted with a new problem or when the techniques of an unfamiliar area might be exploited. For a graduate student in chemistry or physics, the encyclopedia gives a synopsis of the basics and an overview of the range of activities in which physical principles are applied to chemical problems. It will lead any of these groups to the salient points of a new field as rapidly as possible and gives pointers as to where to read about the topic in more detail.
Download or read book Superatoms written by Puru Jena and published by John Wiley & Sons. This book was released on 2021-11-30 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explore the theory and applications of superatomic clusters and cluster assembled materials Superatoms: Principles, Synthesis and Applications delivers an insightful and exciting exploration of an emerging subfield in cluster science, superatomic clusters and cluster assembled materials. The book presents discussions of the fundamentals of superatom chemistry and their application in catalysis, energy, materials science, and biomedical sciences. Readers will discover the foundational significance of superatoms in science and technology and learn how they can serve as the building blocks of tailored materials, promising to usher in a new era in materials science. The book covers topics as varied as the thermal and thermoelectric properties of cluster-based materials and clusters for CO2 activation and conversion, before concluding with an incisive discussion of trends and directions likely to dominate the subject of superatoms in the coming years. Readers will also benefit from the inclusion of: A thorough introduction to the rational design of superatoms using electron-counting rules Explorations of superhalogens, endohedrally doped superatoms and assemblies, and magnetic superatoms A practical discussion of atomically precise synthesis of chemically modified superatoms A concise treatment of superatoms as the building blocks of 2D materials, as well as superatom-based ferroelectrics and cluster-based materials for energy harvesting and storage Perfect for academic researchers and industrial scientists working in cluster science, energy materials, thermoelectrics, 2D materials, and CO2 conversion, Superatoms: Principles, Synthesis and Applications will also earn a place in the libraries of interested professionals in chemistry, physics, materials science, and nanoscience.
Download or read book Physics and Chemistry of Finite Systems From Clusters to Crystals written by Peru Jena and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 1414 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent innovations in experimental techniques such as molecular and cluster beam epitaxy, supersonic jet expansion, matrix isolation and chemical synthesis are increasingly enabling researchers to produce materials by design and with atomic dimension. These materials constrained by sire, shape, and symmetry range from clusters containing as few as two atoms to nanoscale materials consisting of thousands of atoms. They possess unique structuraI, electronic, magnetic and optical properties that depend strongly on their size and geometry. The availability of these materials raises many fundamental questions as weIl as technological possibilities. From the academic viewpoint, the most pertinent question concerns the evolution of the atomic and electronic structure of the system as it grows from micro clusters to crystals. At what stage, for example, does the cluster look as if it is a fragment of the corresponding crystal. How do electrons forming bonds in micro-clusters transform to bands in solids? How do the size dependent properties change from discrete quantum conditions, as in clusters, to boundary constrained bulk conditions, as in nanoscale materials, to bulk conditions insensitive to boundaries? How do the criteria of classification have to be changed as one goes from one size domain to another? Potential for high technological applications also seem to be endless. Clusters of otherwise non-magnetic materials exhibit magnetic behavior when constrained by size, shape, and dimension. NanoscaIe metal particles exhibit non-linear opticaI properties and increased mechanical strength. SimiIarly, materials made from nanoscale ceramic particIes possess plastic behavior.
Download or read book Concepts of Mathematical Physics in Chemistry A Tribute to Frank E Harris written by and published by Academic Press. This book was released on 2016-01-14 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: Concepts of Mathematical Physics in Chemistry: A Tribute to Frank E. Harris - Part B, presents a series of articles concerning important topics in quantum chemistry, including surveys of current topics in this rapidly-developing field that has emerged at the cross section of the historically established areas of mathematics, physics, chemistry, and biology. Presents surveys of current topics in this rapidly-developing field that has emerged at the cross section of the historically established areas of mathematics, physics, chemistry, and biology Features detailed reviews written by leading international researchers
Download or read book Advanced Zeolite Science and Applications written by Michael Stöcker and published by Elsevier. This book was released on 1994-07-19 with total page 715 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites and related microporous materials are used in oil processing and in the fine and petrochemical industries on a large scale. New applications of zeolites contribute to environmentally friendly processes and refined zeolites such as catalytic zeolite membranes and zeolites containing exhaust-pipe reactors are being introduced. Recent diversity in zeolite research has been fueled by the increase in number of microporous materials and the combination with interfacing science areas. The possibility to accommodate ions, large molecules or nanostructures in the crystalline matrix has been explored and the performance of electronic, acoustic and photonic modified response of the materials has been tested. This volume provides up-to-date information on new zeolite and related materials and composites, their applications, testing of new processes and techniques, and promising laboratory results as well. A vast amount of work from a fundamental aspect is incorporated. In particular, the combination of science and application offers useful information for readers interested in molecular sieves.
Download or read book Photoionization and Photodetachment written by Cheuk-Yiu Ng and published by World Scientific. This book was released on 2000-06-30 with total page 1416 pages. Available in PDF, EPUB and Kindle. Book excerpt: Owing to the advances of vacuum ultraviolet and ultrafast lasers and third generation synchrotron sources, the research on photoionization, photoelectrons, and photodetachment has gained much vitality in recent years. These new light sources, together with ingenious experimental techniques, such as the coincidence imaging, molecular beam, pulsed field ionization photoelectron, mass-analyzed threshold ion, and pulsed field ion pair schemes, have allowed spectroscopic, dynamic, and energetic studies of gaseous species to a new level of detail and accuracy. Profitable applications of these methods to liquids are emerging. This invaluable two-volume review consists of twenty-two chapters, focusing on recent developments in photoionization and photodetachment studies of atoms; molecules, transient species, clusters, and liquids. Contents:Part I:Velocity Mapping Studies of Molecular Photodissociation and Photoionization Dynamics (D H Parker)Coherent Control of Photodissociation and Photoionization (R J Gordon & L-C Zhu)Non-Adiabatic Dynamics Studied by Femtosecond Time-Resolved Photoelectron Spectroscopy (C C Hayden & A Stolow)Femtosecond Time-Resolved Photoelectron Spectroscopy of Molecules and Clusters by Photoion-Photoelectron Coincidence Detection (W Radloff) The Renner-Teller Effect and the Role of Electronically Degenerate States in Molecular Ions (P Rosmus & G Chambaud)Zero-Kinetic-Energy Photoelectron Spectroscopic Studies of Aromatic-Argon van der Waals Complexes (K Kimura)Mass-Analyzed Cation Spectroscopy Using Rydberg States: MATI and PIRI (P M Johnson)High Resolution Threshold Photoelectron and Photoelectron-Photoion Coincidence Spectroscopy Using Synchrotron Radiation (Y Morioka)Advances in Photoionization and Photoelectron Studies Using Third Generation Synchrotron Radiation and UV/VUV Lasers (C-Y Ng)Unimolecular Reactions of Molecular Ions and Cluster Ions — From Thermal Towards State-Selective Experiments (K-M Weitzel)Laser Two-Photon Ionization in Solution and on Surface in Ambient Air: Investigations Through Conductivity Measurement (T Ogawa)Photoelectron Spectroscopy at Liquid Surfaces (M Faubel)Part II:Dissociative Electron-Ion Recombination Studies Using Ion Synchrotrons (M Larsson)Dissociative Photodetachment Studies of Transient Molecules by Coincidence Techniques (R E Continetti)Mass Selected Anion-Zero Kinetic Energy Photoelectron Spectroscopy (U Boesl et al.)Photodetachment Photoelectron Spectroscopy of Transition Metal Oxide Species (L-S Wang)Detachment Processes for Molecular Anions (J Simons)Competition Between Autoionization and Predissociation in Molecular Rydberg States (S T Pratt)Electron Capture Processes by Free and Bound Molecules (E Illenberger)Visualization of Electron Correlations in Doubly and Triply Excited States of Atoms (C D Lin & T Morishita)High-Resolution Angle-Resolved Studies of Atoms and Molecules Using Advanced Electron Spectroscopy at the ALS (N Berrah)X-Ray Scattering and Fluorescence from Atoms and Molecules (S H Southworth et al.) Readership: Researchers in physical chemistry, and atomic and molecular physics. Keywords:Reviews: “These volumes will occupy a prominent place on the bookshelf of virtually every practitioner in this field, and the various sets of chapters will be the subject of many student presentations to their research groups.” Journal of the American Chemical Society
Download or read book Optical Properties of Nanoparticle Systems written by Michael Quinten and published by John Wiley & Sons. This book was released on 2010-11-29 with total page 507 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the gap for a description of the optical properties of small particles with sizes less than 1000 nm and to provide a comprehensive overview on the spectral behavior of nanoparticulate matter, this is the most up-to-date reference on the optical physics of nanoparticle systems. The author, an expert in the field with both academic and industrial experience, concentrates on the linear optical properties, elastic light scattering and absorption of single nanoparticles and on reflectance and transmittance of nanoparticle matter.
Download or read book Spectroscopy and Dynamics written by Michael A. Duncan and published by Jai Press. This book was released on 1993 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Atomic and Nano Scale Materials for Advanced Energy Conversion 2 Volumes written by Zongyou Yin and published by John Wiley & Sons. This book was released on 2022-04-18 with total page 887 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomic and Nano Scale Materials for Advanced Energy Conversion Discover the latest advancements in energy conversion technologies used to develop modern sustainable energy techniques In Atomic and Nano Scale Materials for Advanced Energy Conversion, expert interdisciplinary researcher Dr. Zongyou Yin delivers a comprehensive overview of nano-to-atomic scale materials science, the development of advanced electrochemical, photochemical, photoelectrochemical, and photovoltaic energy conversion strategies, and the applications for sustainable water splitting and other technologies. The book offers readers cutting-edge information of two-dimensional nano, mixed-dimensional nano, nano rare earth, clusters, and single atoms. It constructively evaluates emerging nano-to-atomic scale energy conversion technologies for academic research and development (R&D) researchers and industrial technique consultants and engineers. The author sets out a systematic analysis of recent energy-conversion science, covering topics like adaptable manufacturing of Van der Waals heterojunctions, mixed-dimensional junctions, tandem structures, and superlattices. He also discusses function-oriented engineering in polymorphic phases, photon absorption, excitons-charges conversion, non-noble plasmonics, and solid-liquid-gas interactions. Readers will also benefit from: A thorough introduction to emerging nanomaterials for energy conversion, including electrochemical, photochemical, photoelectrochemical, and photovoltaic energy conversion An exploration of clusters for energy conversion, including electrochemical, photochemical, and photoelectrochemical clusters Practical discussions of single atoms for energy conversion in electrochemical, photochemical, and photoelectrochemical energy conversion technologies A thorough analysis of future perspectives and directions in advanced energy conversion technology Perfect for materials scientists, photochemists, electrochemists, and inorganic chemists, Atomic and Nano Scale Materials for Advanced Energy Conversion is also a must-read resource for catalytic chemists interested in the intersection of advanced chemistry and physics in energy conversion technologies.
Download or read book Gas Phase Inorganic Chemistry written by David H. Russell and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of gas phase inorganic ion chemistry is relatively new; the early studies date back approximately twenty years, but there has been intense interest and development in the field in the last ten years. As with much of modern chemistry, the growth in gas phase inorganic ion chemistry can be traced to the development of instrumentation and new experimental methods. Studies in this area require sophisticated instruments and sample introduc tion/ ionization methods, and often these processes are complicated by the need for state-selecting (or collisionally stabilizing) the reactive species in order to assign the chemistry unequivocally. At the present level of experimental development, a wide range of experiments on diverse ionic systems are possible and many detailed aspects of the chemistry can be studied. Gas Phase Inorganic Chemistry focuses on the reactions of metal ions and metal clusters, and on the study of these species using the available modern spectroscopic methods. Three of the twelve chapters cover the chemistry of ionic monometal transition metal ions and the chemistry of these species with small diatomics and model organics. Two of the chapters focus on the studies of the chemical and physical properties of (primarily) transition metal clusters, and these chapters review experimental methods and capabilities. Two chapters also deal with the chemistry of transition metal carbonyl clusters, and these chapters address issues important to cluster growth and activation as well as the characterization of such species.
