Download or read book Adsorption of Perchlorate by Granular Media written by Nicholas Ross Anton and published by . This book was released on 2005 with total page 382 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Adsorption and Desorption of Perchlorate on Granular Activated Carbon written by Mukta Patil and published by . This book was released on 2008 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Perchlorate Adsorption Onto Granular Activated Carbon and Subsequent Desoprtion Via Sodium Borohydride written by Jerome James Alessandro Santos and published by . This book was released on 2008 with total page 118 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Evaluation of Tailored Granular Activated Carbon to Remove Perchlorate in the Presence of Oxyanions written by Judodine Patterson and published by . This book was released on 2009 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Perchlorate written by Baohua Gu and published by Springer Science & Business Media. This book was released on 2006-07-02 with total page 413 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a detailed description of perchlorate chemistry and recent advances in innovative remediation technologies for perchlorate contamination and their pros and cons Additionally, the first book to describe the natural occurrence of perchlorate and its unique isotopic signatures for environmental forensics and its detection in the environment, particularly the real-time analysis using surface enhanced Raman spectroscopy
Download or read book Aquananotechnology written by David E. Reisner and published by CRC Press. This book was released on 2014-09-24 with total page 887 pages. Available in PDF, EPUB and Kindle. Book excerpt: The world's fresh water supplies are dwindling rapidly-even wastewater is now considered an asset. By 2025, most of the world's population will be facing serious water stresses and shortages. Aquananotechnology: Global Prospects breaks new ground with its informative and innovative introduction of the application of nanotechnology to the remediatio
Download or read book Treatability of Perchlorate in Groundwater Using Ion Exchange Technology Phase II written by L. Aldridge and published by IWA Publishing (International Water Assoc). This book was released on 2005-04-30 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since 1997, several perchlorate treatment technologies have proven to be technically feasible at drinking-water treatment scale: biological reduction, ion exchange, reverse osmosis (RO) membranes, and granular activated carbon (GAC). The objectives of this project were to demonstrate the long-term performance of conventional ion-exchange technology for perchlorate removal and evaluate three disparate alternatives (chemical, biological, electrolytic) for brine treatment and reuse. This project evaluated three fundamentally different brine treatment and reuse processes. The first process, the biological brine treatment system, operated as a sequencing batch reactor (SBR). Spent 3 percent (0.5 N NaCl) brine was introduced to the nitrate and perchlorate degrading culture in the reactor and acetic acid was supplied to this culture as an electron donor for the reduction process. Once the nitrate and perchlorate were biodegraded, the mixture was settled, filtered, and amended with chloride before its reuse as regenerant solution. The second process, the physical/chemical brine treatment system, employed a high-pressure and high-temperature catalytic process to reduce the nitrate and perchlorate in the spent brine. After the process, the treated brine was ready for reuse without subsequent treatment. The system used a stoichiometric dose of a chemical reductant (ammonia) based on the measured concentrations of nitrate and perchlorate in the spent brine. The last process, a simple bipolar electrochemical cell, electrolytically reduced the perchlorate and/or nitrate present in the spent ion exchange brine. Once reduced, the brine could be immediately reused. This process did not require the addition of an electron donor as with the biological process, or a reductant as with the physical/chemical treatment process.
Download or read book Perchlorate in the Environment written by Edward Todd Urbansky and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 299 pages. Available in PDF, EPUB and Kindle. Book excerpt: Based on a symposium sponsored by the Environmental Division of the American Chemical Society, Perchlorate in the Environment is the first comprehensive book to address perchlorate as a potable water contaminant. The two main topics are: analytical chemistry (focusing on ion chromatography and electrospray ionization mass spectrometry), and treatment or remediation. Also included are topics such as ion exchange, phytoremediation, bacterial reduction of perchlorate, bioreactors, and in situ bioremediation. To provide complete coverage, background chapters on fundamental chemistry, toxicology, and reulatory issues are also included. The authors are environmental consultants, government researchers, industry experts, and university professors from a wide array of disciplines.
Download or read book Tailoring and Regeneration of Granular Activated Carbon for Perchlorate Removal written by Weifang Chen and published by . This book was released on 2005 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: Perchlorate contaminates waters in 15 US states that 15 million American could otherwise drink. Although, conventional granular activated carbon (GAC) has a very limited capacity for removing perchlorate, it was found that ammonia thermal tailoring could enhance its bed life.
Download or read book Activated Carbon for Water and Wastewater Treatment written by Ferhan Cecen and published by John Wiley & Sons. This book was released on 2011-09-19 with total page 409 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph provides comprehensive coverage of technologies which integrate adsorption and biological processes in water and wastewater treatment. The authors provide both an introduction to the topic as well as a detailed discussion of theoretical and practical considerations. After a review of the basics involved in the chemistry, biology and technology of integrated adsorption and biological removal, they discuss the setup of pilot- and full-scale treatment facilities, covering powdered as well as granular activated carbon. They elucidate the factors that influence the successful operation of integrated systems. Their discussion on integrated systems expands from the effects of environmental to the removal of various pollutants, to regeneration of activated carbon, and to the analysis of such systems in mathematical terms. The authors conclude with a look at future needs for research and develoment. A truly valuable resource for environmental engineers, environmental and water chemists, as well as professionals working in water and wastewater treatment.
Download or read book Removal of Perchlorate in Ammunition Wastewater by Zero valent Iron and Perchlorate Respiring Bacteria written by Se Chang Ahn and published by ProQuest. This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Perchlorate has recently received a great deal of attention due to high concentrations found in groundwaters and surface waters. The US Army and DoD facilities generate ammunition wastewater containing perchlorate (ClO 4 - ), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and 2,4-dinitroanisole (DNAN) (i.e. PAX-21 wastewater) from munitions manufacturing and demilitarization processes. Perchlorate is known to affect human health by interfering with the uptake of iodide into the thyroid glands. The US EPA recently set the perchlorate reference dose to 0.0007 mg/kg/day which corresponds to a drinking water equivalent level of 24.5 ppb. Aqueous perchlorate is both chemically stable in natural water and extremely soluble and mobile; as a result, many traditional wastewater treatment techniques that are commonly used for solvents and other organic pollutants are not effective for removal of perchlorate from contaminated water. Presently, most Army ammunition plants use granular activated carbon (GAC) adsorption and alkaline hydrolysis to separate and treat energetic compounds in wastewater from munitions manufacturing and demilitarization processes. GAC processes are not only expensive but generate explosive-laden spent carbon, which needs to be treated or disposed of properly to avoid secondary contamination problems. This additional treatment further increases the overall cost of wastewater treatment. The overall objective of this research was to develop a novel treatment process for the removal of perchlorate and energetic compounds from mixed ammunition wastewater. We investigated two options for effective removal of perchlorate from mixed munitions wastewater that contains both perchlorate and energetic compounds: (1) increasing the solution temperature to overcome the kinetic barrier of perchlorate reduction by zero-valent iron; and (2) integrating Fe(0)-biological process for simultaneous removal of perchlorate and energetic compounds. Perchlorate reduction by zero-valent iron at elevated temperatures was investigated with a continuous-flow system that consisted of an iron-packed pressure vessel and a heat exchanger. Results from the continuous-flow system showed that 99% of perchlorate was removed in 1 hour of contact time at 175°C. With decreasing pH to 2.5, more than 60% of perchlorate was removed with an iron contact time of 30 min at operation temperature of 95°C. Increasing the reactor temperature to 125°C resulted in 98% perchlorate removal at the same retention time of 30 min. This result demonstrated that Fe(0) technology combined with heating may be a viable option for the removal of perchlorate from Army ammunition wastewater. Biodegradation experiments using glucose as the primary sources of electrons and carbon were conducted to evaluate microbial perchlorate reduction as a practical option for the treatment of perchlorate in PAX-21 wastewater. The results indicated that the constituents in PAX-21 wastewater may be toxic to perchlorate reducing bacteria. A series of batch toxicity test was conducted to identify the toxic constituents in PAX-21 wastewater and DNAN was identified as the primary toxicant responsible for inhibiting the activity of perchlorate reducing bacteria. It was hypothesized that pretreatment of PAX-21 by zero-valent iron granules will transform toxic constituents in PAX-21 wastewater to non-toxic products. Zero-valent iron pretreatment completely removed DNAN and RDX. After a 3-day acclimation period, perchlorate in iron-treated PAX-21 wastewater was rapidly decreased to an undetectable level in 2 days, which demonstrated that iron treatment not only removed energetic compounds but also eliminated the toxic constituents that inhibited the subsequent microbial process. Finally, potential application of energetic compounds as the source of electrons for perchlorate reduction by PRB was investigated. It was hypothesized that the pretreatment of PAX-21 wastewater with Fe(0) would convert energetic compounds to products that are more amenable for biological oxidation and that these products can also serve as electron donors for PRB. Results of batch experiments showed that DNAN was completely reduced to 2,4-diaminoanisole (DAAN) and RDX was completely reduced to formaldehyde in the presence of cast iron granules within 2 h. Batch biodegradation experiments showed that formaldehyde can serve as an electron donor for perchlorate respiring bacteria. It was also demonstrated that complete reduction of perchlorate in iron-treated PAX-21 wastewater can be achieved without adding an exogenous electron donor. This study confirmed that iron pretreatment not only removed energetic compounds, but also transformed the energetic compounds to products that can serve as the source of electrons for perchlorate respiring bacteria. Based on the results, we proposed an integrated Fe(0)-biological process for simultaneous removal of perchlorate and energetic compounds, which consists of (1) a Fe(0) process for the reduction of electron-withdrawing nitro groups to biodegradable compounds and (2) an anaerobic biological treatment process containing perchlorate-respiring bacteria, which utilize Fe(0)-treated energetic compounds as electron donor and perchlorate as electron acceptor.
Download or read book Contaminants in Drinking and Wastewater Sources written by Manish Kumar and published by Springer Nature. This book was released on 2020-06-29 with total page 447 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume takes a multidisciplinary approach to study and evaluate the global human vulnerability to the exposure of contaminants of emerging concern (CECs) in the natural environment. It provides a comprehensive resource on structurally diverse groups of chemical compounds that have adverse effects on the aquatic environment. It explores the global strength, environmental status, chemical risk assessment and management strategies of CECs with relevant modern techniques. The principle focus is on concurrent emerging water quality issues. It defines the impacts of the environmental exposure of trace concentrations of CECs and/or their metabolites and discusses possible technological advances to combat the emerging pollutants. It will be useful to researchers, multi-stakeholder expert groups, policymakers, and graduate students.
Download or read book Batch Adsorption Process of Metals and Anions for Remediation of Contaminated Water written by Deepak Gusain and published by CRC Press. This book was released on 2021-03-18 with total page 241 pages. Available in PDF, EPUB and Kindle. Book excerpt: Adsorption is one of the method that is in use for remediation of contaminated water. The experimental factors affecting the batch mode of adsorption of various metals and inorganic anions are discussed in this book. The elemental contaminants have been categorized into four major categories i.e. major toxic elements; essential elements having toxicity on excessive exposure; miscellaneous elements having undetermined effects; non-toxic elements having trivial or unidentified significance. In addition, anions like nitrate, perchlorate and sulphate as water contaminants are considered. This unique volume fills a niche in the area of water treatment. Key Features: Provides practitioners with the background they need to understand and apply batch adsorption processes to the purification of water Describes the actions of adsorption capacity or percentage removal with respect to factors affecting the adsorption process Excellent source of information for those working in the industry for remediation of metals and anions Discusses the current era of Anthropocene which is highly dependent on the anthropogenic mineral sources for its sustenance
Download or read book Perchlorate written by Kathleen Sellers and published by CRC Press. This book was released on 2006-08-30 with total page 258 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of analytical methods for identifying widespread perchlorate contamination brought about an explosion of research into the environmental problems and their potential solutions along with a corresponding increase in the availability of information. Unlike reference works that focus on only a few aspects of this contaminant, Perchlorate: Environmental Problems and Solutions offers a comprehensive, single source of information on perchlorate contamination in the environment. Summarizing the state of the science and developments in engineering, the book describes: Common sources of perchlorate Its behavior in the environment Methods for analyzing perchlorate in environmental samples Potential risks to human health and the environment Regulatory standards and criteria Techniques for remediating environmental contamination The authors illustrate these points with case studies of perchlorate contamination in soil, groundwater, and surface water. These case studies provide perspective on issues commonly faced by scientists, engineers, and managers of perchlorate-impacted sites. Organized to follow the logical sequence of identifying and solving contamination problems, the book provides the foundation necessary to understand perchlorate's occurrence, environmental behavior, regulatory status, and remediation.
Download or read book Perchlorate written by Kathleen Sellers and published by CRC Press. This book was released on 2006-08-30 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of analytical methods for identifying widespread perchlorate contamination brought about an explosion of research into the environmental problems and their potential solutions along with a corresponding increase in the availability of information. Unlike reference works that focus on only a few aspects of this contaminant, Perchlora
Download or read book Perchlorate written by Brian Scott Aikin and published by Lawyers & Judges Publishing. This book was released on 2006-01 with total page 457 pages. Available in PDF, EPUB and Kindle. Book excerpt: Perchlorate, a naturally occurring and synthesized chemical, is generating intense publicity, scientific debate, regulatory scrutiny, and litigation across the United States. The substance has been widely used for over sixty years in the production of rocket fuel, flares, fireworks, electronics, and munitions, but did not emerge as a significant environmental issue until the mid-1990s, when improved analytical testing methods permitted its detection in groundwater at 4 parts per billion. As of 2005, perchlorate has been detected in forty-nine of the fifty states, and is the focus of mounting regulatory enforcement actions and widespread civil litigation. Perchlorate: A Scientific, Legal, and Economic Assessment is designed to educate and inform business, environmental, legal, and academic audiences about the history and development of the perchlorate controversy. It is also intended to provide practical advice and guidance to those involved in perchlorate litigation, remediation, and regulation. The book identifies and discusses existing and anticipated liability theories and damage claims asserted in perchlorate litigation. The authors explain the theories of environmental liability, identify the tort claims most commonly asserted in environmental litigation, and provide an overview of environmental class actions. The book includes chapters covering key practical issues raised in perchlorate litigation, such as estimating monetary damages, the retention and use of experts, and obtaining insurance coverage for liabilities. These important topics will assist legal and other professionals involved in current perchlorate litigation and provide a broad base of knowledge to apply in future environmental contamination litigation.
Download or read book Development of a Screening Model for Design and Costing of an Innovative Tailored Granular Activated Carbon Technology to Treat Perchlorate contaminated Water written by William C. Powell and published by . This book was released on 2007 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt:
