Download or read book Acetylene and Its Polymers written by Seth C. Rasmussen and published by Springer. This book was released on 2018-07-21 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Brief presents for the first time a detailed historical overview of the development of acetylene polymers, beginning with the initial discovery of acetylene in 1836 and continuing up through the 2000 Nobel Prize in Chemistry. The polymerization of acetylene is most commonly associated with polyacetylene, which was found to be conductive when treated with oxidizing agents such as Br2 or I2 in the mid‐to‐late 1970s. In fact, under the right conditions, oxidized polyacetylenes can exhibit conductivities into the metallic regime, thus providing the first example of an organic polymer exhibiting metallic conductivity. As a consequence, the 2000 Nobel Prize in Chemistry was awarded to Hideki Shirakawa, Alan MacDiarmid, and Alan Heeger for this pioneering research, the award citation reading “for the discovery and development of electrically conductive polymers.” Because of this, most incorrectly view polyacetylene, as well as conducting polymers in general, to originate in the 1970s. In this work, the author examines the polymerization of acetylene from early thermal polymerization studies to the ultimate production of the fully conjugated polyacetylene. Although true polyacetylene was not successfully produced until the 1950s by Giulio Natta, the polymerization of acetylene dates back to 1866 with the work of Marcellin Berthelot. These initial efforts were continued by a range of scientists to produce a polymeric material collectively given the name cuprene in 1900 by Paul Sabatier. Between the initial cuprene studies and the production of true polyacetylene, two related materials were also studied, usually referred to as polyenes and polyvinylenes. Although both of these materials could be thought of as forms of polyacetylene, neither was actually generated from the direct polymerization of acetylene. Readers will gain insight into the fact that polyacetylene and conducting organic polymers have a much longer history than commonly believed and involved the work of a significant number of Nobel Laureates.

Download or read book Polyacetylene written by James C.W. Chien and published by Elsevier. This book was released on 2012-12-02 with total page 649 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyacetylene: Chemistry, Physics, and Material Science reviews the chemistry, physics, and material science of polyacetylene. Topics covered include polymerization and crystal structure of polyacetylene, isomerization, neutral defects, and solitons. Globular morphology and the effect of heat of polymerization on polyacetylene are also discussed, along with doping and chemical reactions of polyacetylene. This book is comprised of 12 chapters and begins with an introduction to a few basic principles of polymer chemistry and solid-state physics, followed by an overview of charge-transfer salts and conducting polymers other than polyacetylene and a historical background on polyacetylene and a general description of its properties. The next chapter gives a detailed treatment of polymerization, with particular reference to the mechanisms and kinetics of acetylene polymerization and direct determination of polyacetylene molecular weight by radioquenching. The remaining chapters focus on the crystal structures and morphology of undoped polyacetylenes; methods of isomerization; spectroscopic, physical, and mechanical properties of undoped polyacetylene; and various chemical reactions of polyacetylene and polymethylacetylene. The probable mechanisms of doping are proposed and theoretical models for polyacetylene are presented. The final chapter considers a few technical applications of polyacetylene. This monograph will be of interest to chemists, physicists, and polymer scientists and engineers.

Download or read book Study of Polymerization of Acetylene Derivatives written by S. Dumitrescu and published by . This book was released on 1972 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Acetylene Chemistry written by François Diederich and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: Acetylenes are an important and valuable class of compounds in organic synthesis. This book expands on this historically well-established concept, while incorporating the many new developments that have widened the number of applications in this field. It remains the only handbook available that embodies all the important facets of acetylene chemistry. Following the first section on synthesis, the leading authors deal with advanced materials before turning to the properties and theory of acetylenes, while a final section looks at the biological aspects. With its range of experimental procedures, this book is a practical aid for both organic and organometallic chemists, as well as for materials scientists, biochemists, and industrial chemists.

Download or read book The Polymerization and Hydrogenation of Acetylene written by Andrew Van Hook and published by . This book was released on 1935* with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Polymerization of Acetylene to Cyclooctatetraene written by Karl Kammermeyer and published by . This book was released on 1947 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Manufacture of Fine Chemicals from Acetylene written by Sifang Li and published by Walter de Gruyter GmbH & Co KG. This book was released on 2021-07-19 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book gives a complete overview on today’s research, development and industrialization of fine chemicals from acetylene. The author provides a comprehensive methodology by covering derivatives from acetylene reacting with formaldehyde, alcohol, ketone, halogen and acetic acid. The book offers extensive and practical reference work for chemists and chemical engineers as well as university teachers and students.

Download or read book Artificial Cilia written by Jaap MJ den Toonder and published by Royal Society of Chemistry. This book was released on 2013-05-31 with total page 279 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cilia are tiny hairs covering biological cells to generate and sense fluid flow. Millions of years of evolution have inspired a novel technology which is barely a decade old. Artificial cilia have been developed to control and sense fluid flow in microscopic systems, presenting new and interesting options for flow control in lab-on-a-chip devices. This appealing link between nature and technology has seen rapid development in the last few years, and this book presents a review of the state-of-the-art in the form of a professional reference book. The editors have pioneered the field, having initiated a major European project on this topic soon after its inception. Active researchers in academia and industry will benefit from the comprehensive nature of this book, while postgraduates and those new to the field will gain a clear understanding of the theory, techniques and applications of artificial cilia.

Download or read book Polyynes written by Franco Cataldo and published by CRC Press. This book was released on 2005-08-29 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyynes: Synthesis, Properties, and Applications compiles information found scattered throughout the literature in inorganic, organic, and polymer chemistry into one cohesive volume. In addition to being a precursor of fullerenes, polyynes are one of the key precursors in the formation of soot and carbon dust, or elemental carbon in the gal

Download or read book The Polymerization of Acetylene written by and published by . This book was released on 1954 with total page 63 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Nanomaterials for Biosensors written by Bansi D. Malhotra and published by William Andrew. This book was released on 2017-10-26 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanomaterials for Biosensors: Fundamentals and Applications provides a detailed summary of the main nanomaterials used in biosensing and their application. It covers recent developments in nanomaterials for the fabrication of biosensor devices for healthcare diagnostics, food freshness and bioprocessing. The various processes used for synthesis and characterization of nanostructured materials are examined, along with the design and fabrication of bioelectronic devices using nanostructured materials as building blocks. Users will find the fundamentals of the main nanomaterials used in biosensing, helping them visualize a systematic and coherent picture of how nanomaterials are used in biosensors. The book also addresses the role of bio-conjugation of nanomaterials in the construction of nano-biointerfaces for application in biosensors. Such applications, including metal nanoparticles, metal oxide nanoparticles, nanocomposites, carbon nanotubes, conducting polymers and plasmonic nanostructures in biosensing are discussed relative to each nanomaterial concerned. Finally, recent advancements in protein functionalized nanomaterials for cancer diagnostics and bio-imaging are also included. Provides a detailed study on how nanomaterials are used to enhance sensing capabilities in biosensors Explains the properties, characterization methods and preparation techniques of the nanomaterials used in biosensing Arranged in a material-by-material way, making it clear how each nanomaterial should be used

Download or read book The Chemistry of Acetylene written by Julius Arthur Nieuwland and published by . This book was released on 1945 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Click Polymerization written by Anjun Qin and published by Royal Society of Chemistry. This book was released on 2018-08-28 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Click Polymerization has been edited by world renowned experts and provides an authoritative guide to this reaction type.

Download or read book Conductive Polymers written by Raymond B. Seymour and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: Those who recognize that our modern life style is dependent, to a large extent, on the use of organic polymers as thermal and elec trical insulators, may be surprised to learn that specific plastics may also be used as conductors of electricity. In addition to demon strating the versatility of polymers, this use as conductors will lead to developments which were not possible with other available materials of construction. This is a new field which is growing rapidly because of intensive research and developmental efforts by many different industrial, governmental and university investigators. Many of these researchers reported advances in this art at a symposium on conductive polymers sponsored by the American Chemical Society's Division of Organic Coatings and Plastics Chemistry held at the Second Chemical Congress of the North American Continent at Las Vegas, in August 1980. The proceedings of this timely symposium are presented in this book. The editor wishes to take this opportunity to express his grati tude to the authors who contributed to this book and to the ACS Organic Coatings and Plastics Division for sponsoring this effort. Raymond B. Seymour Department of Polymer Science University of Southern Mississippi Hattiesburg, MS 39401 v CONTENTS 1 New Horizons in Conductive Polymers Raymond B. Seymour Synthesis and Characterization of Conductive 7 Palladium Containing Polyimide Films • T.L. Wohlford. J. Schaff. L.T. Taylor.

Download or read book The Preparation of the Acetylene Polymer by the Silent Discharge Method and Its Reactions with the Hydrogen Halides written by and published by . This book was released on 1945 with total page 90 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book A Study of the Polymerization of Acetylene by Slow Electrons of Controlled Energy written by Francis William Martin and published by . This book was released on 1938 with total page 30 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Polymer Synthesis Based on Triple bond Building Blocks written by Ben Zhong Tang and published by Springer. This book was released on 2018-07-09 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: ​The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.