Download or read book A Preliminary Investigation of the Kinetics and Mechanism of the Oxidation of the Vanadyl Ion by Peroxydiphophate written by Mary Doris Wiswell and published by . This book was released on 1967 with total page 42 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Kinetics of Trivalent Vanadium Oxidations I By Iodine II By Oxygen written by Morris J. Heldman and published by . This book was released on 1936 with total page 96 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Oxidation Kinetics of Trivalent Vanadium written by Roy Sugimoto and published by . This book was released on 1941 with total page 112 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book A Study of the Kinetics and Mechanism of the Oxidation of NADH by Ferrocenicm Ions and Quinones written by Brian Willard Carlson and published by . This book was released on 1985 with total page 173 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Kinetics of the Trivalent Vanadium oxygen Reaction written by Howard DeVorkin and published by . This book was released on 1939 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Kinetics and Mechanism of Oxidation of Isopropanol with the Hydrogen Peroxide vanadate Ion pyrazine 2 carboxylic Acid System written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The vanadate anion in the presence of pyrazine-2-carboxylic acid (PCA) was found to effectively catalyze the oxidation of isopropanol to acetone with hydrogen peroxide. The electronic spectra of solutions and the kinetics of oxidation were studied. The conclusion was drawn that the rate-determining stage of the reaction was the decomposition of the vanadium(V) diperoxo complex with PCA, and the particle that induced the oxidation of isopropanol was the hydroxyl radical. Supposedly, the HO• radical detached a hydrogen atom from isopropanol, and the Me2 C• (OH) radical formed reacted with HOO• to produce acetone and hydrogen peroxide. The electronic spectra of solutions in isopropanol and acetonitrile and the dependences of the initial rates of isopropanol oxidation without a solvent and cyclohexane oxidation in acetonitrile on the initial concentration of hydrogen peroxide were compared. The conclusion was drawn that hydroxyl radicals appeared in the oxidation of alkanes in acetonitrile in the decomposition of the vanadium diperoxo complex rather than the monoperoxo derivative, as was suggested by us earlier.