Download or read book A Chemical Kinetics Model for the Opposed Flow Diffusion Flame written by C. M. Ablow and published by . This book was released on 1972 with total page 36 pages. Available in PDF, EPUB and Kindle. Book excerpt: A theoretical analysis is developed of the reaction kinetics limitations leading to the extinction of a counterflow diffusion flame. With increasing mass flux of reactants into the diffusion flame a maximum in the consumption rate of fuel and oxidizer in the reaction zone is encountered. The analysis shows that experimental measurements of the extinction conditions ('apparent flame strengths') are amenable to evaluation of overall kinetic parameters such as the activation energy, the preexponential Arrhenius term, and the order of reaction. The theoretical model is applied to the propane-oxygen-nitrogen system and an activation energy of 21.9 kcal/mole is derived from published experimental flame extinction data. (Author).

Download or read book Solid Propellant Kinetics V Fuel Oxidizer Reaction Rates from Heterogeneous Opposed Flow Diffusion Flame written by and published by . This book was released on 1974 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt: A theoretical model is presented relating the gas dynamics and chemical kinetics of the opposed flow diffusion flame formed in the stagnation region between two opposing streams of gaseous reactants, one originating from the surface of a subliming solid, such as ammonium perchlorate. At low gas flows the regression rate of the solid is controlled by the physical properties of the system, including the net heat of gasification, the heat of combustion, and the transport parameters. At high gas flows a limiting solid regression rate is attained due to reaction-rate limitations that cause incomplete combustion of the reactants. The theoretical model developed for the heterogeneous opposed flow diffusion flame allows interpretation of the limit in solid regression rates in terms of global reaction kinetics.

Download or read book Chemical Kinetics in Combustion and Reactive Flows Modeling Tools and Applications written by V. I. Naoumov and published by Cambridge University Press. This book was released on 2019-08-22 with total page 449 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduces advanced mathematical tools for the modeling, simulation, and analysis of chemical non-equilibrium phenomena in combustion and flows, following a detailed explanation of the basics of thermodynamics and chemical kinetics of reactive mixtures. Researchers, practitioners, lecturers, and graduate students will find this work valuable.

Download or read book Analysis of opposed jet hydrogen air counter flow diffusion flame written by and published by DIANE Publishing. This book was released on with total page 84 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Solid Propellant Kinetics II Theoretical Analysis of the Heterogeneous Opposed Flow Diffusion Flame written by C. M. Ablow and published by . This book was released on 1971 with total page 17 pages. Available in PDF, EPUB and Kindle. Book excerpt: A theoretical analysis is presented of the heterogeneous opposed flow diffusion flame (HOFD). In such a system a gaseous reactant (G) impinges on a solid reaction (S) undergoing sublimation (or vaporization) and a diffusion flame is established at the stagnation point. With increasing mass flux of the gaseous reactant (mG) the mass flux of solid reactant (mS) grows until the total consumption rate of reactants reaches a limiting value due to limitations imposed by the kinetics of reaction. The analysis of the axi-symmetrical stagnation point flow with chemical reaction allows evaluation of the kinetics of chemical reaction at temperatures of interest to combustion processes. (Author).

Download or read book Physical and Chemical Aspects of Combustion written by F Dryer and published by CRC Press. This book was released on 1997-08-20 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book contains a collection of papers prepared by leading experts on selected areas of particular importance to researchers in combustion science. The editors have gathered writings on fundamental physical and chemical aspects of combustion, including combustion chemistry, soot formation, and condensed phase and turbulent combustion intended to be a source of current understanding on the topics covered. The materials were originally presented as part of a Colloquium on Combustion held in honor of Professor Irvin Glassman.

Download or read book Investigations into the Combustion Kinetics of Several Novel Oxygenated Fuels written by Wenyu Sun and published by Springer Nature. This book was released on 2023-09-22 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this thesis, attention was paid to several novel oxygenated fuels—carbonates, polyethers and ketones. Combustion kinetic investigations were performed for typical representative compounds, including dimethyl carbonate, diethyl carbonate, cyclopentanone, 3-pentanone, 1,2-dimethoxyethane and dimethoxymethane. For experiments, suitable diagnostic techniques were used to measure the detailed speciation information of the target fuels under different conditions. For kinetic modeling, rate coefficients for crucial elementary reactions were obtained through high-level theoretical calculations. Based on that, validated kinetic models with good predictive performances were developed. On the basis of experimental measurements and model interpretations, this work highlighted two important combustion characteristics regarding the practical use: the pollutant formation and the ignition performance. Besides, the correlation between oxygen-containing functional groups and the aforementioned combustion characteristics was revealed. To reveal the potential interactions between the reaction networks of oxygenated additives and the hydrocarbon base fuels during combustion. Chemical structures of laminar premixed flames fueled by binary fuels were measured, and by changing the initial fuel compositions, the addition effects of the oxygenates on the fuel consumption and pollutant formation behaviors were explored. It was found that complicated chemical interactions do not exist in the reaction networks under the investigated conditions.

Download or read book Diffusion and Heat Exchange in Chemical Kinetics written by David Albertovich Frank-Kamenetskii and published by Princeton University Press. This book was released on 2015-12-08 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: Frank-Kamenetskii, a leader in Russian science, was the first to define conditions for two stable operating regimes in chemical reactions, one controlled by chemical reactions, the other by diffusion processes. In this book he treats mathematically the subjects of reaction ignition, quenching, and periodic processes in chemical kinetics as found in flames, combustion of solids, and other chemical reactions. The book was translated from the Russian by the late N. Thou and edited by R. Wilhelm. Originally published in 1955. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.

Download or read book Chemically Reacting Flow written by Robert J. Kee and published by John Wiley & Sons. This book was released on 2017-08-30 with total page 793 pages. Available in PDF, EPUB and Kindle. Book excerpt: A guide to the theoretical underpinnings and practical applications of chemically reacting flow Chemically Reacting Flow: Theory, Modeling, and Simulation, Second Edition combines fundamental concepts in fluid mechanics and physical chemistry while helping students and professionals to develop the analytical and simulation skills needed to solve real-world engineering problems. The authors clearly explain the theoretical and computational building blocks enabling readers to extend the approaches described to related or entirely new applications. New to this Second Edition are substantially revised and reorganized coverage of topics treated in the first edition. New material in the book includes two important areas of active research: reactive porous-media flows and electrochemical kinetics. These topics create bridges between traditional fluid-flow simulation approaches and transport within porous-media electrochemical systems. The first half of the book is devoted to multicomponent fluid-mechanical fundamentals. In the second half the authors provide the necessary fundamental background needed to couple reaction chemistry into complex reacting-flow models. Coverage of such topics is presented in self-contained chapters, allowing a great deal of flexibility in course curriculum design. • Features new chapters on reactive porous-media flow, electrochemistry, chemical thermodynamics, transport properties, and solving differential equations in MATLAB • Provides the theoretical underpinnings and practical applications of chemically reacting flow • Emphasizes fundamentals, allowing the analyst to understand fundamental theory underlying reacting-flow simulations • Helps readers to acquire greater facility in the derivation and solution of conservation equations in new or unusual circumstances • Reorganized to facilitate use as a class text and now including a solutions manual for academic adopters Computer simulation of reactive systems is highly efficient and cost-effective in the development, enhancement, and optimization of chemical processes. Chemically Reacting Flow: Theory, Modeling, and Simulation, Second Edition helps prepare graduate students in mechanical or chemical engineering, as well as research professionals in those fields take utmost advantage of that powerful capability.

Download or read book Diffusion and Heat Transfer in Chemical Kinetics written by David Alʹbertovich Frank-Kamenet︠s︡kiĭ and published by . This book was released on 1969 with total page 610 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Direct Numerical Simulation for Turbulent Reacting Flows written by Thierry Baritaud and published by Editions TECHNIP. This book was released on 1996 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: Description of accurate boundary conditions for the simulation of reactive flows. Parallel direct numerical simulation of turbulent reactive flow. Flame-wall interaction and heat flux modelling in turbulent channel flow. A numerical study of laminar flame wall interaction with detailed chemistry: wall temperature effects. Modeling and simulation of turbulent flame kernel evolution. Experimental and theoretical analysis of flame surface density modelling for premixed turbulent combustion. Gradient and counter-gradient transport in turbulent premixed flames. Direct numerical simulation of turbulent flames with complex chemical kinetics. Effects of curvature and unsteadiness in diffusion flames. Implications for turbulent diffusion combustion. Numerical simulations of autoignition in turbulent mixing flows. Stabilization processes of diffusion flames. References.

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1991 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Recent Advances in the Aerospace Sciences written by Corrado Casci and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume, published in honor of Prof. Luigi Crocco, appears when Luigi Crocco celebrates his 75th birthday of a life devoted to study, research, and teaching. The events in his life and World War II forced Luigi Crocco, as well as other Italian scientists, to look to foreign countries for the calm haven so vital to study. This notwithstanding, his scientific activity was never inter rupted, and this volume is an acknowledgment of scientists and researchers to his work and life. Prefazione Questo volume in onore del prof. ing. Luigi Crocco vede la luce quando Luigi Crocco compie i 75 anni di una vita dedicata allo studio, alia ricerca e all'insegnamento. a Le vicende della vita, ed anche della 2 guerra mondiale, hanno costretto Luigi Crocco, come altri scienziati italiani, a dover cercare in altri Paesi quella serenita necessaria per dedicarsi allo studio. Ma la sua attivita scientifica non ha avuto interruzioni e questo volume essere la testimonianza di studiosi e di ricercatori alia sua opera e alia sua vita."

Download or read book Applied Mechanics Reviews written by and published by . This book was released on 1983 with total page 876 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Experimental and Kinetic Modeling Study of Cyclohexane and Its Mono alkylated Derivatives Combustion written by Zhandong Wang and published by Springer. This book was released on 2018-01-23 with total page 225 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis investigates the combustion chemistry of cyclohexane, methylcyclohexane, and ethylcyclohexane on the basis of state-of-the-art synchrotron radiation photoionization mass spectrometry experiments, quantum chemistry calculations, and extensive kinetic modeling. It explores the initial decomposition mechanism and distribution of the intermediates, proposes a novel formation mechanism of aromatics, and develops a detailed kinetic model to predict the three cycloalkanes’ combustion properties under a wide range of conditions. Accordingly, the thesis provides an essential basis for studying much more complex cycloalkanes in transport fuels and has applications in engine and fuel design, as well as emission control.

Download or read book Cleaner Combustion written by Frédérique Battin-Leclerc and published by Springer Science & Business Media. This book was released on 2013-09-06 with total page 657 pages. Available in PDF, EPUB and Kindle. Book excerpt: This overview compiles the on-going research in Europe to enlarge and deepen the understanding of the reaction mechanisms and pathways associated with the combustion of an increased range of fuels. Focus is given to the formation of a large number of hazardous minor pollutants and the inability of current combustion models to predict the formation of minor products such as alkenes, dienes, aromatics, aldehydes and soot nano-particles which have a deleterious impact on both the environment and on human health. Cleaner Combustion describes, at a fundamental level, the reactive chemistry of minor pollutants within extensively validated detailed mechanisms for traditional fuels, but also innovative surrogates, describing the complex chemistry of new environmentally important bio-fuels. Divided into five sections, a broad yet detailed coverage of related research is provided. Beginning with the development of detailed kinetic mechanisms, chapters go on to explore techniques to obtain reliable experimental data, soot and polycyclic aromatic hydrocarbons, mechanism reduction and uncertainty analysis, and elementary reactions. This comprehensive coverage of current research provides a solid foundation for researchers, managers, policy makers and industry operators working in or developing this innovative and globally relevant field.

Download or read book Tubular Combustion written by Satoru Ishizuka and published by Momentum Press. This book was released on 2013-11-04 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: Tubular combustors are cylindrical tubes where flame ignition and propagation occur in a spatially confined, highly controlled environment, in a nearly flat, elongated geometry. This allows for some unique advantages where extremely even heat dispersion is required over a large surface while still maintaining fuel efficiency. Tubular combustors also allow for easy flexibility in type of fuel source, allowing for quick changeover to meet various needs and changing fuel pricing. This new addition to the MP sustainable energy series will provide the most up-to-date research on tubular combustion--some of it only now coming out of private proprietary protection. Plentiful examples of current applications along with a good explanation of background theory will offer readers an invaluable guide on this promising energy technology. Highlights include: * An introduction to the theory of tubular flames * The "how to" of maintaining stability of tubular flames through continuous combustion * Examples of both small-scale and large-scale applications like steel making, chemical processing, flexible-fuel-source heaters, efficient boilers, and other similar uses